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3D printing materials and their preparation methods and applications

A technology of 3D printing and printing materials, applied in the field of 3D molding, can solve the problems of bearing difference, restricting the application of continuous fiber printing technology, and restricting the application of continuous fiber printing parts

Active Publication Date: 2021-03-09
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] At this stage, continuous fiber reinforced 3D printing technology has good advantages in printing planar structures or simple structures, with high tensile strength and modulus. However, it is difficult to add fibers to non-printing planes using continuous fibers as 3D printing raw materials. ; Then in this case, if only relying on the adhesive force of the resin, compared with the fiber, there is a significant load difference, thus restricting the application of continuous fiber printing parts on structural parts
At the same time, because the wire contains continuous fibers, it is difficult to use 3D printing technology when forming spatial components (such as lattices), which limits the application of continuous fiber printing technology in lightweight structures or hollow structures.

Method used

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  • 3D printing materials and their preparation methods and applications
  • 3D printing materials and their preparation methods and applications
  • 3D printing materials and their preparation methods and applications

Examples

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preparation example Construction

[0048] In addition, the present invention also provides a preparation method for the above-mentioned 3D printing material, comprising the following steps:

[0049] Step 1, preparing modified chopped fibers, including:

[0050] A1.1 Coat the surface of the fiber with an inert resin solution and heat and cure to obtain the coated fiber;

[0051] A1.2 cutting the coated fibers to obtain coated chopped fibers;

[0052] A1.3 chemically grafting the chopped fibers so that the end faces of the chopped fibers contain active groups;

[0053] Step 2, prepare 3D printing materials, adopt any of the following methods:

[0054] Method 1: Mix the modified chopped fibers prepared in step 1 with thermoplastic resin and granulate to obtain the 3D printing material;

[0055] Method 2: uniformly mix the modified chopped fibers prepared in step 1 with the granulated thermoplastic resin to obtain the 3D printing material.

[0056] Further, the present invention also provides the application of...

Embodiment 1

[0065] Printing process of carbon fiber reinforced polypropylene resin

[0066] Main material: 12K carbon fiber (without sizing agent), polypropylene resin

[0067] Fiber coating process: brush the surface of carbon fiber with epoxy resin solution, the content is 1%-1.5%, and heat and cure;

[0068] Fiber cutting: cutting carbon fiber into 0.5mm long short cut material;

[0069] Fiber chemical treatment: Soak the short fiber in a chemical solution for surface grafting reaction; obtain a material with double bond groups on the end surface.

[0070] Manufacture of granules: add processed fiber (30% v), polypropylene (63% v), styrene (6% v) and catalyst (1% v) into twin-screw equipment for extrusion granulation;

[0071] Manufacturing wire: use wire forming equipment to prepare 1.75mm printing wire (can be omitted, and print directly with pellets);

[0072] Heating and melting: This part is the beginning stage of printing. The wire starts to melt when it is heated at the nozzl...

Embodiment 2

[0077] Printing process of carbon fiber reinforced polyethylene resin

[0078] Main material: 12K carbon fiber (without sizing agent), polyethylene resin

[0079] Fiber coating process: brush the surface of carbon fiber with epoxy resin solution, the content is 1%-1.5%, and heat and cure;

[0080] Fiber cutting: cutting carbon fiber into 1mm long short cut;

[0081] Fiber chemical treatment: Soak the short fibers in a chemical solution for surface grafting reaction; obtain a material with carboxyl groups on the end surface.

[0082] Manufacture particles: polyethylene (73% v), epoxy resin (6% v) and catalyst (1% v) of terminal hydroxyl group, join in twin-screw equipment and carry out extruding granulation and with above-mentioned processed fiber (20 %v) uniform mixing;

[0083] Manufacture wire: use wire forming equipment to prepare 3mm printing wire (can be omitted, and print directly with pellets);

[0084] Heating and melting: This part is the beginning stage of printi...

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Abstract

The invention provides a 3D printing material and its preparation method and application. The printing material includes several modified chopped fibers and a component comprising at least a thermoplastic resin, wherein the end faces of any of the modified chopped fibers are grafted There are active groups, and any part of the modified chopped fiber except the end face is coated with an inert resin, and the inert resin does not react with the active groups. The printing material of the present invention brings the concept of modified chopped fibers, that is, the reactive connection of reinforcement segments, into continuous fiber-reinforced thermoplastic materials, which can not only realize the advantages of continuous fibers in 3D printing, but also maintain this advantage. On the other hand, it is also possible to realize the printing and molding of hollow structures or three-dimensional structures.

Description

technical field [0001] The invention relates to the technical field of 3D molding, in particular to a 3D printing material and its preparation method and application. Background technique [0002] 3D printing, also known as additive manufacturing, is a technology that adds materials layer by layer through printing equipment to manufacture three-dimensional objects based on a pre-designed three-dimensional model. This technology integrates cutting-edge technologies in the fields of digital modeling technology, electromechanical control technology, information technology, material science and chemistry. It is a kind of rapid prototyping technology and is known as the core technology of the "third industrial revolution". The printing technology of thermoplastic resin is the main component, especially the printing technology of continuous fiber reinforcement shows a more prominent prospect with its excellent mechanics and high load-bearing capacity. [0003] At this stage, cont...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B29C64/00B33Y70/10
CPCB33Y70/00B29C64/00
Inventor 毕向军谭洪生刘志涛魏安生
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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