3D printing materials and their preparation methods and applications
A technology of 3D printing and printing materials, applied in the field of 3D molding, can solve the problems of bearing difference, restricting the application of continuous fiber printing technology, and restricting the application of continuous fiber printing parts
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[0048] In addition, the present invention also provides a preparation method for the above-mentioned 3D printing material, comprising the following steps:
[0049] Step 1, preparing modified chopped fibers, including:
[0050] A1.1 Coat the surface of the fiber with an inert resin solution and heat and cure to obtain the coated fiber;
[0051] A1.2 cutting the coated fibers to obtain coated chopped fibers;
[0052] A1.3 chemically grafting the chopped fibers so that the end faces of the chopped fibers contain active groups;
[0053] Step 2, prepare 3D printing materials, adopt any of the following methods:
[0054] Method 1: Mix the modified chopped fibers prepared in step 1 with thermoplastic resin and granulate to obtain the 3D printing material;
[0055] Method 2: uniformly mix the modified chopped fibers prepared in step 1 with the granulated thermoplastic resin to obtain the 3D printing material.
[0056] Further, the present invention also provides the application of...
Embodiment 1
[0065] Printing process of carbon fiber reinforced polypropylene resin
[0066] Main material: 12K carbon fiber (without sizing agent), polypropylene resin
[0067] Fiber coating process: brush the surface of carbon fiber with epoxy resin solution, the content is 1%-1.5%, and heat and cure;
[0068] Fiber cutting: cutting carbon fiber into 0.5mm long short cut material;
[0069] Fiber chemical treatment: Soak the short fiber in a chemical solution for surface grafting reaction; obtain a material with double bond groups on the end surface.
[0070] Manufacture of granules: add processed fiber (30% v), polypropylene (63% v), styrene (6% v) and catalyst (1% v) into twin-screw equipment for extrusion granulation;
[0071] Manufacturing wire: use wire forming equipment to prepare 1.75mm printing wire (can be omitted, and print directly with pellets);
[0072] Heating and melting: This part is the beginning stage of printing. The wire starts to melt when it is heated at the nozzl...
Embodiment 2
[0077] Printing process of carbon fiber reinforced polyethylene resin
[0078] Main material: 12K carbon fiber (without sizing agent), polyethylene resin
[0079] Fiber coating process: brush the surface of carbon fiber with epoxy resin solution, the content is 1%-1.5%, and heat and cure;
[0080] Fiber cutting: cutting carbon fiber into 1mm long short cut;
[0081] Fiber chemical treatment: Soak the short fibers in a chemical solution for surface grafting reaction; obtain a material with carboxyl groups on the end surface.
[0082] Manufacture particles: polyethylene (73% v), epoxy resin (6% v) and catalyst (1% v) of terminal hydroxyl group, join in twin-screw equipment and carry out extruding granulation and with above-mentioned processed fiber (20 %v) uniform mixing;
[0083] Manufacture wire: use wire forming equipment to prepare 3mm printing wire (can be omitted, and print directly with pellets);
[0084] Heating and melting: This part is the beginning stage of printi...
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Abstract
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