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Preparation method of heat-resistant high-strength PVC cable material

A cable material, PVC resin technology, applied in building insulation materials, plastic/resin/wax insulators, building components, etc., can solve the problems of limited heat resistance of PVC cable materials, reduced material mechanical properties, easy to produce embrittlement and other problems, Achieve the effect of improving compatibility, excellent heat resistance and flame retardant performance, and improving thermal stability

Inactive Publication Date: 2018-12-21
ZHEJIANG WELLSCOM PLASTIC CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In order to solve the problem that the heat resistance of the PVC cable material prepared by the prior art is very limited, it is very easy to age and decompose in a high temperature environment, so that the halogen elements in the matrix polyvinyl chloride material and the hydrogen bonds of adjacent carbon atoms jointly produce hydrogen chloride gas to detach and decompose. The carbon-carbon double bond is formed on the matrix polyvinyl chloride, so the mechanical properties of the material are greatly reduced, especially the problems of embrittlement, cracking and thermal deformation are easy to occur. The invention provides a heat-resistant high-strength PVC cable material. Preparation method, it has excellent heat resistance, and has better mechanical properties than ordinary PVC cable materials

Method used

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  • Preparation method of heat-resistant high-strength PVC cable material
  • Preparation method of heat-resistant high-strength PVC cable material
  • Preparation method of heat-resistant high-strength PVC cable material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] 1) Ingredients: 100 parts by weight of PVC resin, 85 parts by weight of chlorinated polyvinyl chloride, 65 parts by weight of silicon composite filler, 10 parts by weight of surface modifier, 70 parts by weight of plasticizer, 7 parts by weight of lubricant, heat stabilizer 1 part by weight, 6 parts by weight of EMI resin, 8 parts by weight of oxidized polyvinyl alcohol and 1 part by weight of bloom inhibitor to weigh each component;

[0036] 2) Mixing: mix the components weighed in step 1) and stir evenly, the stirring temperature is 45°C, the stirring rate is 60r / min, the stirring time is 5h, and the mixed material is obtained after stirring;

[0037] 3) Granulating: granulating the mixture obtained in step 2) to obtain heat-resistant high-strength PVC cable material;

[0038] Wherein step 1) described surface modifier is gamma-(2,3-glycidoxy) propyltrimethoxysilane, plasticizer is dibutyl phthalate, lubricant is with mass ratio 1: Glyceryl stearate and oxidized poly...

Embodiment 2

[0044] 1) Ingredients: 100 parts by weight of PVC resin, 110 parts by weight of chlorinated polyvinyl chloride, 95 parts by weight of silicon composite filler, 22 parts by weight of surface modifier, 105 parts by weight of plasticizer, 12 parts by weight of lubricant, heat stabilizer 3.5 parts by weight, 10 parts by weight of EMI resin, 17 parts by weight of oxidized polyvinyl alcohol and 3 parts by weight of blooming inhibitor to weigh each component;

[0045] 2) Mixing: Mix the components weighed in step 1) and stir evenly, the stirring temperature is 60°C, the stirring rate is 80r / min, the stirring time is 10h, and the mixture is obtained after stirring;

[0046] 3) Granulating: granulating the mixture obtained in step 2) to obtain heat-resistant high-strength PVC cable material;

[0047] Wherein in step 1) the surface modifier is maleic anhydride grafted polylactic acid, the plasticizer is dioctyl phthalate, and the lubricant is glyceryl stearate mixed with a mass ratio of...

Embodiment 3

[0053] 1) Ingredients: 100 parts by weight of PVC resin, 95 parts by weight of chlorinated polyvinyl chloride, 70 parts by weight of silicon composite filler, 15 parts by weight of surface modifier, 90 parts by weight of plasticizer, 8.5 parts by weight of lubricant, heat stabilizer 1.75 parts by weight, 7.5 parts by weight of EMI resin, 13 parts by weight of oxidized polyvinyl alcohol and 1.75 parts by weight of bloom inhibitor to take each component;

[0054] 2) Mixing: Mix the components weighed in step 1) and stir evenly, the stirring temperature is 55°C, the stirring rate is 80r / min, the stirring time is 6h, and the mixed material is obtained after stirring;

[0055] 3) Granulating: granulating the mixture obtained in step 2) to obtain heat-resistant high-strength PVC cable material;

[0056] Wherein step 1) described surface modifier is gamma-(2,3-glycidoxy) propyltrimethoxysilane, plasticizer is dibutyl phthalate, lubricant is with mass ratio 1: Glyceryl stearate and o...

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Abstract

The invention relates to the field of PVC materials, in particular to a preparation method of a heat-resistant high-strength PVC cable material. The preparation method comprises the following preparation steps of (1) material preparation, wherein 100 parts by weight of PVC resin, 85-110 parts by weight of chlorinated polyvinyl chloride, 65-95 parts by weight of silicon compound filler, 10-22 partsby weight of surface modifier, 70-105 parts by weight of plasticizer, 7-12 parts by weight of lubricant, 1-3.5 parts by weight of heat stabilizer, 6-10 parts by weight of flow modifier, 8-17 parts byweight of film-forming agent and 1-3 parts by weight of spray inhibitor are weighed separately; (2) mixing, wherein the components weighed in the step (1) are evenly stirred after being mixed, a stirring temperature is 45-60 DEG C, a stirring rate is 60-80 r / min, stirring time is 5-10 h, and a mixture is obtained after even mixing is conducted; (3) pelleting, wherein the mixture obtained in the step (2) is subjected to pelleting to obtain the heat-resistant high-strength PVC cable material.

Description

technical field [0001] The invention relates to the field of PVC materials, in particular to a preparation method of a heat-resistant high-strength PVC cable material. Background technique [0002] In the prior art, the cable industry usually uses PVC as the insulating pipe material on the outside of the cable, but due to its own shortcomings, the heat resistance of PVC resin is very limited, and it is very easy to age and decompose in a high temperature environment, making the halogen in the matrix PVC material Hydrogen bonds between elements and adjacent carbon atoms produce hydrogen chloride gas to detach and form carbon-carbon double bonds on the matrix polyvinyl chloride, thus greatly reducing the mechanical properties of the material, especially prone to embrittlement, cracking and thermal deformation. [0003] On March 16, 2018, the Chinese Patent Office disclosed a patent application for a preparation method of a heat-resistant PVC pipe. The application announcement ...

Claims

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Application Information

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IPC IPC(8): C08L27/06C08L27/24C08L25/12C08L29/04C08L23/30C08L95/00C08L45/02C08K13/06C08K5/12C08K5/103C08K3/30C08K3/06H01B3/44
Inventor 赵亚琼
Owner ZHEJIANG WELLSCOM PLASTIC CO LTD
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