A long-branched chain double-comb-shaped polyarylindole anion exchange membrane and a preparation method thereof

An ion-exchange membrane and long-chain branched technology, which is applied in the field of long-chain branched double-comb polyarylindole anion-exchange membrane and its preparation, can solve problems such as molecular chain degradation and membrane performance impact

Active Publication Date: 2019-01-01
DALIAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

However, recent studies have found that these polymer backbones containing ether oxygen bonds have the disadvantage of being easily attacked in a hot-alkali environment and causing molecular chain degradation. T...

Method used

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  • A long-branched chain double-comb-shaped polyarylindole anion exchange membrane and a preparation method thereof
  • A long-branched chain double-comb-shaped polyarylindole anion exchange membrane and a preparation method thereof
  • A long-branched chain double-comb-shaped polyarylindole anion exchange membrane and a preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0050] Synthesis of polyarylindole polymer: under the protection of inert gas, 5.25g 2,3-indoledione and 5.42g biphenyl were dissolved in 6mL methylene chloride and 11mL trifluoroacetic acid, after completely dissolving, the The reaction was placed in an ice-bath environment, 25 mL of trifluoromethanesulfonic acid was slowly added, and then the temperature was gradually raised to room temperature for about 0.5 to 2 hours. When the reaction turned into a highly viscous liquid, the reaction was completed, and it was poured into methanol to obtain a blocky white solid, soaked for about 12 hours, filtered and dried to obtain a crude product. Dissolve the crude product in about 120mL of NMP, pour it into methanol to precipitate a white fibrous solid after completely dissolving, soak for 24 hours, filter, wash with methanol for more than three times, and dry at 60°C for 24 hours in a vacuum environment to obtain the purified polyarylene Indole polymers.

[0051] Preparation of long...

Embodiment 2

[0056] Synthesis of polyarylindole polymer: under the protection of inert gas, 5.25g 2,3-indoledione and 5.42g biphenyl were dissolved in 6mL methylene chloride and 11mL trifluoroacetic acid, after completely dissolving, the The reaction was placed in an ice-bath environment, 25 mL of trifluoromethanesulfonic acid was slowly added, and then the temperature was gradually raised to room temperature for about 0.5 to 2 hours. When the reaction turned into a highly viscous liquid, the reaction ended, and it was poured into methanol to obtain a blocky white solid, soaked for about 12 hours, filtered and dried to obtain a crude product. Dissolve the crude product in about 120mL of NMP, pour it into methanol after completely dissolving to obtain a white fibrous solid, soak for 24 hours, filter, wash with methanol for more than three times, and dry at 60°C for 24 hours in a vacuum environment to obtain the purified polyarylene Indole polymers.

[0057] Preparation of long-chain branch...

Embodiment 3

[0062] Synthesis of polyarylindole polymer: under the protection of inert gas, 5.25g 2,3-indoledione and 5.42g biphenyl were dissolved in 6mL methylene chloride and 11mL trifluoroacetic acid, after completely dissolving, the The reaction was placed in an ice-bath environment, 25 mL of trifluoromethanesulfonic acid was slowly added, and then the temperature was gradually raised to room temperature for about 0.5 to 2 hours. When the reaction turned into a highly viscous liquid, the reaction ended, and it was poured into methanol to obtain a blocky white solid, soaked for about 12 hours, filtered and dried to obtain a crude product. Dissolve the crude product in about 120mL of NMP, pour it into methanol after completely dissolving to obtain a white fibrous solid, soak for 24 hours, filter, wash with methanol for more than three times, and dry at 60°C for 24 hours in a vacuum environment to obtain the purified polyarylene Indole polymers.

[0063] Preparation of long-chain branch...

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Abstract

The invention discloses a long-branched chain double-comb-shaped polyarylindole anion exchange membrane and a preparation method thereof, belonging to the technical field of alkaline anion exchange membranes. The invention synthesizes a polyarylindole polymer containing an aromatic amide group with good stability and mechanical properties, and then grafts the polymer to the long-branched chain ionic liquid to prepare a membrane. The prepared membrane has good alkaline stability and high ionic conductivity, and can be used in alkaline fuel cells.

Description

technical field [0001] The invention belongs to the technical field of basic anion exchange membranes, and relates to a long-chain branched double-comb polyarylindole anion exchange membrane and a preparation method thereof. Background technique [0002] As environmental and energy issues become increasingly prominent, fuel cells, as a clean and efficient power conversion device, are considered to be the most promising and promising solid-state and mobile applications. Among various fuel cells, alkaline fuel cells (AFCs) are considered due to their improved oxygen reduction kinetics and better fuel oxidation kinetics resulting in higher efficiencies and the ability to use low-cost non-precious metal catalysts. is an attractive option. Over the past few decades, there has been increasing interest in AFCs, especially those using anion-exchange membranes (AEMs). In AEMFCs, AEM acts as a solid electrolyte to transport hydroxide ions and prevent fuel crossover between anode and...

Claims

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Application Information

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IPC IPC(8): H01M8/1027H01M8/103H01M8/1072
CPCH01M8/1027H01M8/103H01M8/1072Y02E60/50
Inventor 焉晓明王凯锋贺高红代岩郑文姬阮雪华潘昱
Owner DALIAN UNIV OF TECH
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