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Method for molding biomass composite product based on subcritical water micro-foaming

A biomass material and subcritical water technology, which is applied in the field of biomass composite product molding based on subcritical water micro-foaming, can solve the problems of distribution, size-limited mixing uniformity of foaming agents, and biomass material addition process links. , uneven distribution of cells, etc., to achieve the effect of simple molding process and process flow, light weight and good compatibility

Active Publication Date: 2019-01-08
SOUTH CHINA UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The distribution and size of the cells are greatly limited by the uniformity of the foaming agent in the melt, and the introduction of the foaming agent often increases the cost or is not friendly to the environment
At the same time, the drying treatment of biomass materials also increases the process links and cannot be continuously produced
[0004] Aiming at the discontinuous production of micro-foamed biomass composites and uneven distribution of cells, a molding method of biomass composite products based on subcritical water micro-foaming was proposed.

Method used

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  • Method for molding biomass composite product based on subcritical water micro-foaming
  • Method for molding biomass composite product based on subcritical water micro-foaming

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Embodiment Construction

[0021] The present invention will be further described in detail below with reference to the drawings and embodiments.

[0022] In this embodiment, the composite system includes: a foaming grade polymer matrix, a biomass material, a nucleating agent, a carbonate protection assistant and other assistants. Among them, the foamed polymer matrix is ​​insoluble in water. Biomass materials include, but are not limited to, long natural fibers, wood flour, rice husks; biomass materials do not need to be dried, and can be pretreated by steam explosion and other pretreatment methods to improve the phase Capacitive. Nucleating agents include, but are not limited to, nano-calcium carbonate and nano-montmorillonite; nucleating agents are used to help heterogeneous nucleation of composite material systems with high melt viscosity, increase gas core density, improve bubble size, and reduce cell merger occur. Carbonate protection additives are used to neutralize the acetic acid formed by acety...

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Abstract

The invention relates to a method for molding a biomass composite product based on subcritical water micro-foaming. The composite system is pre-mixed according to a formula and then added to an eccentric rotor extruder through a feed port. The composite system is plasticized into a melt after a solid delivery stage and a melting stage, wherein water in the biomass material is used as a foaming agent, and the biomass material is used as a carrier of the foaming agent to realize first mixed distribution of the foaming agent at a mixing stage I. The water in the melt is in a subcritical state byproviding pressure at a pressurization stage, the subcritical water is fully dispersed and mixed at a mixing stage II under the action of tensile rheology to form dense nucleuses, finally the subcritical water is triggered to foam at a depressurization stage, and the foam is cooled and molded by a mold. The water in the biomass material is used as a foaming agent, so that the biomass material doesnot need to be dried. The foaming agent is distributed more uniformly after two dispersions, so that the cell distribution is more uniform, and the performance of the molded product is more excellent. The method belongs to the field of polymer material molding.

Description

Technical field [0001] The invention relates to the field of polymer material molding, in particular to a method for molding biomass composite material products based on subcritical water micro-foaming. Background technique [0002] Biomass composite material has mechanical processability, water resistance, corrosion resistance, long service life, wide raw material sources, low cost, and excellent mechanical properties. It is an environmentally friendly recyclable material widely used in various fields. However, the mechanical properties of biomass composite materials are limited by the compatibility of the biomass filler material with the polymer matrix, especially the impact resistance. At the same time, its higher density also limits the application of biomass composite materials. [0003] The current molding method of continuous extrusion foamed biomass composite material usually requires drying the biomass material that has been pretreated, such as steam explosion, and mixing...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B29C48/025B29C48/36B29K105/00B29K105/06
CPCB29K2105/0026B29K2105/0044B29K2105/06B29K2105/16B29K2105/25
Inventor 瞿金平
Owner SOUTH CHINA UNIV OF TECH
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