Organic photoelectric material and preparation method thereof

A technology of organic optoelectronic materials and raw materials, applied in the field of optoelectronic materials, can solve the problems of poor photothermal stability of rare earth complexes, difficulty in realizing industrialization process, and difficulty in large-scale process, so as to improve functional characteristics, solve temperature quenching, Effect of improving electrical conductivity

Inactive Publication Date: 2019-03-08
LANZHOU INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, due to the complex preparation method, poor photothermal stability of rare earth complexes, and the difficulty of large-scale process, it is difficult to realize the industrialization process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] An organic photoelectric material, prepared from the following raw materials in parts by weight: 60 parts of polyurethane acrylate, 15 parts of conductive carbon black modified by surface grafting, 6.5 parts of nano-alumina, rare earth orthophosphate (LaPO 4 ) 10 parts, 6 parts of aminosilane coupling agent, 1.8 parts of light stabilizer 783, 1.4 parts of maleic anhydride graft compatibilizer, wherein, the conductive carbon black of described surface graft modification adopts glycidyl methacrylate Glycidyl methacrylate and 4-vinylpyridine copolymer are modified by surface grafting, and the graft density of glycidyl methacrylate and 4-vinylpyridine copolymer is 0.27 chains / μm 2 , the molar content of 4-vinylpyridine in the graft polymer is 42%;

[0027] Prepare the raw materials according to the above ratio, and then prepare it through the following steps:

[0028] 1) Treat conductive carbon black with hydrogen peroxide to obtain surface hydroxylated conductive carbon b...

Embodiment 2

[0035] An organic photoelectric material, prepared from the following raw materials in parts by weight: 54 parts of polyurethane acrylate, 13.5 parts of conductive carbon black modified by surface grafting, 6.5 parts of nano-alumina, rare earth orthophosphate (GdPO 4 ) 9 parts, 5.5 parts of aminosilane coupling agent, 1.5 parts of light stabilizer 783, 1.5 parts of maleic anhydride graft compatibilizer, wherein, the conductive carbon black of described surface graft modification adopts glycidyl methacrylate Glycidyl methacrylate and 4-vinylpyridine copolymer are modified by surface grafting, and the graft density of glycidyl methacrylate and 4-vinylpyridine copolymer is 0.27 chains / μm 2 , the molar content of 4-vinylpyridine in the graft polymer is 42%;

[0036] Prepare the raw materials according to the above ratio, and then prepare it through the following steps:

[0037] 1) Treat conductive carbon black with hydrogen peroxide to obtain surface hydroxylated conductive carbo...

Embodiment 3

[0044] An organic photoelectric material, prepared from the following raw materials in parts by weight: 65 parts of polyurethane acrylate, 16 parts of conductive carbon black modified by surface grafting, 6.8 parts of nano-alumina, rare earth orthophosphate (LaPO 4 ) 10.8 parts, 6.5 parts of aminosilane coupling agent, 2.2 parts of light stabilizer 783, 1.8 parts of maleic anhydride graft compatibilizer, wherein, the conductive carbon black of described surface graft modification adopts glycidyl methacrylate Glycidyl methacrylate and 4-vinylpyridine copolymer are modified by surface grafting, and the graft density of glycidyl methacrylate and 4-vinylpyridine copolymer is 0.27 chains / μm 2 , the molar content of 4-vinylpyridine in the graft polymer is 42%;

[0045] Prepare the raw materials according to the above ratio, and then prepare it through the following steps:

[0046] 1) Treat conductive carbon black with hydrogen peroxide to obtain surface hydroxylated conductive carb...

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Abstract

The invention discloses an organic photoelectric material and a preparation method thereof, and belongs to the technical field of organic photoelectric materials. The material is prepared from the following raw materials in parts by weight: 54-65 parts of urethane acrylate, 13.5-16 parts of surface grafting modified conductive carbon black, 6.5-6.8 parts of nano-alumina, 9-10.8 parts of rare earthorthophosphate, 5.5-6.5 parts of a coupling agent, 1.5-2.2 parts of a stabilizer and 1.4-1.8 parts of a compatibilizer, wherein the surface grafting modified conductive carbon black is obtained by surface grafting modification of glycidyl methacrylate and a 4-vinylpyridine copolymer. The organic photoelectric material provided by the invention not only has the characteristics of good thermal stability, high luminous efficiency, and easiness in processing and molding, but also has sufficient antibacterial and moisture resistant properties, and can be normally used in a humid environment, thereby greatly satisfying market demands.

Description

technical field [0001] The invention belongs to the technical field of photoelectric materials, and in particular relates to an organic photoelectric material and a preparation method thereof. Background technique [0002] Organic photoelectric materials are a class of photoelectrically active organic materials, usually organic molecules rich in carbon atoms and with large π-conjugated systems, including small molecules and polymers. Organic photoelectric materials have broad application prospects in the fields of organic light-emitting diodes, chip tubes, solar cells, and memories, and thus become one of the most popular research topics in the scientific and industrial circles. However, due to the short life of the device and low efficiency, the industrialization process is far below people's expectations. In addition, there are still many problems unresolved in the process of industrialization. Among them, rare earth complexes have superior optical, electrical, magnetic a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/14C08L51/00C08K9/04C08K9/02C08K9/06C08K3/04C08K3/22
CPCC08K2003/2227C08K2201/001C08K2201/011C08L75/14C08L2201/08C08L51/00C08K9/08C08K9/02C08K9/06C08K3/04C08K3/22
Inventor 韩国才张锂李得科
Owner LANZHOU INST OF TECH
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