Manufacturing method of lithium ion battery high-compaction density pole plate

A technology of lithium ion battery and manufacturing method, which is applied in the field of designing battery pole piece manufacturing, can solve the problems of pole piece becoming hard and flexible, affecting product quality, and uneven surface curling, reducing internal resistance, shortening drying time, volume The effect of increasing specific energy

Inactive Publication Date: 2019-03-15
HUIZHOU WES NEW ENERGY LIMITED
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At the same time, the pole piece of the one-time coating process increases the rolling compound during rolling. When pursuing high compaction density, it is easy to stick to the roll under excessive rolling pressure, the pole piece becomes hard and flexible, the surface is curled and uneven, and even broken. Phenomena such as brittle chips affect product quality

Method used

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  • Manufacturing method of lithium ion battery high-compaction density pole plate
  • Manufacturing method of lithium ion battery high-compaction density pole plate
  • Manufacturing method of lithium ion battery high-compaction density pole plate

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0023] Original technology: positive electrode one-time coating process surface density 21mg / cm 2 , gram capacity 164mAh / g, compaction 4.10g / cm 3 , Design capacity 5542mAh.

[0024] The present invention: the positive electrode is coated twice, and the positive electrode surface density of the first coating is 10.5mg / cm 2 , which is 48% of the designed areal density, and the compacted density is 4.10 g / cm 3 , the surface density of the second coating positive electrode is 11.0 mg / cm 2 , which is 52% of the designed areal density, and the compacted density is 4.20 g / cm 3 , the overall compacted density of the pole piece is 4.20 g / cm 3 , the design capacity is 5647mAh, and the capacity is increased by 1.9% compared with the one-time coating process.

[0025] Table 1 Effect of secondary coating on battery performance

[0026]

[0027] The present invention achieves the purpose of maximum overall compaction and increased capacity by coating the positive electrode twice, a...

Embodiment 2

[0029] Original technology: positive electrode one-time coating process surface density 21mg / cm 2, gram capacity 164mAh / g, compaction 4.10 g / cm 3 ; Negative electrode coating surface density 10.90mg / cm 2 , gram capacity 345mAh / g, compaction 1.67 g / cm 3 , Design capacity 5542mAh.

[0030] The present invention: the positive electrode is coated twice, and the surface density of the positive electrode after one coating is 2.15 mg / cm 2 , which is 10% of the designed areal density, the compacted density is 4.10 g / cm3, and the surface density of the secondary coated positive electrode is 19.35 m g / cm 2 , which is 90% of the designed areal density, and the compacted density is 4.20 g / cm 3 , the overall compacted density of the pole piece is 4.20 g / cm 3 ;

[0031] Negative electrode secondary coating: once coated negative electrode double-sided density 5.45 mg / cm 2 , compacted density 1.67 g / cm 3 , the double-sided density of the second coating is 5.95 mg / cm 2 , compaction 1....

Embodiment 3

[0036] Original technology: positive electrode one-time coating process surface density 21mg / cm 2 , gram capacity 164mAh / g, compaction 4.10 g / cm 3 ; Negative electrode coating surface density 10.90mg / cm 2 , gram capacity 345mAh / g, compaction 1.67 g / cm 3 ; Design capacity 5542mAh.

[0037] In the present invention: multiple coatings on the positive electrode: once coated, the surface density of the positive electrode is 3.23 mg / cm 2 , which is 15% of the designed areal density, the compacted density is 4.10 g / cm3, and the surface density of the secondary coated positive electrode is 8.6 mg / cm 2 , which is 40% of the design area density, and the compacted density is 4.20g / cm 3 , three-time coated positive surface density of 9.76 mg / cm 2 , which is the design surface density of 45%, and the compacted density of 4.20 g / cm 3 , the overall compacted density of the pole piece is 4.20 g / cm 3 ;

[0038] Multiple coatings on the negative electrode: once coated, the density on bo...

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Abstract

The invention discloses a manufacturing method of a lithium ion battery high-compaction density pole plate. The pole plate comprises a metal current collector and a conducting mixed slurry; the conductive mixed slurry is coated on the metal current collector at twice or multiple times, the pole plate is dried and rolled after the first coating, and the plate is dried and then rolled after the second coating, the coating, the drying, and the rolling are orderly performed until the conducting mixed slurry is completely coated. The thickness of the conducting mixed slurry wet coating layer through twice or multiple coating is thinner than that of once coating process, the drying load is educed, the drying time is shortened, the single rolling load is reduced, the roll coating is hard to occurunder high rolling pressure, the coating uniformity and precision are improved, the compaction density of the pole plate is increased, so that the volumetric specific energy is increased, the internal resistance of the pole plate is reduced, the polarization is reduced, the discharge capacity is increased, the battery energy density is increased, the cost is reduced, the flexibility of the pole plate is guaranteed, and the phenomena that the surface is curly uneven and even the plate is broken or crisp are avoided.

Description

technical field [0001] The invention relates to the field of making battery pole pieces, in particular to a method for making high-pressure compacted density pole pieces of lithium-ion batteries. Background technique [0002] Lithium-ion batteries were first successfully developed and commercialized by Sony Corporation of Japan in 1990, with their advantages of high voltage, light weight, large specific energy, less self-discharge, long cycle life, no memory effect, and less environmental pollution. , has been developed rapidly, and the foot replaces secondary rechargeable batteries such as Ni-Nd, Ni-MH, and lead-acid, and becomes an indispensable mobile power source in life. [0003] The manufacturing process of lithium-ion batteries is more complicated, including: pulping, coating, sheeting, winding, assembly, liquid injection, standing, pre-full capacity, high temperature aging and other processes. The coating process is to use a coating machine to uniformly coat the met...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/04H01M4/139H01M10/0525
CPCH01M4/0404H01M4/0435H01M4/139H01M10/0525Y02E60/10
Inventor 宋金涛肖世玲龙梅喻标
Owner HUIZHOU WES NEW ENERGY LIMITED
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