A kind of method that prepares beryllium-containing silicon carbide ceramic fiber by gallium bath
A technology of silicon carbide ceramics and fibers, which is applied in the field of silicon carbide fiber preparation, can solve problems such as insufficient reaction, unevenness, and general stability of finished products, and achieve the effect of non-uniform doping and efficient deoxidation
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Examples
Embodiment 1
[0037] Taking PSCS (molecular weight is 160) and beryllium acetylacetonate as raw materials, the mass proportion of the two (the proportioning described in the following examples is the mass proportion) is beryllium acetylacetonate:PSCS=10:100, 420°C of reaction temperature, The pyrolysis temperature was 500°C, and after holding the reaction for 6 hours, it was dissolved in xylene and filtered, and the filtrate was distilled under reduced pressure at 350°C for 30 minutes to obtain PBCS with a softening point of 195°C and a beryllium content of 1.31wt%. PBCS was added to the melt spinning device and degassed under the protection of high-purity nitrogen, at 258 ° C, 4 × 10 5 Under the pressure of Pa, melt spinning at a speed of 300m / min to obtain a PBCS precursor with a diameter of 20μm; place the above fiber in a non-melting treatment device, and heat it to 185°C at a heating rate of 10°C per hour in an air atmosphere. ℃, keep warm for 2 hours, and cool to room temperature to o...
Embodiment 2
[0041] Other conditions are consistent with embodiment 1; the difference is:
[0042] The PBCS infusible fibers were placed in a metal gallium solution at 80°C; ultrasonicated for 60 min under the condition of 45KHz; taken out to obtain deoxidized PBCS infusible fibers.
[0043] The obtained beryllium-containing silicon carbide fiber has a tensile strength of 2.68 GPa and an elastic modulus of 345 GPa.
Embodiment 3
[0045] Using PCS (molecular weight 300) and beryllium as raw materials, beryllium: PCS = 5:100, the reaction temperature is 430 ° C, the cracking temperature is 490 ° C, and the reaction time is 4h, dissolved in xylene, and filtered, and the filtrate is at 350 ° C. ℃ for 1 hour under reduced pressure to obtain PBCS with a softening point of 202 ℃ and 0.61 wt% beryllium; PBCS was added to the melt spinning device and degassed under the protection of high-purity nitrogen, at 268 ℃, 4.5 × 10 5 Under Pa pressure, melt spinning at a speed of 350 m / min to obtain PBCS precursors with a diameter of 18 μm; the above fibers are placed in an infusible treatment device, and heated to 180 °C at a heating rate of 10 °C per hour in an air atmosphere. ℃, kept for 2 hours, and cooled to room temperature to obtain PBCS non-melting fibers;
[0046] The PBCS infusible fibers were placed in a metal gallium solution at 90°C; treated for 120 min; taken out to obtain deoxidized PBCS infusible fibers;...
PUM
Property | Measurement | Unit |
---|---|---|
strength | aaaaa | aaaaa |
softening point | aaaaa | aaaaa |
softening point | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
- R&D Engineer
- R&D Manager
- IP Professional
- Industry Leading Data Capabilities
- Powerful AI technology
- Patent DNA Extraction
Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.
© 2024 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com