Active bio-based chlorine-containing s-triazine type macromolecular dye preparation method

A macromolecular dye and bio-based technology, which is applied in the field of preparation of active bio-based chlorine-containing s-triazine-type macromolecular dyes, can solve the problems of being unable to be used as a macromolecular colorant and having no color, so as to improve the brightness of the coating, Good heat resistance, deep color effect

Inactive Publication Date: 2019-04-02
安徽清彩科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] Chinese invention patent "A preparation method of dichloro-s-triazine active group modified sodium alginate", (patent application number 201510844044.7) discloses a preparation method of dichloro-s-triazine active group modified sodium alginate , the present invention uses dichloro-s-triazine type active groups to chemically modify the sodi

Method used

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  • Active bio-based chlorine-containing s-triazine type macromolecular dye preparation method
  • Active bio-based chlorine-containing s-triazine type macromolecular dye preparation method
  • Active bio-based chlorine-containing s-triazine type macromolecular dye preparation method

Examples

Experimental program
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Example Embodiment

[0031] Example 1

[0032] First add cyanuric chloride and stir evenly with water, add the prepared 15% soda ash to adjust the pH to about 8.0, and then add the refined small molecule dye precursor formula (1), where the cyanuric chloride and the small molecule dye precursor are moles The ratio is 0.95:1, the temperature is increased to 75-80℃, and the pH=5.0~6.0 is maintained for 4-6h to obtain dichloros-triazine dye monomer. After washing with 80℃ warm water, it is dried at 100℃ Use DMF-H again 2 After O recrystallization and refining, pure dye monomer can be obtained.

[0033] 1g of the dye monomer and 10g of chitosan compound synthesized above are reacted in DMF phase at 50°C for 5h, and then water is added to precipitate and filter to obtain the final product.

Example Embodiment

[0034] Example 2

[0035] First add cyanuric chloride and stir evenly with water, add the prepared 15% soda ash water to adjust the pH to about 8.0, and then add the refined small molecule dye precursor formula (2), where the cyanuric chloride and the small molecule dye precursor are moles The ratio is 0.95:1, the temperature is increased to 75-80℃, and the pH=5.0~6.0 is maintained for 4-6h to obtain dichloros-triazine dye monomer. After washing with 80℃ warm water, it is dried at 100℃ Use DMF-H again 2 After O recrystallization and refining, pure dye monomer can be obtained.

[0036] Combine the 1g dye monomer synthesized above and 10gH 2 N-PEG-NH 2 (α,ω-diaminopolyethylene glycol amine, molecular weight 1000), react in the water phase at 50°C for 10h, then add water to precipitate and filter to obtain the final product.

Example Embodiment

[0037] Example 3

[0038] First add cyanuric chloride and stir evenly with water, add the prepared 15% soda ash to adjust the pH to about 8.0, and then add the refined small molecule dye precursor formula (7), where the cyanuric chloride and the small molecule dye precursor are moles The ratio is 0.95:1, the temperature is increased to 75-80℃, and the pH=5.0~6.0 is maintained for 4-6h to obtain dichloros-triazine dye monomer. After washing with 80℃ warm water, it is dried at 100℃ Use DMF-H again 2 After O recrystallization and refining, pure dye monomer can be obtained.

[0039] Combine the synthesized 1g fluorescent dye monomer and 10gH 2 N-PEG-NH 2 (α,ω-diaminopolyethylene glycol amine, molecular weight 2000), reacted in the water phase at 50°C for 10h, then filtered and dried to obtain the final product.

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Abstract

The invention discloses an active bio-based chlorine-containing s-triazine type macromolecular dye preparation method, and relates to the technical field of new material preparation. The active bio-based chlorine-containing s-triazine type macromolecular dye preparation method comprises: carrying out a reaction on cyanuric chloride and a small molecule dye precursor in a DMF phase or an aqueous phase, filtering the slurry after completing the reaction, washing the filter cake with warm water, drying, re-crystallizing to remove excess salt so as to obtain a pure dye monomer, carrying out a reaction on the obtained dye monomer and a macromolecular bio-based material in DMF or water, precipitating the slurry after completing the reaction, filtering, washing the filter cake with warm water, and drying. According to the present invention, the dichloro s-triazine type dye monomer is prepared from the cyanuric chloride and the small molecule dye precursor, and the active bio-based chlorine-containing s-triazine type macromolecular dye is prepared from the dichloro s-triazine type dye monomer and the molecular bio-based material.

Description

technical field [0001] The invention belongs to the technical field of preparation of new materials, and in particular relates to a preparation method of an active bio-based chlorine-containing s-triazine type macromolecular dye. Background technique [0002] Small molecule dyes are widely used in textiles, leather, fur, paper, plastics, rubber, coatings, inks, food colorings, cosmetics, etc., but there are still many shortcomings, such as the toxicity of small molecules, poor fastness, and Inadequate solvent resistance, migration resistance and heat resistance severely limit the application of small molecule dyes in food, ink, paint, fiber, plastic and other coloring materials. In order to meet the market's demand for high efficiency and safety, polymer dyes have been developed. Polymer dyes are new colored polymers that introduce chromophoric groups into the main chain or side chains of polymers through chemical reactions. The combined polymer dye not only has the high s...

Claims

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Application Information

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IPC IPC(8): C09B69/10C09K11/06
Inventor 李军配陈军吴祥松杨文东李怡霞项羽
Owner 安徽清彩科技有限公司
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