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Deposition of lithium fluoride on lithium metal surface and lithium secondary battery using same

A secondary battery and lithium metal technology, applied in the field of lithium metal, can solve problems that have not yet been raised

Pending Publication Date: 2019-04-02
LG ENERGY SOLUTION LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

That is, no technique has been proposed to utilize LiF to coat the surface of Li metal by deposition

Method used

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  • Deposition of lithium fluoride on lithium metal surface and lithium secondary battery using same
  • Deposition of lithium fluoride on lithium metal surface and lithium secondary battery using same
  • Deposition of lithium fluoride on lithium metal surface and lithium secondary battery using same

Examples

Experimental program
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Effect test

experiment example 1

[0048] Experimental Example 1: Electrochemical charge and discharge performance

[0049] The charge capacity and discharge capacity were measured during the charge and discharge process according to the examples and comparative examples. The results are shown in figure 2 middle. The charge-discharge efficiency at this time is shown in image 3 middle.

[0050] refer to figure 2 , the cycle performance of the example and the cycle performance of the comparative example were similar to each other in the early cycle; however, the cycle performance of the example and the cycle performance of the comparative example were very different from each other after 50 cycles. It can be seen that the examples exhibit better performance than the comparative examples, and the difference in performance between the examples and the comparative examples becomes larger as the number of cycles increases.

[0051] refer to image 3 , it can be seen that even in the early cycle, the example ...

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Abstract

When a lithium metal is used to increase a capacity of a lithium secondary battery, reversibility for charging and discharging is reduced by a dendrite or the like. The lithium metal on which LiF is deposited according to the present invention has high stability against reduction of the reversibility and thus has high reversibility for charging and discharging. In addition, when LiF is deposited,there are advantages in that the lithium metal which is a cathode in the prior art is not consumed itself and the shape of the lithium metal electrode itself is not greatly changed.

Description

technical field [0001] The present invention relates to a negative electrode of a lithium metal secondary battery and a method of manufacturing the negative electrode, more particularly to a method of depositing lithium fluoride (LiF) on the surface of lithium metal used as a negative electrode of a lithium metal secondary battery, and to a process by Lithium metal produced by the method, and a negative electrode and a lithium metal secondary battery using the lithium metal. Background technique [0002] With recent weight reduction and performance improvement of portable devices such as smartphones, laptop computers, tablet computers, and portable game machines, demands on secondary batteries used as their driving sources have changed. In the past, nickel-cadmium batteries, nickel-metal hydride batteries, and nickel-zinc batteries were used. Currently, lithium secondary batteries having high operating voltage and high energy density per unit weight are being used most. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01M4/1395H01M4/04H01M4/134H01M4/02
CPCH01M4/0421H01M4/134H01M4/1395Y02E60/10H01M4/0423H01M4/0428H01M2004/026H01M2004/027H01M4/136H01M4/1397H01M10/0525
Inventor 蔡午秉禹相昱崔希源金银卿
Owner LG ENERGY SOLUTION LTD