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Deformed magnesium alloy with high strength and easy corrosion and preparation method thereof

A deformed magnesium alloy, easy to corrode technology, applied in the field of magnesium alloy materials

Inactive Publication Date: 2019-04-16
山东银光钰源轻金属精密成型有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are few literatures reporting that Ni is added as an alloying element to study its effect on the mechanical properties and microstructure properties of magnesium alloys.

Method used

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  • Deformed magnesium alloy with high strength and easy corrosion and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] A high-strength and easily corroded deformed magnesium alloy and a preparation method thereof are prepared from the following raw materials by mass percentage:

[0017] 94.5%Mg, 4.0%Zn, 0.7%Ni and 0.8% impurities;

[0018] Specifically, it is realized through the following steps:

[0019] Step 1: Preheating the magnesium ingots, zinc ingots and magnesium-nickel master alloys according to mass percentage respectively to 150°C;

[0020] Step 2: Put the preheated magnesium ingot in the crucible and heat it to a molten state, and inject CO into the crucible during the heating and melting process 2 and SF 6 Mixed protective gas, where CO 2 and SF 6 The volume ratio of the magnesium ingot is 99:1, and the magnesium ingot is completely melted and left to stand for 30 minutes;

[0021] Step 3: When the temperature rises to 720°C, add the preheated zinc ingot and magnesium-nickel master alloy in turn, and keep stirring during the period. After it is completely melted, add t...

Embodiment 2

[0024] A high-strength and easily corroded deformed magnesium alloy and a preparation method thereof are prepared from the following raw materials by mass percentage:

[0025] 93.6%Mg, 5.0%Zn, 1.2%Ni and 0.2% impurities;

[0026] Specifically, it is realized through the following steps:

[0027] Step 1: Preheating magnesium ingots, zinc ingots and magnesium-nickel master alloys according to mass percentages to 180°C respectively;

[0028] Step 2: Put the preheated magnesium ingot in the crucible and heat it to a molten state, and inject CO into the crucible during the heating and melting process 2 and SF 6 Mixed protective gas, where CO 2 and SF 6 The volume ratio of the magnesium ingot is 99:1, and the magnesium ingot is completely melted and allowed to stand for 45 minutes;

[0029] Step 3: When the temperature rises to 740°C, add the preheated zinc ingot and magnesium-nickel master alloy in turn, and keep stirring during the period. After it is completely melted, add t...

Embodiment 3

[0032] Table 1 shows the mechanical properties and corrosion rates of the high-strength and easily corrodible wrought magnesium alloys prepared in Example 1 and Example 2. In the measurement of corrosion rate, a sample block of 50×50×25 mm was cut and immersed in a 5% NaCl solution for corrosion test. The corrosion time was 1 day, and the water temperature and room temperature were both at room temperature.

[0033]

[0034] Table 1

[0035] To sum up, the tensile strength of the wrought magnesium alloy produced by this process can reach 235-250MPa at room temperature, the yield strength can reach 150-170MPa, the elongation can reach 13-15%, and the corrosion rate in 5% NaCl solution at room temperature can reach 30-45mg / cm 2 / d.

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Abstract

The invention discloses a deformed magnesium alloy with high strength and easy corrosion and a preparation method thereof. The deformed magnesium alloy is prepared from the following raw materials inpercentage by mass: 92.5-96.2% of Mg, 3.5-5.0% of Zn, 0.3-1.5% of Ni and less than 1.0% of impurities. The preparation method specifically comprises the following steps that magnesium ingots, zinc ingots and magnesium-nickel intermediate alloys are correspondingly preheated according to the mass percent; the preheated magnesium ingots are placed in a crucible and heated to a molten state, and standing is carried out; the preheated zinc ingots and magnesium-nickel intermediate alloys are added into the molten magnesium ingots, a refining agent is added after the preheated zinc ingots and magnesium-nickel intermediate alloys are completely molten, refining is carried out by manually stirring, then argon is used for removing surface slag; standing and heating are carried out after a power failure to obtain an alloy casting solution, and casting is carried out in a die to obtain a casting blank; and the blank is put into a heating furnace for preheating and extrusion to obtain the deformedmagnesium alloy with the high strength and easy corrosion.

Description

technical field [0001] The invention belongs to the technical field of magnesium alloy materials, and in particular relates to a high-strength and easily corroded deformed magnesium alloy and a preparation method thereof. Background technique [0002] In the prior art, magnesium alloy is the metal material with the lightest structure in engineering applications, and has the advantages of high specific strength, specific stiffness, easy recycling, excellent casting performance, and machining performance. [0003] The influence of Ni element on magnesium alloy is mainly manifested in corrosion resistance, so Ni element is removed as impurity element. However, there are few literatures reporting that Ni is added as an alloying element to study its effect on the mechanical properties and microstructure properties of magnesium alloys. The mechanical properties of magnesium alloys, especially heat resistance, can be improved by adding an appropriate amount of Ni element; in addit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C23/04C22C1/03C22F1/06
CPCC22C23/04C22C1/03C22F1/06
Inventor 王晓虎王绍著王前进蒋孝平吴永霞王光政杨永强王飞
Owner 山东银光钰源轻金属精密成型有限公司