A method for online monitoring of odor concentration

A concentration and odor technology, which is used in measurement devices, analysis of gas mixtures, standard gas analyzers, etc., can solve the problems of abnormally complex composition of odor pollutants, distortion of response spectrum of electronic nose method, and inapplicability of pattern recognition algorithms. Achieve accurate and reliable data results, simple and convenient maintenance, and equipment that is resistant to leather

Active Publication Date: 2021-08-03
浙江省环境监测中心
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Problems solved by technology

Judging from the pilot situation, the electronic nose method cannot be applied to fine chemical industries such as dyes, pharmaceutical intermediates, and pesticides. The interference of a variety of gases with different properties on the electronic nose sensor array, coupled with the low smell threshold of many pollutants, lead to a series of problems such as distortion of the response spectrum of the electronic nose method, and the inapplicability of the set pattern recognition algorithm.

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  • A method for online monitoring of odor concentration
  • A method for online monitoring of odor concentration
  • A method for online monitoring of odor concentration

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Embodiment example

[0051] A total of 47 monitoring points were selected from several adjacent enterprises in a certain place. The online mass spectrometer monitored all the points once every 2 hours, continuously monitored 24 hours a day, and arranged artificial odor concentration monitoring at the same time. An effective odor monitoring model for mass spectrometry data, and the model predicts the odor concentration of the measured gas, which specifically includes the following steps:

[0052] (1) The online mass spectrometer does not have a pretreatment separation system such as a chromatographic column, and the measured gas directly enters the online mass spectrometer for online monitoring.

[0053] (2) Carry out continuous sampling of the measured gas under a certain working condition, use an online mass spectrometer to perform full-scan analysis on the measured gas, record the full-scan mass spectrum, and obtain each ion and its ion intensity; use three-point comparison simultaneously Manual...

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Abstract

The invention relates to the technical field of on-line monitoring, and discloses an on-line monitoring method of odor concentration, comprising: the gas sample directly enters an online mass spectrometer without going through a pretreatment system such as a chromatographic column, and performs a full scan in the range of a mass-to-charge ratio of 1 to 200 m / z Analyze and obtain mass spectrometry data, and simultaneously use manual monitoring methods to obtain odor concentration; repeat the above steps to establish a database of mass spectrometry data-odor concentration; build an odor monitoring model, and divide the data samples in the database into training sets and test sets. The monitoring model is trained, the characteristic vector of the mass spectrometry data is used as the input, and the corresponding odor concentration is output; the gas to be measured is scanned and analyzed to obtain the mass spectrometry data, which is input to the trained odor monitoring model to obtain the corresponding odor concentration. The online monitoring method for odor concentration of the present invention has accurate and reliable monitoring results, high monitoring efficiency, reliable system operation, simple and convenient maintenance, and wide applicability, and can be generally applied to various industrial source odor concentration monitoring occasions.

Description

technical field [0001] The invention relates to the technical field of on-line monitoring, in particular to an on-line monitoring method of odor concentration. Background technique [0002] Odor pollution has become one of the focuses and urgent problems to be solved by governments at all levels and society because of the mental and physical harm it causes to the human body. There are more than 4,000 pollutants that can cause odor pollution. According to their chemical properties, they can be divided into inorganic odor pollutants and organic volatile odor pollutants. The former such as hydrogen sulfide, carbon disulfide, ammonia, etc., the latter such as Volatile organic pollutants such as trimethylamine, styrene, and benzene. Odor pollution sources mainly include domestic sources and industrial sources. Among them, the odor pollution caused by industrial sources, especially chemical industry parks, has a large range of influence, many pollution sources, and the discharge ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): G01N33/00
CPCG01N33/0006
Inventor 冯元群林文浩高翔王静孙晓慧楼振纲戴争博刘劲松
Owner 浙江省环境监测中心
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