Process method and process system combined with hydrogenation and catalytic cracking

A catalytic cracking and catalytic cracking gasoline technology, applied in the field of hydrocarbon oil processing, can solve the problems of gasoline cracking, gasoline yield loss, gasoline condensation and coking, etc., and achieve the effect of high-efficiency conversion and high light oil yield

Active Publication Date: 2021-05-14
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0009] CN1388219A reduces the content of gasoline olefins by using the hydrogen donor components with a distillation range less than 400°C to react with gasoline, but when it is necessary to reduce the gasoline olefins and at the same time lighten the hydrogen donor, it cannot be balanced
However, since gasoline enters one of the risers separately to reduce olefins, there is a regenerated catalytic cracking catalyst with strong gasoline contact cracking ability, which leads to more gasoline cracking, and there is no external hydrogen donor to provide hydrogen source for gasoline, and gasoline needs to obtain hydrogen from itself. Part of the problem of gasoline condensation and coking is more, resulting in a large loss of gasoline yield, and because there is no hydrogen donor and gasoline fed together, the effect of reducing olefins is not good

Method used

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  • Process method and process system combined with hydrogenation and catalytic cracking
  • Process method and process system combined with hydrogenation and catalytic cracking

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specific Embodiment approach 1

[0054] Preferred embodiment 1: Combine all of the catalytically cracked heavy cycle oil from step (1) with all of the catalytically cracked light cycle oil from step (3) and all of the catalytically cracked heavy cycle oil from step (3) The cycle oil is introduced into the hydrogenation unit in step (2) for hydrogenation reaction.

specific Embodiment approach 2

[0055] Preferred embodiment 2: all the catalytic cracking heavy cycle oil from step (1), all the catalytic cracking light cycle oil from step (1), and all the catalytic cracking light cycle oil from step (3) The cycle oil and all the catalytically cracked heavy cycle oil from step (3) are introduced into the hydrogenation unit of step (2) for hydrogenation reaction.

[0056] In the aforementioned preferred embodiment 1, the catalytically cracked light cycle oil from step (1) and the low-olefin catalytically cracked gasoline from step (3) are taken out of the unit as diesel products and gasoline products, respectively.

[0057] Preferably, the present invention can also introduce all the catalytically cracked light cycle oil from step (1) into a hydrogenation unit for hydrogenation reaction, and use the low-olefin catalytically cracked gasoline from step (3) as gasoline The product comes out of the device.

[0058] Preferably, the catalytic cracking oil slurry obtained in step...

Embodiment 1

[0112] The residual hydrogenated tail oil A is used as the raw material, and its properties are shown in Table 1. use figure 1 The process flow shown is carried out.

[0113] Residue hydrogenation tail oil A enters the first riser of the double riser medium-sized catalytic cracking test device, and contacts with water vapor and the catalyst from the regenerator to perform the first catalytic cracking reaction. The conditions of the first catalytic cracking reaction are: reaction temperature The temperature is 480°C, the agent-to-oil weight ratio is 6, and the residence time in the first riser is 1.5 seconds. After the reaction, oil and gas are separated to separate dry gas, liquefied gas, first riser catalytic cracking gasoline, first riser catalytic cracking light cycle oil, first riser catalytic cracking heavy cycle oil and first riser catalytic cracking oil pulp. The first riser catalytic cracking light cycle oil is all used as diesel products. All the first riser catal...

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Abstract

The invention relates to the field of heavy oil processing, and discloses a combined hydrogenation and catalytic cracking process and system, including: (1) introducing catalytic cracking raw oil into the first catalytic cracking riser to perform the first catalytic cracking reaction, separating the catalytic cracking The product of the cracking reaction; (2) introducing the catalytic cracking heavy cycle oil, optionally at least part of the catalytic cracking light cycle oil, into the hydrogenation unit for hydrogenation reaction, and separating the hydrogenation reaction product to obtain the hydrogenation cycle oil; (3 ) introducing a part of the hydrogenated cycle oil into the lower part of the second riser of the catalytic cracking for catalytic cracking reaction; introducing the gasoline fraction and another part of the hydrogenated cycle oil into the upper part of the second riser of the catalytic cracking and combining with the catalyst from the lower part of the second riser Carry out catalytic cracking reaction with oil and gas. The method provided by the invention can efficiently convert heavy oil and produce catalytic gasoline with low olefins and catalytic diesel with a higher cetane number, and can flexibly adjust the ratio of diesel to gasoline and has high yield of light oil.

Description

technical field [0001] The invention relates to the field of hydrocarbon oil processing, in particular to a hydrogenation and catalytic cracking combined process method and a hydrogenation and catalytic cracking combined process system. Background technique [0002] At present, the world is facing the trend of crude oil becoming heavier and worse, while people's demand for heavy fuel oil is gradually decreasing, while the demand for light oil is greatly increasing. Therefore, refiners are pursuing the maximum conversion of residual oil. [0003] Among the various methods of lightening residual oil, high-quality paraffin-based heavy oil can be directly subjected to catalytic cracking to produce light oil products. Inferior high-sulfur and high-residual carbon residue oil is first subjected to hydrotreating, and the hydrogenated tail oil is then processed by catalytic cracking. The residue oil is hydrotreated to remove impurities such as metals, sulfur, nitrogen, etc., and t...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C10G69/04
Inventor 牛传峰张执刚戴立顺崔琰杨清河刘涛邵志才邓中活施瑢聂鑫鹏
Owner CHINA PETROLEUM & CHEM CORP
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