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Preparation technology of boron-containing high molecular slow-release fertilizer

A preparation process and polymer technology, applied in fertilization devices, fertilizer mixtures, applications, etc., can solve the problems that the fertilizer effect of trace elements cannot be exerted normally, the coating material is difficult to degrade, and the price is expensive.

Inactive Publication Date: 2019-05-28
曾勇
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

At present, the domestic research on slow-release fertilizers has made some progress, but there are still some problems, mainly as follows: (1) The price of slow-release fertilizers is generally high, which limits their popularization and application. Currently, they are mainly used for flowers, Markets such as lawns and golf courses; (2) Most of the slow-release fertilizers currently used in the market are coated slow-release fertilizers. This fertilizer is not only expensive, but most of the coating materials are difficult to degrade, and remain in the soil after the fertilizer nutrients are completely released. (3) There are 17 types of nutrients necessary for plant growth, including macronutrients and micronutrients, but the nutrients contained in slow-release fertilizers are single, and most reports are Nitrogen-containing slow-release fertilizers cannot meet the needs of crops for phosphorus, potassium and trace elements other than nitrogen
[0003] Although micro-fertilizers have developed rapidly in recent years, there are also some problems in the application: (1) trace elements exist in the form of metal ions in trace element compound fertilizers, which are easily solidified by the soil, making the fertilizer effect of trace elements ineffective. (2) Water-soluble metal chelates can be used as micro-fertilizers to obtain obvious yield-increasing effects, but the high cost limits their application

Method used

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  • Preparation technology of boron-containing high molecular slow-release fertilizer

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Embodiment Construction

[0018] A preparation process for boron-containing polymer slow-release fertilizer, comprising the following steps,

[0019] (1) Add 2.06g of boric acid and 1.87g of potassium hydroxide into a round bottom flask, react at 90°C for 3h to obtain product A, and cool down the system for later use;

[0020] (2) Add a certain proportion of urea and formaldehyde into the three-necked flask, adjust the pH of the system to 8 with 5% KOH aqueous solution, stir and react at T1 temperature for 80 minutes (addition reaction), adjust the temperature of the water bath to 60°C and continue the reaction for 40 minutes (polycondensation reaction); add to the system of step (1), adjust the temperature to T3 (gel temperature), react under stirring until the system starts to become viscous and stop the reaction, and dry at T4 temperature after granulation.

[0021] The addition reaction in step (2) is that formaldehyde and urea react under alkaline conditions to generate methylol urea:

[0022] ...

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Abstract

The invention provides a preparation technology of boron-containing high molecular slow-release fertilizer and belongs to the technical field of fertilizer preparation. The preparation technology comprises the following steps: (1) adding 2.06g of boric aid and 1.87g of potassium hydroxide into a round bottomed flask; reacting at 90 DEG C for 3h to obtain a product A; cooling a system for later use; (2) adding a certain ratio of urea and formaldehyde into a three-necked flask and adjusting the pH (Potential of Hydrogen) of the system to be 8 through a 5 percent KOH water solution; stirring at the temperature T1 and reacting for 80min (through carrying out addition reaction); adjusting the temperature of a water-bath pot to be 60 DEG C and continually reacting for 40min (through carrying outcondensation polymerization reaction); adding a product into the system of step (1) and adjusting the temperature to be T3 (gelation temperature); reacting under stirring until the system becomes sticky, and stopping reaction; after granulating, drying at the temperature T4. The slow-release fertilizer prepared by the preparation method is more reliable.

Description

technical field [0001] The invention relates to the technical field of fertilizer preparation, in particular to a preparation process of boron-containing polymer slow-release fertilizer. Background technique [0002] Looking at the development of fertilizers at home and abroad, it can be seen that slow-release fertilizers are ideal fertilizers for developing sustainable ecological agriculture, improving fertilizer utilization rates and causing less environmental pollution. At present, the domestic research on slow-release fertilizers has made some progress, but there are still some problems, mainly as follows: (1) The price of slow-release fertilizers is generally high, which limits their popularization and application. Currently, they are mainly used for flowers, Markets such as lawns and golf courses; (2) Most of the slow-release fertilizers currently used in the market are coated slow-release fertilizers. This fertilizer is not only expensive, but most of the coating mate...

Claims

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Application Information

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IPC IPC(8): C05G3/00
Inventor 曾勇
Owner 曾勇
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