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Biodegradable organic polymer nitrogen fertilizer and preparation method thereof

A technology of organic polymers and nitrogen fertilizers, applied in fertilization devices, fertilizer mixtures, applications, etc., can solve the problems of reduced nutrient content, pollution, and increased production costs of chemical fertilizers, and achieve improved utilization, reduced fixed amounts, and excellent slow and controlled release. performance effect

Active Publication Date: 2017-05-17
ZHONGBEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Although the slow and controlled release performance of chemical fertilizers can be endowed by coating methods, it also brings the following problems: it belongs to secondary processing, which leads to increased production costs; the nutrient content in chemical fertilizers is reduced, and contains components that cannot be absorbed by crops; The coating residues in the soil will cause pollution

Method used

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  • Biodegradable organic polymer nitrogen fertilizer and preparation method thereof
  • Biodegradable organic polymer nitrogen fertilizer and preparation method thereof
  • Biodegradable organic polymer nitrogen fertilizer and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Biodegradable organic polymer nitrogen fertilizer, the preparation method of which is:

[0037] Add 1.00mol methyl carbamate, 0.10mol urea and 0.06mol catalyst potassium carbonate to the reaction vessel, react at 160°C for 6h, then add 0.33mol crosslinking agent triisocyanate, stir, when the reaction solution becomes viscous, Granulate and dry to obtain biodegradable organic high molecular nitrogen fertilizer.

[0038] The cold water solubility of the obtained biodegradable organic polymer nitrogen fertilizer is 2%, and the hot water solubility is 32%.

Embodiment 2

[0040] Biodegradable organic polymer nitrogen fertilizer, the preparation method of which is:

[0041] Add 1.00mol methyl carbamate, 0.10mol urea and 0.06mol catalyst potassium carbonate to the reaction vessel, react at 160°C for 6h, then add 0.026mol crosslinking agent triisocyanate, stir, when the reaction solution becomes viscous, Granulate and dry to obtain biodegradable organic high molecular nitrogen fertilizer.

[0042] The nitrogen content of the obtained biodegradable organic polymer nitrogen fertilizer is 27.76%, the cold water solubility is 20%, and the hot water solubility is 75%.

Embodiment 3

[0044] Biodegradable organic polymer nitrogen fertilizer, the preparation method of which is:

[0045] Add 1.00mol methyl carbamate, 0.10mol urea and 0.06mol catalyst potassium carbonate to the reaction vessel, react at 160°C for 6h, then add 0.02mol crosslinking agent triisocyanate, stir, when the reaction solution becomes viscous, Granulate and dry to obtain biodegradable organic high molecular nitrogen fertilizer.

[0046] The nitrogen content of the obtained biodegradable organic polymer nitrogen fertilizer is 28.25%, the solubility in cold water is 30%, and the solubility in hot water is 81%.

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Abstract

The invention relates to the field of slow and controlled release of fertilizers, and specifically is a biodegradable organic polymeric nitrogen fertilizer and a preparation method therefor. Compared with existing fertilizer capable of slow and controlled release, the nitrogen fertilizer of the invention has the following advantages: (1) nutrient elements of carbon, hydrogen, oxygen and nitrogen of molecules of the nitrogen fertilizer of the invention are firmly connected to a same polymer chain by chemical bonds, thereby providing the nitrogen fertilizer with excellent properties of slow and controlled release. Total nitrogen release in water and soil shows an obvious rising trend within 1 to 20 days, and nutrient release is relatively slower within 20 to 90 days, thus greatly improving the utilization rate of the nitrogen fertilizer. and (2)After being applied in the soil, the biodegradable organic polymeric nitrogen fertilizer of the invention, under the effect of soil microbes and the water, gradually degrades into small-molecule nutrients for absorption and utilization by plants, so that the amount of nutrient elements of nitrogen fixed in the soil is reduced, and non-absorbable harmful substances are not left in the soil. The Biodegradable organic polymeric nitrogen fertilizer is a novel fertilizer that meets the green environmental protection requirements.

Description

technical field [0001] The invention relates to the field of slow and controlled release chemical fertilizers, in particular to a biodegradable organic high molecular nitrogen fertilizer and a preparation method thereof. Background technique [0002] Nitrogen is a nutrient element of special importance in the process of plant growth. Because the nitrogen fertility of the world's soil is not high, nitrogen is not easy to accumulate in the soil, and modern intensive agriculture has caused excessive loss of soil organic matter and nitrogen. In most cases, the increase in yield per unit of nitrogen is higher than that of phosphorus and potassium nutrients. Therefore, since the 20th century, the production of nitrogen fertilizer has been playing a pivotal role both at home and abroad. According to the survey, more than 80% of the arable land in our country is deficient in nitrogen, but at the same time the average utilization rate of nitrogen fertilizer in our country is only ab...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C05G3/08C05G3/90
Inventor 刘亚青赵贵哲郝率群程冬冬向阳
Owner ZHONGBEI UNIV
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