Graphene material directional arrangement and silica gel pad composite molding method and product

A technology of directional arrangement and composite molding, applied in the field of thermal interface materials, can solve the problems of easy falling off and insufficient strength, and achieve the effect of good heat dissipation function, firm connection, and easy large-scale industrial production.

Active Publication Date: 2019-08-23
中科热科技江苏有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] Aiming at the above-mentioned problems in the prior art, the present invention provides a method for directional arrangement of graphene materials and composite molding with silica gel pads and heat-conducting silica gel gasket products. Wetting dispersion and surface modification of bulk materials, the obtained graphene dispersion is sprayed or coated on the upper surface of the substrate pad, and with the volatilization of organic diluent solvents, graphene can achieve good orientation and realize thermal pad Excellent thermal conductivity and heat uniformity; at the same time, during the high-temperature vulcanization process, the coupling agent containing unsaturated groups adsorbed on the surface of graphene can produce cross-linking reaction with hydrogen-containing silicone oil and vinyl on the surface of the gasket, so as to realize the relationship between graphene materials and The firm connection of the gasket solves the problem of insufficient strength and easy to produce defects such as falling off in the process of combining the existing graphene with the thermally conductive silicone gasket

Method used

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  • Graphene material directional arrangement and silica gel pad composite molding method and product

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Embodiment 1

[0042] Graphene material directional arrangement of the present invention and the heat-conducting silica gel gasket product that is compositely formed with silica gel pad utilize the following components in the preparation process: (A) 15 parts by weight of methyl vinyl silicone oil, and the viscosity is 400mPa·s; ( B) 3 parts by weight of hydrogen-containing silicone oil, 0.1% of hydrogen content; (C) 4 parts by weight of γ-methacryloxypropyl trimethoxysilane coupling agent; (D) concentration is 1.5 parts by weight of platinum catalyst of 2000ppm Parts; (E) 500 parts by weight of spherical heat-conducting alumina powder fillers, including alumina powders of large and small particle sizes, the particle size of the large particle size alumina powder is 90 μm, and the particle size of the small particle size alumina powder is 5 μm , wherein the ratio of large and small particle size alumina powder is 300 parts by weight: 200 parts by weight; (F) 150 parts by weight of organic dil...

Embodiment 2

[0044] Graphene material directional arrangement of the present invention and the heat-conducting silica gel gasket product that is compounded with silica gel mat molding utilize in the preparation process the following components: (A) 20 parts by weight of methyl vinyl silicone oil, viscosity is 1000mPa·s; ( B) 3 parts by weight of hydrogen-containing silicone oil, 0.15% hydrogen content; (C) 4 parts by weight of vinyltrimethoxysilane coupling agent; (D) 1.5 parts by weight of platinum catalyst with a concentration of 2000ppm; (E) spherical thermal oxidation 500 parts by weight of aluminum powder filler, including alumina powders with large and small particle sizes, the particle size of the large particle size alumina powder is 95 μm, and the particle size of the small particle size alumina powder is 4 μm. The ratio of powder is 300 parts by weight: 200 parts by weight; (F) 150 parts by weight of organic volatile diluting solvent n-hexane; (G) 30 parts by weight of graphene, p...

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Abstract

The invention provides a graphene material directional arrangement and silica gel pad composite molding method and a thermally conductive silica gel pad product. A graphene powder material is wetted and dispersed and surface modified by adopting an organic volatilizable dilution solvent and a coupling agent. The obtained graphene dispersion liquid is added to the upper surface of a substrate pad in a spraying or coating mode. With volatilization of the organic dilution solvent, graphene can realize good directional arrangement, and excellent thermal conductivity and soaking performance of thethermally conductive pad are realized. Meanwhile, in a high-temperature vulcanization process, the coupling agent containing unsaturated groups adsorbed on the surface of graphene can generate crosslinking reaction with hydrogen-containing silicone oil and vinyl on the surface of the pad, thereby realizing firm connection between the graphene material and the raphene material directional arrangement and silica gel pad composite molding method and pad and solving the problems of defects such as insufficient strength, easy occurrence of falling off and the like in the bonding process of the graphene and the thermally conductive silica gel pad in the prior art.

Description

technical field [0001] The invention belongs to the field of thermal interface materials, and relates to a heat-conducting silica gel pad, in particular to a method for directional arrangement of graphene materials and composite molding with a silica gel pad, and a heat-conducting silica gel pad product. Background technique [0002] In the field of electronic products, with the increasing integration of electronic components, heat dissipation has become one of the bottlenecks restricting the performance of electronic products. If the temperature of electronic equipment is too high, it will lead to a significant decline in operational stability and service life. The heat generated by electronic components is often concentrated in a very limited area, and it is easy to form local hot spots. The key difficulty in heat dissipation technology is how to extract this part of the heat from the limited space, and there is an urgent need for high-performance heat-conducting materials....

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L83/07C08L83/05C08K13/06C08K9/06C08K7/18C08K3/04C08K5/5425B29C35/02
CPCB29C35/02C08K2201/003C08K2201/014C08L83/04C08L2205/025C08K13/06C08K9/06C08K7/18C08K3/042C08K5/5425
Inventor 刘斌淮秀兰李勋锋胡玄烨周敬之
Owner 中科热科技江苏有限公司
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