A kind of heterocyclic organic optoelectronic material and its preparation method and application

A technology of organic optoelectronic materials and heterocycles, applied in the direction of luminescent materials, organic chemistry, chemical instruments and methods, etc., can solve the problems of unsatisfactory device driving voltage luminous efficiency, etc., and achieve excellent electron transport characteristics, good electron transport capabilities, thermal stable good effect

Active Publication Date: 2021-02-12
SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the influence of material properties, reflected on the device, the driving voltage or luminous efficiency of the device is not ideal

Method used

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  • A kind of heterocyclic organic optoelectronic material and its preparation method and application
  • A kind of heterocyclic organic optoelectronic material and its preparation method and application
  • A kind of heterocyclic organic optoelectronic material and its preparation method and application

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0068] Embodiment 1: Compound 1 and its synthetic method

[0069] The structure of compound 1 is as follows:

[0070] The synthetic method of above-mentioned compound 1, according to following synthetic method:

[0071] Add 0.2mol of raw material 1a to a 2L three-necked flask, then measure 400.00ml of DMF, dissolve the raw material under mechanical stirring, slowly add 0.3mol of sodium hydride, and start to drop the DMF solution of raw material 1b (0.2mol +200mlDMF) The reaction temperature was 5°C, the reaction time was 2 hours, the liquid phase followed the reaction of the raw materials, and the reaction was terminated.

[0072] After the reaction is over, dilute the reaction solution with 1.5L of dichloroethane and slowly pour it into 3L of water, let it stand, separate the liquids, extract the water phase with 1L of dichloroethane, combine the organic phases, wash with water until neutral, and use After drying 200g of anhydrous sodium sulfate, distill under reduced pre...

Embodiment 2

[0080] Embodiment 2: Compound 2 and its synthetic method

[0081] The structure of compound 2 is as follows:

[0082] The synthetic method of above-mentioned compound 2, according to following synthetic method:

[0083] Add 0.2 mol of raw material 2a to a 2L three-necked flask, then measure 480.00ml of DMF, and dissolve the raw material under mechanical stirring, slowly add 0.4 mol of sodium hydride, and dropwise add the DMF solution of raw material 2b (0.22mol+135mlDMF). The reaction temperature is 15 °C, the reaction time was 5 hours, the liquid phase followed the reaction of the raw materials, and the reaction was terminated.

[0084] After the reaction is over, dilute the reaction solution with 1.5L of dichloroethane and slowly pour it into 3L of water, let it stand, separate the liquids, extract the water phase with 1L of dichloroethane, combine the organic phases, wash with water until neutral, and use After drying 200g of anhydrous sodium sulfate, distill under redu...

Embodiment 3

[0090] Embodiment 3: Compound 3 and its synthetic method

[0091] The structure of compound 3 is as follows:

[0092] The synthetic method of above-mentioned compound 3, according to following synthetic method:

[0093]Add 0.2 mol of raw material 3a to a 2L three-necked flask, then measure 500.00ml of DMF, and dissolve the raw material under mechanical stirring, slowly add 0.5 mol of sodium hydride, and dropwise add the DMF solution of raw material 2b (0.24mol+200mlDMF). The reaction temperature is 25 °C, the reaction time is 10 hours, the liquid phase follows the reaction of the raw materials, and the reaction is terminated.

[0094] After the reaction is over, dilute the reaction solution with 1.5L of dichloroethane and slowly pour it into 3L of water, let it stand, separate the liquids, extract the water phase with 1L of dichloroethane, combine the organic phases, wash with water until neutral, and use After drying 200g of anhydrous sodium sulfate, distill under reduced...

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Abstract

The present invention relates to a heterocyclic organic photoelectric material and its preparation method and application. The material is a compound shown in the following formula I: the material of the present invention is a heterocyclic aromatic hydrocarbon derivative with excellent chemical stability, electron mobility, etc., and is synthesized in one step , high conversion rate, the material has the advantages of excellent electron transport characteristics and hole mobility, good thermal stability, high efficiency, low driving voltage and not easy to crystallize, it is used in electroluminescent devices with low driving voltage and high brightness, Good thermal stability, long half-life period, low cost, and 2-3 times longer lifespan.

Description

technical field [0001] The invention belongs to the technical field of electroluminescence, and in particular relates to a heterocyclic organic photoelectric material and its preparation method and application. Background technique [0002] Organic electroluminescent devices (OLEDs) have the advantages of high efficiency, high brightness, low driving voltage, fast response, and large-area photoelectric display. Therefore, they have great application prospects in the fields of display and high-efficiency lighting. [0003] OLED is an injection light-emitting device, and its basic structure is a sandwich structure formed by sandwiching an organic thin film layer between two electrodes. The organic thin film layer consists of a hole injection layer, a hole transport layer, a light emitting layer, an electron transport layer and an electron injection layer. layer composition. The hole transport layer (HTL) is responsible for adjusting the injection rate and amount of holes, and...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C07D251/22C07D401/12C07D405/12C07D405/04C07D403/04C07D417/04C07D401/14C07D403/10C07D405/10C09K11/06H01L51/50H01L51/54
CPCC07D251/22C07D401/12C07D405/12C07D405/04C07D403/04C07D417/04C07D401/14C07D403/10C07D405/10C09K11/06C09K2211/1007C09K2211/1011C09K2211/1029C09K2211/1059C09K2211/1037C09K2211/1088H10K85/615H10K85/626H10K85/654H10K85/657H10K85/6574H10K85/6572H10K50/16
Inventor 王亚龙李红燕陈志伟吴兴志薛震王金平赵宇杨凯凯
Owner SHAANXI LIGHTE OPTOELECTRONICS MATERIAL CO LTD
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