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High cold resistant and stress cracking resistant polycarbonate material

A technology of stress crack resistance and polycarbonate, which is applied in the field of polycarbonate materials, can solve the problems of polycarbonate's poor impact resistance, achieve good molding fluidity, solve low-temperature impact resistance, and improve impact resistance The effect of sex and weather resistance

Inactive Publication Date: 2019-11-08
WUXI JIAHONG PLASTICS TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] In view of the problems in the prior art, the present invention provides a polycarbonate material with high weather resistance and stress cracking resistance, using cage polysilsesquioxane as a polycarbonate modifier, which improves the overall impact resistance and weather resistance, Solved the problem of low temperature impact resistance of polycarbonate itself

Method used

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  • High cold resistant and stress cracking resistant polycarbonate material
  • High cold resistant and stress cracking resistant polycarbonate material

Examples

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Effect test

Embodiment 1

[0029] High weather resistance and stress cracking resistance polycarbonate material, its mass ratio is as follows:

[0030] 20 parts of polycarbonate, 10 parts of methyltrichlorosilane, 5 parts of cage polysilsesquioxane, 2 parts of silane coupling agent, 5 parts of filler, 3 parts of antioxidant, 20 parts of distilled water, 1 part of catalyst, none 5 parts of water ethanol.

[0031] The filler adopts ABS particles, and the particle diameter of the particles is 0.1-0.2mm.

[0032] The antioxidant adopts hindered phenolic antioxidant.

[0033] The catalyst is aluminum silicate.

[0034] The preparation method of described polycarbonate material follows the steps:

[0035] Step 1, after stirring polycarbonate, cage polysilsesquioxane and silane coupling agent evenly, seal and heat and stir to obtain solution A;

[0036] Step 2, adding the filler to absolute ethanol, stirring evenly, adding an antioxidant to obtain colloidal slurry B;

[0037] Step 3, adding methyltrichlor...

Embodiment 2

[0045] High weather resistance and stress cracking resistance polycarbonate material, its mass ratio is as follows:

[0046] 30 parts of polycarbonate, 15 parts of methyltrichlorosilane, 10 parts of cage polysilsesquioxane, 5 parts of silane coupling agent, 8 parts of filler, 6 parts of antioxidant, 30 parts of distilled water, 2 parts of catalyst, none 10 parts of water ethanol.

[0047] The filler adopts ABS particles, and the particle diameter of the particles is 0.1-0.2mm.

[0048] Said antioxidant adopts phosphite antioxidant.

[0049]The catalyst is aluminum silicate.

[0050] The preparation method of described polycarbonate material follows the steps:

[0051] Step 1, after stirring polycarbonate, cage polysilsesquioxane and silane coupling agent evenly, seal and heat and stir to obtain solution A;

[0052] Step 2, adding the filler to absolute ethanol, stirring evenly, adding an antioxidant to obtain colloidal slurry B;

[0053] Step 3, adding methyltrichlorosila...

Embodiment 3

[0061] High weather resistance and stress cracking resistance polycarbonate material, its mass ratio is as follows:

[0062] 25 parts of polycarbonate, 13 parts of methyltrichlorosilane, 7 parts of cage polysilsesquioxane, 4 parts of silane coupling agent, 7 parts of filler, 5 parts of antioxidant, 25 parts of distilled water, 2 parts of catalyst, none 8 parts of water ethanol.

[0063] The filler adopts ABS particles, and the particle diameter of the particles is 0.1-0.2mm.

[0064] The antioxidant adopts hindered phenolic antioxidant.

[0065] The catalyst is aluminum silicate.

[0066] The preparation method of described polycarbonate material follows the steps:

[0067] Step 1, after stirring polycarbonate, cage polysilsesquioxane and silane coupling agent evenly, seal and heat and stir to obtain solution A;

[0068] Step 2, adding the filler to absolute ethanol, stirring evenly, adding an antioxidant to obtain colloidal slurry B;

[0069] Step 3, adding methyltrichlo...

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Abstract

Belonging to the technical field of polycarbonate materials, the invention in particular relates to a high cold resistant and stress cracking resistant polycarbonate material, which comprises the following components by mass: 20-30 parts of polycarbonate, 10-15 parts of methyltrichlorosilane, 5-10 parts of cage polysilsesquioxane, 2-5 parts of a silane coupling agent, 1-3 parts of filler, 3-6 parts of an antioxidant, 20-30 parts of distilled water, 1-2 parts of a catalyst, and 5-10 parts of anhydrous ethanol. The distilled water contains toluene with a volume content of 20-30%. The invention also provides a preparation method. The invention adopts the cage polysilsesquioxane as the polycarbonate modifier, improves the overall impact resistance and weather resistance, and solves the problemof low temperature impact resistance of polycarbonate itself.

Description

technical field [0001] The invention belongs to the technical field of polycarbonate materials, in particular to a polycarbonate material with high weather resistance and stress cracking resistance. Background technique [0002] Polycarbonate (PC) is the general term for polyester corresponding to carbonic acid, which is divided into aliphatic, aliphatic-aromatic and aromatic polycarbonate, among which aromatic polycarbonate is listed as the top five engineering plastics because of its excellent comprehensive performance. one. Among aromatic PCs, bisphenol A PC is the most widely used and is widely used to prepare PC blends. Because polycarbonate has excellent properties such as high impact strength, creep resistance, good dimensional stability, heat resistance, and insulation, it has become a leader in general engineering plastics, and its development speed ranks first. However, many polycarbonate polymers are brittle especially at low temperatures, and while polycarbonat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L69/00C08L83/04C08L55/02C08K5/54
CPCC08L69/00C08L83/04C08L55/02C08K5/54
Inventor 顾友强管锡康
Owner WUXI JIAHONG PLASTICS TECH
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