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Ultralow-ammonia concentrated natural latex and preparation method thereof

A technology of natural rubber latex and ultra-low ammonia, which is applied in the field of ultra-low ammonia concentrated natural rubber latex and its preparation, which can solve problems affecting product exports, skin allergies, and human health irritation, and achieve reduced consumption, less consumption, and economical production cost effect

Active Publication Date: 2019-12-17
海南天然橡胶产业集团金橡有限公司 +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are two major problems in the product after adding ammonia: one is the odor problem, the human body is unacceptable to the smell of ammonia volatilized in the product or it may cause skin allergies, which is irritating and harmful to human health, and may also affect the export of the product; The other is a chemical problem. The vulcanization process of natural latex is a chemical cross-linking process. The presence of ammonia will cause harmful side reactions in this process, resulting in difficulty in vulcanization. It has a certain impact on the application of natural latex and the development of modification technology. limits
[0003] With the rapid development of the rubber industry, the traditional ammonia sterilization preservation system can no longer meet the requirements of modern rubber production. At the same time, due to the volatility and irritation of ammonia, it causes serious environmental pollution. Therefore, the development of efficient and economical non-toxic Ammonia or low-ammonia natural rubber latex production technology has become an inevitable trend in the development of natural rubber industry

Method used

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preparation example Construction

[0023] The preparation method of the ultra-low ammonia concentrated natural rubber latex provided by the invention specifically comprises the following steps:

[0024] S1, collect fresh latex, carry out pretreatment;

[0025] S2. Add ammonia, bactericidal preservative and phosphate, stir evenly, clarify for 8-72 hours, and remove sediment;

[0026] Wherein, the mass ratio of the bactericidal preservative to the fresh latex is (0.0012-0.0025): 1, the mass fraction of the ammonia is adjusted to be 0.15%-0.25%, and the mass fraction of the phosphate is adjusted to be 30%-50% %, control the free calcium and magnesium content to 80-100mol / kg; the phosphate is used to combine with the free calcium and magnesium in the fresh latex, which can inhibit the coagulation of the latex on the one hand, and can also inhibit the activation of enzymes and bacteria on the other hand; preferably Preferably, the phosphate is ammonium dihydrogen phosphate, and of course it can also be phosphates s...

Embodiment 1

[0033] A preparation method of ultra-low ammonia concentrated natural rubber latex, specifically comprising the following steps:

[0034] S1. Collect fresh latex, detect and classify the fresh latex, and filter the fresh latex that meets the detection standard according to industry testing standards to remove impurities other than latex;

[0035] S2, add ammonia, the bactericidal antistaling agent and diammonium hydrogen phosphate, stir evenly, clarify for 18 hours, and remove the sediment; wherein, the mass ratio of the bactericidal antistaling agent to fresh latex is 0.0012:1, and adjust the ratio of the ammonia The mass fraction is 0.2%, and the mass fraction of diammonium hydrogen phosphate is adjusted to 40%, and the content of free calcium and magnesium is controlled to 80mol / kg.

[0036] S3, transfer the clarified latex to a centrifuge for centrifugation, separate the latex and thick milk, transfer the thick milk to a regulating tank, immediately add the bactericidal an...

Embodiment 2

[0040] A preparation method of ultra-low ammonia concentrated natural rubber latex, specifically comprising the following steps:

[0041] S1. Collect fresh latex, detect and classify the fresh latex, and filter the fresh latex that meets the detection standard according to industry testing standards to remove impurities other than latex;

[0042] S2, add ammonia, the bactericidal antistaling agent and diammonium hydrogen phosphate, stir evenly, clarify for 72 hours, and remove the sediment; wherein, the mass ratio of the bactericidal antistaling agent to fresh latex is 0.0025:1, and adjust the concentration of the ammonia The mass fraction is 0.15%, and the mass fraction of diammonium hydrogen phosphate is adjusted to 30%, and the content of free calcium and magnesium is controlled to be 100mol / kg.

[0043] S3, transfer the clarified latex to a centrifuge for centrifugation, separate the latex and thick milk, transfer the thick milk to a regulating tank, immediately add the bact...

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PUM

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Abstract

The invention discloses a preparation method of ultralow-ammonia concentrated natural latex, and the preparation method comprises the following steps: S1, collecting fresh latex, and pretreating; s2,adding ammonia, a sterilizing fresh-keeping agent and phosphate, adjusting the mass fraction of the ammonia to 0.15-0.25%, uniformly stirring, clarifying for 8-72 hours, and removing sediments; s3, transferring the clarified latex to a centrifugal machine to be centrifuged, separating out skim latex and concentrated milk, transferring the concentrated milk to an adjusting tank, immediately addingthe sterilizing fresh-keeping agent and lauric soap, fully and uniformly stirring, and accumulating the concentrated milk to obtain concentrated latex; and S4, adjusting the dry glue content in the concentrated latex. By adopting the preparation method of the ultralow-ammonia concentrated natural latex provided by the invention, the effects of sterilization and bacteriostasis can be achieved for along time, the latex character is more stable, the use amount of ammonia can be reduced, no irritation is caused, the environment is protected, the use amount is small, and the cost is saved.

Description

technical field [0001] The invention relates to the technical field of natural concentrated latex production, in particular to an ultra-low ammonia concentrated natural latex and a preparation method thereof. Background technique [0002] Soon after the natural rubber latex flows out from the tree, the enzymes and bacteria start to act, especially under the action of oxygen and light, they become more active, decomposing the proteins, sugars, esters, etc. in the latex to generate organic acids or spoilage substances, neutralizing the rubber The charges on the particles cause coagulation. On the one hand, the presence of metal salts reacts with the protective layer in the latex, and on the other hand, it can also promote the activation of enzymes and bacteria. Among them, magnesium ions have the greatest impact, which also promotes the coagulation of latex. For these reasons, usually 6 to 12 hours after tapping, the latex will naturally solidify. If the latex is coagulated,...

Claims

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Application Information

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IPC IPC(8): C08C1/06
CPCC08C1/06
Inventor 蔡笃坤吴陵江
Owner 海南天然橡胶产业集团金橡有限公司
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