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A carrier material prepared from hazardous chemical waste and its preparation method and use

A carrier material and hazardous waste technology, applied in the field of preparation of the carrier material, can solve the problems of low utilization rate and the like, and achieve the effects of low cost, reasonable design, and good adsorption and permeation effect.

Active Publication Date: 2020-06-19
翟作栋 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] With the research and utilization of industrial waste, the technology continues to advance, and the level of comprehensive utilization has improved, but the utilization rate is still far lower than that of Western developed countries

Method used

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  • A carrier material prepared from hazardous chemical waste and its preparation method and use

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] Example 1, a carrier material prepared from chemical hazardous waste, the carrier material is made of the following raw materials in weight ratio:

[0044] (1) High-salt chemical hazardous waste: 50%; the NaCl content of this high-salt chemical hazardous waste is 95%;

[0045] (2) Clay or gangue: 20%;

[0046] (3) Solid waste is alkali slag: 30%.

[0047] The preparation method steps of this carrier material are as follows:

[0048] (1) After the raw materials are crushed and stirred evenly according to the above ratio, the granulator is used to granulate to obtain material granules;

[0049] (2) The material particles enter the rotary kiln for two-stage roasting. The first stage of the two-stage roasting is low-temperature roasting, and the low-temperature section is continuously and gradually increased in temperature, and roasted at 100°C-300°C for 45 minutes; the second The section is fired at a high temperature, and fired at 890°C-950°C for 60 minutes to obtain s...

Embodiment 2

[0060] Example 2, a carrier material prepared from chemical hazardous waste, the carrier material is made of the following raw materials in weight ratio:

[0061] (1) High-salt chemical hazardous waste: 45%; the NaCl content of this high-salt chemical hazardous waste is 90%;

[0062] (2) Clay or gangue: 18%;

[0063] (3) Solid waste: 37%, selected from a mixture of tailings sand and waste slag, half and half.

[0064] The preparation method step of carrier material is as follows:

[0065] (1) After the raw materials are crushed and stirred evenly according to the above ratio, the granulator is used to granulate to obtain material granules;

[0066] (2) The material particles enter the rotary kiln for two-stage roasting. The first stage of the two-stage roasting is low-temperature roasting at 200°C-400°C for 30 minutes; the second stage is high-temperature roasting at 1000-1100°C Roast for 100 minutes to obtain spherical ceramsite with a vitrified surface.

Embodiment 3

[0067] Example 3, a carrier material prepared from chemical hazardous waste, the carrier material is made of the following raw materials in weight ratio:

[0068] (1) High-salt chemical hazardous waste: 30%; the NaCl content of this high-salt chemical hazardous waste is 75%;

[0069] (2) Clay or gangue: 20%;

[0070] (3) Solid waste: 50%, selected from the mixture of lead-zinc slag and iron slag, half and half.

[0071] The preparation method step of carrier material is as follows:

[0072] (1) After the raw materials are crushed and stirred evenly according to the above ratio, the granulator is used to granulate to obtain material granules;

[0073] (2) The material particles enter the rotary kiln for two-stage roasting. The first stage of the two-stage roasting is low-temperature roasting at 150°C-350°C for 60 minutes; the second stage is high-temperature roasting at 950°C-1150°C Lower firing for 50 minutes to obtain spherical ceramsite with a vitrified surface.

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Abstract

The invention is a carrier material prepared by chemical hazardous waste. The carrier material is made of high-salt chemical hazardous waste, clay or coal gangue, and solid waste, wherein the NaCl content of the high-salt chemical hazardous waste is 75%-95%; and the solid waste is selected from one or a mixture composed of more of tailings sand, fly ash, lead-zinc slag, waste slag, alkali slag, gypsum slag, and iron slag. The invention also discloses a preparation method of the carrier material, and the surface layer porcelainized spherical ceramsite is obtained through granulation and roasting. The carrier material can be used as an adsorbent material and a permeable material. The technical prejudice and technical blind area in the prior art that highly hazardous waste salts generated bychemical synthesis, excessive evaporation, refining and distillation, and the like cannot be used to prepare carrier materials are overcome, the high-salt chemical hazardous waste as the main materialis effectively used to prepare the carrier material, turning waste into treasure is realized, and a new and efficient method for treatment, amount reduction and resource comprehensive utilization ofthe high-salt chemical hazardous waste is provided.

Description

technical field [0001] The invention relates to a method for rationally utilizing hazardous chemical waste, in particular to a carrier material prepared from hazardous chemical waste. The invention also relates to a preparation method and application of the carrier material. Background technique [0002] Hazardous chemical waste seriously affects my country's ecological environment and also restricts the production of enterprises. With the continuous implementation of hazardous waste control measures in my country, the disposal and comprehensive utilization of chemical hazardous waste provides a broad space for development. According to relevant public statistics, the residues (high-salt chemical hazardous waste) produced by chemical synthesis, transitional evaporation, refining distillation, etc. in my country reach more than 2 million tons every year. The processing method to it in the prior art is stockpiling, incineration or landfill, can't realize reasonable utilization...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C04B33/132C04B33/13C04B33/04
CPCC04B33/04C04B33/13C04B33/132C04B2235/6567C04B2235/661Y02P40/60
Inventor 翟作栋翟红伟
Owner 翟作栋