Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Preparation method of proton exchange membrane fuel cell membrane electrode

A fuel cell membrane and proton exchange membrane technology, applied in fuel cells, battery electrodes, circuits, etc., can solve problems such as the degradation of catalytic layer and electrolyte, membrane electrode performance, etc., to improve contact performance, improve power generation performance, reduce Effect of small contact resistance

Pending Publication Date: 2020-03-17
DONGFENG MOTOR CORP HUBEI
View PDF11 Cites 4 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

None of them can solve the problem that the poor contact between the catalytic layer and the electrolyte leads to the degradation of the performance of the membrane electrode.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Preparation method of proton exchange membrane fuel cell membrane electrode
  • Preparation method of proton exchange membrane fuel cell membrane electrode
  • Preparation method of proton exchange membrane fuel cell membrane electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] A kind of preparation method of the membrane electrode of proton exchange membrane fuel cell provided by the invention, the steps are:

[0043] a. Preparation of gas diffusion electrode

[0044] 1) Preparation of catalyst ink:

[0045]Weigh 0.5g of platinum black and mix it with 1.0g of deionized water, then carry out ultrasonication in an ice bath, set the power of the ultrasonic instrument to 3W, and the ultrasonic time is 10 minutes. By observing that there is no platinum black powder solid in the mixed solution, the solid-liquid distribution is uniform and then mixed. Finish. Then add 1.0g isopropanol and 0.5g concentration of 5wt% Nafion solution, finally add 0.21g solid content 60wt% PTFE emulsion (about 20% PTFE content in the solid after drying), after mixing, disperse by ball milling method: transfer the mixed solution into a ball mill jar, and add zirconia stirring particles (the mass ratio of zirconia stirring particles to the mixed solution is 1.5:1), and ...

Embodiment 2

[0054] A kind of preparation method of the membrane electrode of proton exchange membrane fuel cell provided by the invention, the steps are:

[0055] a. Preparation of gas diffusion electrode

[0056] 1) Preparation of catalyst ink:

[0057] Weigh 0.5g of platinum black and mix it with 1.5g of deionized water, and perform ultrasonication in an ice bath. The power of the ultrasonic instrument is set to 5W, and the ultrasonic time is 10 minutes. By observing that there is no platinum black powder solid in the mixed solution, the solid-liquid distribution is uniform and then mixed. Finish. Then add 1.33g isopropanol and 0.5g concentration of 5wt% Nafion solution, finally add 0.27g solid content 60wt% PTFE emulsion (about 24% PTFE content in the solid after drying), after mixing, disperse by ball milling method: transfer the mixed solution into a ball mill jar, and add zirconia stirring particles (the mass ratio of zirconia stirring particles to the mixed solution is 1.5:1), an...

Embodiment 3

[0066] A kind of preparation method of the membrane electrode of proton exchange membrane fuel cell provided by the invention, the steps are:

[0067] a. Preparation of gas diffusion electrode

[0068] 1) Preparation of catalyst ink:

[0069] Weigh 0.5g of platinum black and mix it with 2.0g of deionized water, then carry out ultrasonication in an ice bath, set the power of the ultrasonic instrument to 4W, and the ultrasonic time is 5 minutes. By observing that there is no platinum black powder solid in the mixed solution, the solid-liquid distribution is uniform and then mixed. Finish. Then add 2.0g isopropanol and 0.4g concentration of 5wt% Nafion solution, finally add 0.36g solid content 60wt% PTFE emulsion (about 30% PTFE content in the solid after drying), after mixing, disperse by ball milling method: transfer the mixed solution into a ball mill jar, and add zirconia stirring particles (the mass ratio of zirconia stirring particles to the mixed solution is 1.5:1), and ...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention discloses a preparation method of a proton exchange membrane fuel cell membrane electrode, which is characterized by comprising the following steps: a, preparing a gas diffusion electrode by using catalyst ink and a gas diffusion layer; b, coating the surface of a catalyst layer of the gas diffusion electrode with a perfluorosulfonic acid diluent with the concentration of 0.5 wt%-1wt%, and drying the gas diffusion electrode at 90-120 DEG C for 30-60 minutes; and c, fitting the surfaces, coated with the perfluorosulfonic acid, of the two gas diffusion electrodes with the two sidesof the solid electrolyte respectively, and performing hot pressing to obtain the membrane electrode. According to the invention, the surface of the catalyst layer is coated with a Nafion diluent; themembrane and the proton exchange membrane have the same substance and different substance states; in the hot pressing process, Nafion resin on the surface of the catalyst layer and Nafion resin in the proton exchange membrane are reconstructed in physical state and are fused and combined, so that the catalyst layer and the proton exchange membrane are better combined into a whole, the contact performance between the catalyst layer and the proton exchange membrane is improved, the contact resistance is reduced, and the power generation performance is improved.

Description

technical field [0001] The invention relates to a fuel cell, in particular to a method for preparing a membrane electrode of a proton exchange membrane fuel cell. Background technique [0002] The proton exchange membrane fuel cell is an energy conversion device that converts the chemical energy stored in the fuel into electrical energy. The membrane electrode assembly (MEA) is the core component of the proton exchange membrane fuel cell. The performance of the membrane electrode assembly is largely It directly determines the pros and cons of proton exchange membrane fuel cells. [0003] The membrane electrode consists of two gas diffusion electrodes, the cathode and the anode, and a solid electrolyte separating the two electrodes. Solid electrolytes generally use perfluorosulfonic acid membrane materials, and DuPont's registered Nafion series products are representative of proton exchange membranes. Such as figure 1 As shown, the gas diffusion electrode 10 is divided int...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): H01M4/88H01M8/1006
CPCH01M4/8882H01M8/1006Y02E60/50
Inventor 张泽史建鹏张新丰李洪涛张宇覃博文
Owner DONGFENG MOTOR CORP HUBEI
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products