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Reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and preparation method thereof

A technology of grouting reinforcement and mechanical strength, which is applied in the field of grouting reinforcement materials, can solve problems such as poor permeability and toughness, high exothermic temperature, failure of rescue devices, etc., achieve strong penetration ability, low viscosity, and reduce preparation costs Effect

Inactive Publication Date: 2020-06-05
CHINA COAL TECH & ENG GRP CHONGQING RES INST CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

But find that above-mentioned three kinds of materials all have corresponding deficiencies in the actual use process, specifically as follows: (1) water glass-cement slurry grouting reinforcement material needs on-the-spot preparation cement slurry during construction, thus causes construction site Dust and the prepared materials have poor permeability and toughness; (2) The polyurethane grouting material has excellent mechanical properties, but it will foam when encountering water during construction, the heat release temperature is high, and the construction is still difficult. It will release irritating gas. In addition, polyurethane grouting materials generally contain halogen-based flame retardants. Once the heat storage of large-volume grouting materials causes high-temperature smoke or fire, the halogen-containing flame retardants will generate harmful gases after burning. Hydrogen, which makes the rescue devices worn by workers invalid, causing casualties

Method used

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  • Reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and preparation method thereof
  • Reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and preparation method thereof
  • Reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0027] First prepare component A and component B according to the parts by weight in Table 1, and then mix and cure equal volumes of component A and component B to obtain a reactive type with low smoke toxicity and high mechanical strength Grout reinforcement material.

[0028] Table 1 Composition of different materials

[0029]

[0030]

[0031] The preparation method is:

[0032] (1) Preparation of component A: take a reaction stabilizer, a reaction accelerator and an aqueous silicate solution in parts by weight, stir to make them evenly mixed, and obtain component A, which is sealed and packaged for use;

[0033] (2) Preparation of component B: according to parts by weight, take polyisocyanate, film-forming aids and reinforcing agents and add them to the reaction kettle, stir to make them evenly mixed, and obtain component B, which is sealed and packaged for use;

[0034] (3) Curing: Mix the A component and the B component in the sealed package according to the equa...

Embodiment 2

[0036] Compression performance, stability, safety, viscosity, permeability, diffusion radius of the material prepared in Test Example 1, and water glass-cement grouting reinforcement material, polyurethane grouting material and silicic acid in the prior art Salt-modified polyurethane grouting materials were compared, and the results are shown in Table 2.

[0037] Table 2 Performance comparison of different grouting reinforcement materials

[0038]

[0039]

[0040] It can be seen from the performance in Table 2 that the reactive grouting reinforcement material prepared by the present invention has excellent compression performance (up to 60Mpa or more), good stability (both stability is good), high safety (material smoke toxicity It can reach ZA1 level, self-extinguishing after leaving the fire within 1s), and also has the characteristics of low viscosity (viscosity of component A and component B are both below 325mPa.s), strong penetration ability, and large diffusion r...

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Abstract

The invention relates to a reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and a preparation method of the reactive grouting reinforcement material, and belongs to the field of mining polymer grouting reinforcement materials. The reactive grouting reinforcement material is prepared from a component A and a component B according to a ratio of 1: 1, wherein the volume ratio of the components is 1. The coating comprises the following components: a silicate aqueous solution, a reaction stabilizer, a reaction promoter, polyisocyanate, a coalescing agentand a reinforcing agent, the obtained reactive grouting reinforcement material has the characteristics of low smoke toxicity and high mechanical strength, the smoke toxicity grade of the material canreach the quasi-safety grade, the compressive strength can reach 60 Mpa, the flame retardant property can realize self-extinguishing 1s away from fire, the safety performance is high, and the stability is good; meanwhile, the characteristics of low viscosity, strong infiltration capacity and large diffusion radius are also realized; in addition, the preparation method of the material is simple and easy to operate, and the preparation cost of the reinforcing material can be further reduced.

Description

technical field [0001] The invention belongs to the field of grouting reinforcement materials, in particular to a reactive grouting reinforcement material with low smoke toxicity and high mechanical strength and a preparation method thereof. Background technique [0002] Reactive grouting reinforcement material is a type of grouting material that needs to undergo a chemical reaction during the construction process to achieve the effects of bonding, strengthening, enriching, and stabilizing. According to statistics, there are mainly three types of reactive grouting reinforcement materials used on site: water glass-cement grouting reinforcement materials, polyurethane grouting materials and silicate modified polyurethane grouting materials. But find that above-mentioned three kinds of materials all have corresponding deficiencies in the actual use process, specifically as follows: (1) water glass-cement slurry grouting reinforcement material needs on-the-spot preparation cemen...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L75/04C08L75/08C08K3/34C08K5/101C08K5/54C08G18/48C08G18/32
CPCC08G18/3206C08G18/4833C08K3/34C08K5/101C08K5/54C08L2201/02C08L75/04C08L75/08
Inventor 许向彬刘青周亭王斌斌张青松刘标懿吴磊李时宜屈凡瑞张川沈莉樊淑兰
Owner CHINA COAL TECH & ENG GRP CHONGQING RES INST CO LTD
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