Photocatalytic degradation composite particle, and preparation method and application thereof

A composite particle, photocatalytic technology, applied in the field of photocatalysis, can solve problems such as affecting cultivation, aggravation, and difficulty in large-scale use, and achieve the effects of reducing production costs, reducing usage, and strong degradation ability.

Inactive Publication Date: 2020-07-03
NANCHANG HANGKONG UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] With the continuous and rapid development of industrialization and urbanization, the traditional soot-type pollution has not yet been controlled, and the composite air pollution caused by vehicle exhaust has become increasingly prominent. A large amount of nitrogen oxides and volatile organic compounds have caused fine particles, ozone, and acid rain in cities. Secondary pollution is intensifying, and a large amount of domestic wastewater and industrial wastewater are produced. At present, people will add photocatalysts for photolysis when treating wastewater. The degradation effect of photocatalysts is good and there will be no secondary pollution, but at present The production cost of photocatalyst particles is high, and it is difficult to use them on a large scale. At the same time, in order to control air pollution, rice straw and corn straw in farmland are currently prohibited from burning, but leaving them in the field will affect the cultivation of the next year. Therefore, The government is also actively encouraging enterprises to purchase rice stalks and corn stalks for processing and production. However, the current use of rice stalks and corn stalks is too low, and the market demand is too low. How to increase the use of rice stalks and corn stalks is also a big problem that needs to be solved at present question

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] nanoscale anatase TiO 2 Put it in an oven at 110°C for 12 hours and seal it up; put the washed rice straw into a muffle furnace, fully calcinate it at 500°C for 4 hours, collect the ash, put the ash in a grinder and add water to grind it into a homogenate, Filter to remove soluble salt; pass the residue on the filter paper through a 400-mesh sieve under water washing, and collect the sieved particles; suspend the sieved particles in the container, settle naturally for 10 minutes, and then remove the upper suspension; repeat 6 times After the natural precipitation process, pure silica particles are obtained; after peeling the corn stalks, cut them into 1 cm long cylinders, soak them in 10% dilute hydrochloric acid for 48 hours, and then wash them repeatedly with distilled water until the chloride ions are washed away. Then dried at 80°C for 24h, soaked in FeVO 4 In the gel, vacuumize for 30min, take it out after standing for 4h, and dry it at 80°C; put it in a muffle fu...

Embodiment 2

[0021] nanoscale anatase TiO 2 Put it in an oven at 110°C for 12 hours and seal it up; put the washed rice straw into a muffle furnace, fully calcinate it at 500°C for 6 hours, collect the ash, put the ash in a grinder and add water to grind it into a homogenate, Remove the soluble salt by filtration; pass the residue on the filter paper through a 400-mesh sieve under water washing, and collect the sieved particles; suspend the sieved particles in the container, settle naturally for 15 minutes, and then remove the upper suspension; repeat 8 times After the natural precipitation process, pure silica particles are obtained; after peeling the corn stalks, cut them into 1 cm long cylinders, soak them in 10% dilute hydrochloric acid for 48 hours, and then wash them repeatedly with distilled water until the chloride ions are washed away. Then dried at 80°C for 24h, soaked in FeVO 4 In the gel, vacuumize for 30 minutes, take it out after standing for 4 hours, and dry it at 80°C; put...

Embodiment 3

[0023] nanoscale anatase TiO 2 Put it in an oven at 110°C for 12 hours and seal it up; put the washed rice straw into a muffle furnace, fully calcinate it at 500°C for 5 hours, collect the ash, put the ash in a grinder and add water to grind it into a homogenate, Filter to remove soluble salt; pass the residue on the filter paper through a 400-mesh sieve under water washing, and collect the sieved particles; suspend the sieved particles in the container, settle naturally for 10 minutes, and then remove the upper suspension; repeat 7 times After the natural precipitation process, pure silica particles are obtained; after peeling the corn stalks, cut them into 1 cm long cylinders, soak them in 10% dilute hydrochloric acid for 48 hours, and then wash them repeatedly with distilled water until the chloride ions are washed away. Then dried at 80°C for 24h, soaked in FeVO 4 In the gel, vacuumize for 30 minutes, take it out after standing for 4 hours, and dry it at 80°C; put it in a...

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Abstract

The invention relates to the technical field of photocatalysis, and concretely relates to a photocatalytic degradation composite particle, and a preparation method and an application thereof. The photocatalytic degradation composite particle comprises nano-scale anatase titanium dioxide, silicon dioxide particles, triclinic FeVO4 crystal particles and a coupling agent. Rice straws can be used forproducing the silicon dioxide particles, the triclinic FeVO4 crystal particles are produced by utilizing corn corns, and the triclinic FeVO4 crystal particles, silicon dioxide particles and nanoscaleanatase titanium dioxide are mixed by utilizing the coupling agent. In a laboratory environment, methyl violet can be completely degraded within 150 min, the degradation capacity of the composite particle on wastewater is high, the use amount of titanium dioxide is greatly reduced, the production cost is reduced, waste is treated with waste, and a new application is provided for the rice straws and corn corns.

Description

technical field [0001] The invention relates to the technical field of photocatalysis, in particular to a photocatalytic degradation composite particle and a preparation method and application thereof. Background technique [0002] With the continuous and rapid development of industrialization and urbanization, the traditional soot-type pollution has not yet been controlled, and the composite air pollution caused by vehicle exhaust has become increasingly prominent. A large amount of nitrogen oxides and volatile organic compounds have caused fine particles, ozone, and acid rain in cities. Secondary pollution is intensifying, and a large amount of domestic wastewater and industrial wastewater are produced. At present, people will add photocatalysts for photolysis when treating wastewater. The degradation effect of photocatalysts is good and there will be no secondary pollution, but at present The production cost of photocatalyst particles is high, and it is difficult to use t...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J23/847B01J37/08C02F1/30C02F101/30
CPCB01J23/8472B01J23/002B01J35/004B01J37/08C02F1/30B01J2523/00C02F2101/308C02F2305/10
Inventor 吴美凤陈歆王登科刘虎晏小放李双邹建平
Owner NANCHANG HANGKONG UNIVERSITY
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