A kind of method for preparing sei film by magnetization
A preparation step and magnetic field technology, which is applied in the field of magnetized SEI film preparation, can solve the problems of low charge and discharge efficiency, large irreversible capacity loss, and large amount of lithium ion intercalation on the SEI film, achieving excellent rate performance, excellent charge and discharge efficiency, The effect of excellent cycle performance
Active Publication Date: 2022-01-11
ZHEJIANG UNIV OF TECH
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Problems solved by technology
[0009] In order to solve the problem that the existing SEI film has low charge and discharge efficiency when used, and the amount of lithium ions intercalated on the SEI film is large after long-term cycling, resulting in a large irreversible capacity loss, and the existing improved processes cannot effectively solve the problem , the invention provides a method for preparing SEI film by magnetization
Method used
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Effect test
Embodiment 1
[0058] 一种磁化制备SEI膜的方法,所述制备方法包括以下制备步骤:
[0059] 1)以市售TBL18650锂离子电池(Typical 1C=2400mAh / Nominal 1C=2350mAh)作为试验模板(选用完全相同的各原料),按照常规TBL18650工艺将阴极片、阳极片和隔离膜采用叠片组装的方式组装为裸电芯,在裸电芯外包装外壳后注满电解液,静置20min至阴极片和阳极片均被充分浸润,得到预制电芯;
[0060] 2)对预制电芯进行35℃、24h的陈化处理,陈化后的预制电芯置于化成机中化成,化成时对预制电芯施加磁场,磁场方向与预制电芯中阴极片和阳极片连线的夹角为0°、磁场强度为0.5T,在磁场作用下进行化成处理,化成温度为85℃,化成电流为0.2C,化成截止电位为3.7V,化成处理结束后在阳极片表面形成SEI膜,即得到含有SEI膜的成品电芯。
Embodiment 2
[0062] 具体操作与实施例1相同,所不同的是:磁场强度为1.5T。
Embodiment 3
[0064] 具体操作与实施例1相同,所不同的是:磁场强度为2.0T。
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The invention relates to the field of new energy materials, in particular to a method for preparing an SEI film by magnetization. The preparation method includes the following preparation steps: assembling the cathode sheet, the anode sheet and the separator into a bare battery cell, injecting an electrolyte solution after the bare cell outer packaging shell, and standing until the cathode sheet and the anode sheet are fully soaked to obtain Prefabricated cells: place the prefabricated cells in a chemical formation machine, apply a magnetic field to the prefabricated cells during the formation, and perform a chemical conversion process under the action of the magnetic field. After the chemical conversion process, an SEI film is formed on the surface of the anode sheet. When the SEI film prepared by the method of the present invention is used in a battery, the charge and discharge efficiency, cycle performance and rate performance can all be significantly optimized and improved.
Description
technical field [0001] The invention relates to the field of new energy materials, in particular to a method for preparing an SEI film by magnetization. Background technique [0002] The development of lithium-ion batteries has provided rapid advances in portable electronic devices and enabled the realization of electric vehicles. However, the low reduction potential of graphite requires the formation of a solid electrolyte phase (SEI) to passivate the electrode surface for long-term cycling. [0003] SEI film, the full name of solid electrolyte interface, solid electrolyte interface (membrane), as the name implies, it is a passivation film layer with solid electrolyte properties. SEI is Li + It is an excellent conductor, which can allow lithium ions to be transported in it, enter the graphite surface, and perform lithium deintercalation work. At the same time, it is also a good electronic insulator, which can effectively reduce the probability of internal short circuit a...
Claims
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IPC IPC(8): H01M10/058H01M10/44H01M10/0525
CPCH01M10/058H01M10/446H01M10/0525Y02E60/10Y02P70/50
Inventor 唐谊平沈康侯广亚
Owner ZHEJIANG UNIV OF TECH



