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Preparation method of flexible high-conductivity elastomer composite material

A technology of composite materials and elastomers, which is applied in the field of composite material preparation, can solve the problems of large impedance changes, uneven dispersion of inorganic conductive fillers, poor electrical stability, etc., and achieve the effect of improving electrical conductivity

Inactive Publication Date: 2020-12-18
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Using the solution to dissolve the elastic matrix and the inorganic conductive filler at the same time, and then casting and heating together to remove the solvent and lay the film, so that the inorganic conductive filler can be directly introduced into the matrix, which simply and effectively improves the conductivity of the elastic matrix. However, the inorganic conductive filler is in The dispersion inside the matrix is ​​not uniform, and the impedance changes greatly during the stretching process (poor electrical stability)

Method used

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  • Preparation method of flexible high-conductivity elastomer composite material
  • Preparation method of flexible high-conductivity elastomer composite material
  • Preparation method of flexible high-conductivity elastomer composite material

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] Take 5 g of granular styrene-butadiene-styrene (SBS) block copolymer and dissolve it in 60 g of tetrahydrofuran solution, sonicate for 30 minutes until the solution is clear and transparent. film, the solution was dried for 2 hours to form a sheet. Silver trifluoroacetate 5g (AgCF 3 COO) was dissolved in 45 g of ethanol solution, ultrasonicated for 20 minutes until the solution was light yellow, clear and transparent, which was recorded as AgCF 3 COO-C 2 h 5 OH (10 wt%) solution. The prepared SBS was cut into 1g strips by a punching machine, and then immersed in the prepared silver trifluoroacetate ethanol (10wt%) solution at room temperature to obtain the conductive precursor (AgCF) containing to be reduced. 3 COO) and swollen SBS, denoted as AgCF 3 COO-C 2 h 5 OH-SBS swelling matrix. AgCF 3 COO-C 2 h 5 The OH-SBS swelling matrix is ​​immersed in an ethanol solution of hydrazine hydrate (hydrazine accounts for 50 wt%) at room temperature. Conductive silver ...

Embodiment 2

[0022] Take 5 g of granular styrene-butadiene-styrene (SBS) block copolymer and dissolve it in 60 g of tetrahydrofuran solution, sonicate for 30 minutes until the solution is clear and transparent. film, the solution was dried for 2 hours to form a sheet. Silver trifluoroacetate 10g (AgCF 3 COO) was dissolved in 40 g of ethanol solution, ultrasonicated for 20 minutes until the solution was light yellow and clear, which was recorded as AgCF 3 COO-C 2 h 5 OH (20 wt%) solution. The prepared SBS was cut into 1g strips by a punching machine, and then immersed in the prepared silver trifluoroacetate ethanol (20wt%) solution at room temperature to obtain the conductive precursor (AgCF) containing to be reduced. 3 COO) and swollen SBS, denoted as AgCF 3 COO-C 2 h 5 OH-SBS swelling matrix. AgCF 3 COO-C 2 h 5 The OH-SBS swelling matrix is ​​immersed in an ethanol solution of hydrazine hydrate (hydrazine accounts for 50 wt%) at room temperature. The conductive nano-silver par...

Embodiment 3

[0025] Take 5 g of granular styrene-butadiene-styrene (SBS) block copolymer and dissolve it in 60 g of tetrahydrofuran solution, sonicate for 30 minutes until the solution is clear and transparent. film, the solution was dried for 2 hours to form a sheet. Silver trifluoroacetate 15g (AgCF 3 COO) was dissolved in 35 g of ethanol solution, ultrasonicated for 20 minutes until the solution was light yellow, clear and transparent, which was recorded as AgCF 3 COO-C 2 h 5 OH (30 wt%) solution. The prepared SBS was cut into 1g strips by a punching machine, and then immersed in the prepared silver trifluoroacetate ethanol (30wt%) solution at room temperature to obtain the conductive precursor (AgCF) containing to be reduced. 3 COO) and swollen SBS, denoted as AgCF 3 COO-C 2 h 5 OH-SBS swelling matrix. AgCF 3 COO-C 2 h 5 The OH-SBS swelling matrix is ​​immersed in an ethanol solution of hydrazine hydrate (hydrazine accounts for 50 wt%) at room temperature. While the conduct...

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Abstract

The invention relates to a high-conductivity elastomer composite material prepared by microscopically constructing a conductive network and a preparation method of the high-conductivity elastomer composite material, and belongs to the field of preparation of flexible conductive composite materials, and the flexible conductive material has the characteristic of stable conductivity under deformation. The preparation method comprises the following steps: swelling an SBS elastic matrix membrane by using a silver salt solution, introducing a large amount of conductive precursor Ag+ to be reduced into an elastomer matrix, reducing the swollen elastomer to reduce a large amount of silver ions inside and on the surface of the elastomer into nano-silver particles, taking out the nano-silver particles, and drying the nano-silver particles to obtain the SBS elastic matrix membrane, wherein the conductive nano-silver particles are tightly compressed along with the reduction of the drying volume toform a compact and folded conductive surface coating and an internal conductive network. The composite material prepared by the method solves the problems of aggregation and low content of the conductive filler in the matrix, can improve the resistance stability in the stretching process while improving the conductivity, can well reserve the mechanical properties of the SBS, and has the advantages of simple operation and wide application prospects.

Description

technical field [0001] The invention relates to a method for preparing a high-conductivity elastomer composite material by constructing a conductive network at the microscopic level, and belongs to the technical field of composite material preparation. Background technique [0002] In recent years, with the continuous development of electronic information technology, electronic devices are also moving toward miniaturization and lightweight development. Highly conductive elastomer composites have received extensive attention due to their good flexibility and large deformation. As a highly conductive material, nano-silver particles can effectively improve the electrical conductivity of the composite material. However, due to the low content of conductive fillers and uneven dispersion, the electrical conductivity decreases significantly and the impedance increases significantly during stretching (poor electrical stability). Highly conductive elastomer composites with silver na...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L53/02C08K3/08C08J5/18C08J7/02
CPCC08K3/08C08J5/18C08J7/02C08K2201/011C08K2003/0806C08K2201/001C08K2201/013C08J2353/02
Inventor 陈广新王添泽师晋超李齐方
Owner BEIJING UNIV OF CHEM TECH
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