Aqueous binder and preparation method thereof, glued diaphragm and preparation method thereof, and lithium ion secondary battery
A technology for water-based binders and diaphragms, applied in the fields of water-based binders, preparation methods, preparations, glue-coated diaphragms, and lithium-ion secondary batteries. Effect
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Embodiment 1
[0072]This embodiment provides a water-based adhesive. The raw materials of the water-based adhesive include point-bonded polymers, surface-bonded polymers, and polymer lithium salts. The point-bonding polymer is a granular polymer with a D50 particle size of 0.5um; the surface-bonding polymer is polyacrylic acid with a molecular mass of 200,000 and a glass transition temperature of 70°C; the polymer lithium The salt is lithium carboxymethyl cellulose;
[0073]The point-bonding polymer accounts for 75% of the total dry basis mass of the water-based binder raw materials, and the surface-bonding polymer accounts for 20% of the total dry basis mass of the water-based binder raw materials; the polymer lithium salt accounts for the total dry mass of the water-based binder raw materials. 5% of the base mass.
[0074]This embodiment also provides a method for preparing the water-based adhesive, including:
[0075](1) Prepare the first glue solution and the second glue solution of the surface-bondin...
Embodiment 2
[0083]This embodiment provides a water-based adhesive. The raw materials of the water-based adhesive include point-bonded polymers, surface-bonded polymers, and polymer lithium salts. The point-bonding polymer is a granular polymer with a D50 particle size of 1.5um; the surface-bonding polymer is polyacrylamide with a molecular mass of 1 million and a glass transition temperature of 100°C; the polymer The lithium salt is a lithium polyacrylate;
[0084]The point-bonding polymer accounts for 85% of the total dry-based mass of the water-based binder raw materials, and the surface-bonding polymer accounts for 13% of the total dry-based mass of the water-based binder raw materials. 2% of the base mass.
[0085]This embodiment also provides a method for preparing the water-based adhesive, including:
[0086](1) Prepare the first glue solution and the second glue solution of the surface-bonding polymer and polymer lithium salt respectively;
[0087](2) Stir the first glue solution, revolution 15r / min...
Embodiment 3
[0094]This embodiment provides a water-based adhesive. The raw materials of the water-based adhesive include point-bonded polymers, surface-bonded polymers, and polymer lithium salts. The point-bonding polymer is a granular polymer with a D50 particle size of 3um; the surface-bonding polymer is a polyamide with a molecular mass of 500,000 and a glass transition temperature of 120°C; the polymer lithium salt Lithium carboxyethyl cellulose;
[0095]Point-bonding polymer accounts for 92% of the total dry basis mass of water-based binder raw materials, and surface-bonding polymer accounts for 7% of the total dry-based mass of water-based binder raw materials; polymer lithium salt accounts for the total dry mass of the water-based binder 1% of the base mass.
[0096]This embodiment also provides a method for preparing the water-based adhesive, including:
[0097](1) Prepare the first glue solution and the second glue solution of the surface-bonding polymer and polymer lithium salt respectively;
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