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High-transparency conductive nano paper as well as convenient preparation method and application thereof

A transparent conductive, nano-paper technology, applied in the field of conductive paper, can solve the problems of limited application of conductive paper, high energy consumption, discount of paper conductivity, etc., to achieve excellent bending resistance and electrical stability, fast photopolymerization, good The effect of tensile properties

Pending Publication Date: 2021-02-02
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, there are still a series of problems in the current production of conductive paper, such as (1) the high Young's modulus of the hard conductive filler, which leads to the tendency of the paper fiber to fall off during the bending process, and the resistance rises significantly after repeated bending (2) Some metal powders have the problem of oxidation, which greatly reduces the conductivity of the paper; (3) After some carbon-based conductive materials are combined with the paper, the transparency of the paper is greatly reduced or completely black
In addition, most of the existing high-transparency conductive paper preparation processes use physical deposition methods to control the thickness of the conductive layer within 50nm to obtain high transparency. However, the complicated deposition process requires harsh high-pressure, vacuum or high-temperature conditions. High consumption and low output limit the practical application of conductive paper
These problems have greatly limited the further expansion of the application field of conductive paper.

Method used

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  • High-transparency conductive nano paper as well as convenient preparation method and application thereof
  • High-transparency conductive nano paper as well as convenient preparation method and application thereof
  • High-transparency conductive nano paper as well as convenient preparation method and application thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0038] A highly transparent conductive nano paper comprises nano cellulose paper and a transparent conductive ink layer covered on the nano cellulose paper, and the transparent conductive ink layer is prepared by curing a polymerizable deep eutectic solvent and a crosslinking agent.

[0039] The preparation process of described highly transparent conductive nano paper is as follows:

[0040] (1) Preparation of transparent conductive ink: Mix choline chloride and acrylic acid at a molar ratio of 1:2, heat and stir the mixture in a closed flask at 90°C for about 4 hours until a uniform clear and transparent solution PDES is formed, and then Crosslinking agent polyethylene glycol diacrylate and photoinitiator 2-hydroxyl-4'-(2-hydroxyethoxy)-2-methylpropiophenone are added in PDES, the addition of crosslinking agent and photoinitiator Both are 1wt.% of the total mass of PDES, and the PDES conductive ink can be prepared after ultrasonication for 10 minutes.

[0041] (2) Preparatio...

Embodiment 2

[0052] A highly transparent conductive nano paper comprises nano cellulose paper and a transparent conductive ink layer covered on the nano cellulose paper, and the transparent conductive ink layer is prepared by curing a polymerizable deep eutectic solvent and a crosslinking agent.

[0053] The preparation process of the nanocellulose paper described in this example is basically the same as that of Example 1, the difference is that the polymerizable deep eutectic solvent of this example is composed of choline chloride and methacrylic acid at a mass ratio of 1:1 at 90°C The reaction was obtained in 4h.

Embodiment 3

[0055] A highly transparent conductive nano paper comprises nano cellulose paper and a transparent conductive ink layer covered on the nano cellulose paper, and the transparent conductive ink layer is prepared by curing a polymerizable deep eutectic solvent and a crosslinking agent.

[0056] The preparation process of nanocellulose paper described in this example is basically the same as that of Example 1, the difference is that the polymerizable deep eutectic solvent of this example is reacted at 90°C by anhydrous betaine and crotonic acid at a mass ratio of 1:1.5 4h to get.

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Abstract

The invention discloses high-transparency conductive nano paper (TCNP) as well as a convenient preparation method and application thereof. The high-transparency conductive nano paper comprises nano cellulose paper and a transparent conductive ink layer covering the nano cellulose paper, and the transparent conductive ink layer is prepared by curing a polymerizable eutectic solvent, a cross-linkingagent and an initiator. According to the invention, the polymerizable eutectic solvent is used as the conductive ink, the nano cellulose paper is used as a transparent substrate, and the simple and efficient preparation of the high-transparency conductive nano paper is realized by combining a printing and coating process. The prepared high-transparency conductive nano paper shows excellent optical, mechanical and electrical properties. The TCNP conductive paper prepared by the invention also has excellent bending resistance and electrical stability, is successfully applied to a paper-based electroluminescent device, and plays a role in promoting the development of flexible electronic components.

Description

technical field [0001] The invention relates to the technical field of conductive paper, more specifically, the invention relates to highly transparent conductive nano paper and its convenient preparation method and application. Background technique [0002] As an important development direction of the electronics industry in the future, flexible and green functional electronic components are the development trend, and paper, as an ancient and widely used material, is light, portable, flexible, bendable, foldable, and biodegradable. , environmental friendliness and low price have attracted the attention of researchers. In addition, the mature papermaking technology also paves the way for fast, simple and low-cost paper-based electronics manufacturing processes. Therefore, these characteristics of paper endow it with infinite possibilities in the field of electronics in the future. However, traditional paper is prepared from natural cellulose with a diameter of 20-50 μm, wh...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D21H27/36D21H21/14D21H11/18D21J5/00C09D11/52G02F1/1523G02F1/153G02F1/1516B32B29/00B32B33/00
CPCD21H27/36D21H21/14D21H11/18D21J5/00C09D11/52G02F1/1523G02F1/1533G02F1/15165B32B29/005B32B33/00B32B2250/02B32B2250/26B32B2551/00
Inventor 何明辉张凯丽陈广学李仁爱田君飞
Owner SOUTH CHINA UNIV OF TECH
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