Organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and preparation method thereof

A network interpenetrating, three-dimensional porous technology, applied in the field of electrochemical energy storage, can solve problems such as safety hazards, and achieve the effect of improving electrical performance and improving interface compatibility.

Inactive Publication Date: 2021-02-19
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In addition, bridges, high-speed railways, and many other civil engineering structures present safety hazards due to vibration

Method used

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  • Organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and preparation method thereof
  • Organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and preparation method thereof
  • Organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] (1) Dissolve 10g of PAA in 80g of water, and fully stir at 500rpm at 25°C for 30min to obtain a uniform organic polymer aqueous solution;

[0042](2) adding 8g KOH to the aqueous solution of step (1), fully stirring at room temperature for 15 min at 500rpm to obtain a uniform organic polymer electrolyte;

[0043] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;

[0044] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.

[0045] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a cement cur...

Embodiment 2

[0047] (1) Dissolve 20g PAA in 80g water, fully stir for 30min at 500rpm at 25°C to obtain a uniform organic polymer aqueous solution;

[0048] (2) 8g KOH was added to the aqueous solution of step (1), fully stirred at 500rpm for 15min at room temperature to obtain a uniform organic polymer electrolyte;

[0049] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;

[0050] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.

[0051] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a cement curing room...

Embodiment 3

[0053] (1) 10g PEO was dissolved in 80g water, fully stirred at 500rpm at 25°C for 30min to obtain a uniform organic polymer aqueous solution;

[0054] (2) 20g LiCl was added to the aqueous solution of step (1), and the room temperature was fully stirred at 500rpm for 15min to obtain a uniform organic polymer electrolyte;

[0055] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;

[0056] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.

[0057] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a...

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Abstract

The invention relates to an organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and a preparation method thereof, the preparation method comprises the following steps: (1) weighing an organic polymer, dissolving in water, heating and uniformly stirring to obtain an organic polymer aqueous solution; (2) adding the ionic conductive phase into an organic polymeraqueous solution, and uniformly stirring at room temperature to obtain an organic polymer electrolyte; (3) adding cement powder into the organic polymer electrolyte, and uniformly stirring at room temperature to obtain uniform slurry; and (4) pouring the uniform slurry into a mold, carrying out hardening molding, and carrying out maintenance to obtain the target product. Compared with the prior art, the electrolyte with the three-dimensional porous structure has the advantages that the interfacial compatibility of the electrolyte with the three-dimensional porous structure and a structure electrode material is improved, and meanwhile, high comprehensive performance is realized.

Description

technical field [0001] The invention belongs to the technical field of electrochemical energy storage, and relates to a three-dimensional porous structure electrolyte with organic / inorganic network interpenetration and a preparation method thereof. Background technique [0002] With the continuous consumption of fossil fuels and the continuous emission of greenhouse gases, green and renewable electrical energy sources have been widely developed, such as solar energy, wind energy, tidal energy, geothermal energy, nuclear energy and electrochemical energy storage. Due to the challenges such as being affected by weather, geographical distribution, etc., these renewable electric energy sources will generate strong intermittency and randomness. Therefore, large-scale structural components are expected to be combined with the above-mentioned renewable electric energy sources to solve this problem, including electrochemical energy storage (battery), thermal energy storage (high tem...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01G11/56H01G11/84
CPCH01G11/56H01G11/84
Inventor 张东方翠琴
Owner TONGJI UNIV
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