Organic/inorganic network interpenetrating three-dimensional porous structure electrolyte and preparation method thereof
A network interpenetrating, three-dimensional porous technology, applied in the field of electrochemical energy storage, can solve problems such as safety hazards, and achieve the effect of improving electrical performance and improving interface compatibility.
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Embodiment 1
[0041] (1) Dissolve 10g of PAA in 80g of water, and fully stir at 500rpm at 25°C for 30min to obtain a uniform organic polymer aqueous solution;
[0042](2) adding 8g KOH to the aqueous solution of step (1), fully stirring at room temperature for 15 min at 500rpm to obtain a uniform organic polymer electrolyte;
[0043] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;
[0044] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.
[0045] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a cement cur...
Embodiment 2
[0047] (1) Dissolve 20g PAA in 80g water, fully stir for 30min at 500rpm at 25°C to obtain a uniform organic polymer aqueous solution;
[0048] (2) 8g KOH was added to the aqueous solution of step (1), fully stirred at 500rpm for 15min at room temperature to obtain a uniform organic polymer electrolyte;
[0049] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;
[0050] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.
[0051] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a cement curing room...
Embodiment 3
[0053] (1) 10g PEO was dissolved in 80g water, fully stirred at 500rpm at 25°C for 30min to obtain a uniform organic polymer aqueous solution;
[0054] (2) 20g LiCl was added to the aqueous solution of step (1), and the room temperature was fully stirred at 500rpm for 15min to obtain a uniform organic polymer electrolyte;
[0055] (3) adding 200g cement powder to the electrolyte of step (2), fully stirring at room temperature for 120s at 200r / min to obtain a uniform slurry;
[0056] (4) pour the uniform slurry in step (3) into 3*3*3cm 3 It was hardened and formed in a silica gel mold, and then put into a cement curing room (temperature 22° C., relative humidity 90%) for curing for 28 days. After demoulding, a cube-shaped electrolyte was obtained for mechanical property testing.
[0057] (5) Insert the cut stainless steel sheet into 1*1*1cm 3 After the two ends of the silicone mold, the uniform slurry in step (3) is poured into the mold to harden and form, and then put into a...
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