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Nano-diamond polishing solution for SiC substrate processing and preparation method thereof

A technology of nano-diamond and polishing fluid, which is applied in the fields of polishing compositions containing abrasives, semiconductor/solid-state device manufacturing, electrical components, etc., and can solve problems such as low polishing efficiency

Active Publication Date: 2021-04-02
ZHENGZHOU RES INST FOR ABRASIVES & GRINDING CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] Usually polished using nano-SiO 2 Polishing fluid, nano SiO 2 The Mohs hardness is about 6.8, and the Mohs hardness of the SiC substrate is about 9.5. The hardness of the abrasive is much lower than the hardness of the workpiece, and the polishing efficiency is low. Therefore, the polishing time often takes several hours, which is the bottleneck restricting the entire processing time.

Method used

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  • Nano-diamond polishing solution for SiC substrate processing and preparation method thereof
  • Nano-diamond polishing solution for SiC substrate processing and preparation method thereof
  • Nano-diamond polishing solution for SiC substrate processing and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] A nano-diamond polishing solution for processing SiC substrates, consisting of: 500g of water, 15g of diamond micropowder, 3g of fatty alcohol polyoxyethylene ether (dispersant), 25g of hydroxyethyl cellulose (suspending agent), and modified sodium polyacrylate (suspension agent) 25g, ethylene glycol 75g (lubricant), silicone defoamer 0.5g.

[0033] The preparation method of above-mentioned polishing fluid, comprises the steps:

[0034] S1. Get 100g of water and 3g of fatty alcohol polyoxyethylene ether to form a dispersant solution after uniform mixing;

[0035] S2. Under stirring conditions, slowly add 15g of 600nm diamond micropowder with wear-resistant abrasive particles / round abrasive particle number ratio of 1 to the dispersant solution, and use 500W ultrasonic wave to disperse for 90min until the diamond micropowder is completely dispersed and uniform, forming diamond micropowder Dispersions;

[0036] S3. Take 400g of water, add 25g each of hydroxyethyl cellulo...

Embodiment 2

[0039] A preparation method of nano-diamond polishing liquid for SiC substrate processing, comprising the steps of:

[0040] S1. Take 100g of water and mix evenly with 3g of sodium citrate to form a dispersant solution.

[0041] S2. Under stirring conditions, slowly add 15g of 600nm diamond micropowder with wear-resistant abrasive grains / circular abrasive grain number ratio of 3 to the dispersant solution, and disperse with 500W ultrasonic wave for 90min to form diamond micropowder dispersion liquid.

[0042] S3. Take 400g of water, add 25g each of hydroxyethyl cellulose and modified sodium polyacrylate, fully stir to dissolve evenly, and form a suspending agent solution.

[0043] S4. Mix the diamond micropowder dispersion and suspending agent solution evenly, add 75g of ethylene glycol and 0.5g of silicone defoamer in sequence, and stir evenly.

Embodiment 3

[0045] A preparation method of nano-diamond polishing liquid for SiC substrate processing, comprising the steps of:

[0046] S1. Take 100g of water and 3g of fatty alcohol polyoxyethylene ether and mix them uniformly to form a dispersant solution.

[0047] S2. Under stirring conditions, slowly add 15g of 600nm diamond micropowder with wear-resistant abrasive grains / circular abrasive grain number ratio of 6 to the dispersant solution, and disperse with 500W ultrasonic wave for 90min to form diamond micropowder dispersion liquid.

[0048] S3. Take 400g of water, add 25g each of hydroxyethyl cellulose and modified sodium polyacrylate, fully stir to dissolve evenly, and form a suspending agent solution.

[0049] S4. Mix the diamond micropowder dispersion and suspending agent solution evenly, add 75g of ethylene glycol and 0.5g of silicone defoamer in sequence, and stir evenly.

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Abstract

The invention discloses a nano-diamond polishing solution for SiC substrate processing and a preparation method thereof, and belongs to the technical field of ultra-precision grinding and polishing. The polishing solution consists of the following raw materials in parts by weight: 50-85 parts of water; 0.5-15 part of diamond micro powder; 0.1-5 part of a dispersing agent; 0.1-5 part of a suspending agent; 1-40 parts of a lubricant; and 0.001-0.1 part of defoamer, wherein the particle size of the diamond micro-powder is 10-1000 nm, the ratio of the number of the wear-resistant abrasive particles to the number of the round abrasive particles in the diamond micro-powder is 1-15: 1, and the round abrasive particles are obtained when the roundness Fc is larger than 0.950, and wear-resisting abrasive particles are obtained when Fc is more than or equal to 0.900 and less than or equal to 0.950. According to the polishing solution, the morphology composition of the diamond micro-powder is controlled, the polishing efficiency is improved through the wear-resisting abrasive particles, the surface damage layer and roughness are repaired through the round abrasive particles, and thus polishingscratching is controlled.

Description

technical field [0001] The invention belongs to the field of ultra-precision grinding and polishing, and in particular relates to a nano-diamond polishing liquid for SiC substrate processing and a preparation method thereof. Background technique [0002] As a typical representative of the third-generation semiconductor materials, SiC has formed a global industrial chain of materials, devices and applications. Due to its excellent performance in high temperature, high frequency, radiation resistance, and high power applications, it is widely used in core industries such as national defense armaments, 5G mobile communications, energy Internet, new energy vehicles, and rail transit. The new generation of "golden track" in the semiconductor industry and the reputation of "green energy devices" that drive the energy revolution have catalyzed the hot spot of "the one who wins SiC wins the world". [0003] The purpose of polishing is to remove the scratches, pits and other mechani...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09G1/02H01L21/304
CPCC09G1/02H01L21/304
Inventor 徐明艳代克豁国燕冯兵强马亚飞
Owner ZHENGZHOU RES INST FOR ABRASIVES & GRINDING CO LTD
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