High-strength electronic copper foil preparation method
An electronic copper foil, high-strength technology, applied in the direction of electroforming, electrolysis, etc., can solve the problem of low tensile strength of electrolytic copper foil, achieve excellent mechanical properties, meet the needs of development, and high elongation
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Embodiment 1
[0013] A method for preparing high-strength electronic copper foil according to an embodiment of the present invention includes the following steps:
[0014] Step S1, dissolving copper rods and copper wires into an aqueous solution with sulfuric acid as the main electrolyte, the contents of copper and sulfuric acid in the main electrolyte are 80g / L and 100g / L respectively;
[0015] Step S2, put additives into the main electrolyte, the additives include A agent, B agent, C agent,
[0016] The A agent is thiazolethione at 5 mg / l, the B agent is 8 mg / l 3-mercapto-1-propanesulfonate sodium, and the C agent is 10 mg / l polyethylene glycol;
[0017] Step S3, at a temperature of 55°C and a flow rate of 50 3 / h, the current density is 3000A / m 2 Under certain conditions, the main electrolyte with additives is electrolyzed;
[0018] Step S4: The main electrolyte is electrolyzed to electrodeposit a thickness of 9um on the cathode to obtain high-strength electronic copper foil.
Embodiment 2
[0020] A method for preparing high-strength electronic copper foil according to an embodiment of the present invention includes the following steps:
[0021] Step S1, dissolving copper rods and copper wires into an aqueous solution with sulfuric acid as the main electrolyte, the contents of copper and sulfuric acid in the main electrolyte are 95g / L and 120g / L respectively;
[0022] Step S2, put additives into the main electrolyte, the additives include A agent, B agent, C agent,
[0023] The A agent is thiazolethione at 5 mg / l, the B agent is 8 mg / l 3-mercapto-1-propanesulfonate sodium, and the C agent is 10 mg / l polyethylene glycol;
[0024] Step S3, at a temperature of 55°C and a flow rate of 50 3 / h, the current density is 3000A / m 2 Under certain conditions, the main electrolyte with additives is electrolyzed;
[0025] Step S4: The main electrolyte is electrolyzed to electrodeposit a thickness of 12um on the cathode to obtain high-strength electronic copper foil.
Embodiment 3
[0027] A method for preparing high-strength electronic copper foil according to an embodiment of the present invention includes the following steps:
[0028] Step S1, dissolving the copper rod, copper wire, and chloride into an aqueous solution with sulfuric acid as the main electrolyte, the contents of copper, sulfuric acid, and chlorine in the main electrolyte are respectively 80g / L, 100g / L, and 25mg / L;
[0029] Step S2, put additives into the main electrolyte, the additives include A agent, B agent, C agent,
[0030] The A agent is 18 mg / l fatty amine ethoxy sulfonate, the B agent is 20 mg / l sodium polydithiodipropane sulfonate and 2-mercaptobenzimidazole, and the C agent is 10 mg / l Sodium dodecylbenzenesulfonate;
[0031] Step S3, when the temperature is 55°C and the flow rate is 45 3 / h, the current density is 5600A / m 2 Under certain conditions, the main electrolyte with additives is electrolyzed;
[0032] Step S4: The main electrolyte is electrolyzed to electrodeposi...
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