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A kind of high temperature resistant boiled polypropylene composite material and preparation method thereof

A technology of composite materials and polypropylene, which is applied in the field of high-temperature-resistant boiled polypropylene composite materials and its preparation, can solve the problems of difficulty in passing the high-temperature boil-resistant test of painted parts, harsh test conditions, and failure, and achieve low catalyst residues , Narrow molecular weight distribution and low molecular weight content

Active Publication Date: 2022-06-07
TIANJIN KINGFA NEW MATERIAL
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

When testing the base material of the same painted part, the last test method is the method of soaking in boiling water at 99 °C for 4 hours. The test conditions are the most severe, and the failure phenomenon is the most likely to occur. It is the most difficult to pass the high temperature boiling test of the painted parts.

Method used

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  • A kind of high temperature resistant boiled polypropylene composite material and preparation method thereof
  • A kind of high temperature resistant boiled polypropylene composite material and preparation method thereof
  • A kind of high temperature resistant boiled polypropylene composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0031]A high temperature resistant boiling polypropylene composite material, the composite material is made of raw materials including the following parts by mass: metallocene polypropylene Metocene HM640T 49kg, high crystalline polypropylene BX3900 30kg, crystalline POE ENGAGE XLT8677 10kg, talc TYT-777A 10kg, carbon black masterbatch 2718 1kg, main antioxidant AO-330 0.15kg, auxiliary antioxidant 168 0.3kg, acid scavenger BS-2818 0.2kg, lubricant TR451 0.2kg.

[0032] The preparation method of the high temperature resistant boiling polypropylene composite material comprises the following steps: mixing the metallocene polypropylene, high crystalline polypropylene, talc powder, crystalline thermoplastic polyolefin elastomer, and carbon black masterbatch , Antioxidant, lubricant and acid scavenger are added into the twin-screw extruder from the main feeding port of the screw extruder, and after the melt physical blending, extrusion, water cooling, water removal, pelletizing and ...

Embodiment 2

[0034] A high temperature resistant boiling polypropylene composite material, the composite material is made from raw materials including the following parts by weight: metallocene polypropylene Metocene HM640T 49kg, high crystalline polypropylene BX3900 20kg, crystalline POE ENGAGE XLT8677 15kg, talc TYT-777A 15kg, carbon black masterbatch 2718 1kg, main antioxidant AO-330 0.15kg, auxiliary antioxidant 168 0.3kg, acid scavenger BS-2818 0.2kg, lubricant TR451 0.2kg.

[0035] The preparation method of the high temperature resistant boiling polypropylene composite material is the same as that in Example 1.

Embodiment 3

[0037] A high temperature resistant boiling polypropylene composite material, the composite material is made from raw materials including the following parts by weight: metallocene polypropylene Metocene HM640T 49kg, high crystalline polypropylene BX3900 10kg, crystalline POE ENGAGE XLT8677 20kg, talc TYT-777A 20kg, carbon black masterbatch 2718 1kg, main antioxidant AO-330 0.15kg, auxiliary antioxidant 168 0.3kg, acid scavenger BS-2818 0.2kg, lubricant TR451 0.2kg.

[0038] The preparation method of the high temperature resistant boiling polypropylene composite material is the same as that in Example 1.

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Abstract

The invention provides a high-temperature-resistant boiled polypropylene composite material and a preparation method thereof. The composite material is made of the following raw materials by weight: 20-70 parts of metallocene polypropylene (mPP), 10-40 parts of high-crystalline polypropylene , 5-20 parts of crystalline POE, 5-25 parts of mineral powder, 0.8-1.5 parts of carbon black masterbatch, 0.1-0.6 parts of antioxidant, 0.1-0.2 parts of lubricant, and 0.1-0.2 parts of acid scavenger. The high-temperature-resistant boiled polypropylene composite material of the present invention adopts the method of blending mPP with a rather narrow molecular weight distribution and a small amount of high-crystallization PP (between 47-50%) to obtain a compound with high fluidity, narrow molecular weight distribution, and high crystallinity. The blended PP with the characteristics of low molecular weight content, low content of small molecular weight and low metallocene catalyst residue is used as the new PP matrix of the present invention, and other components and additives are added in the same way.

Description

technical field [0001] The invention belongs to the field of polymer materials, and in particular relates to a high temperature resistant boiling polypropylene composite material and a preparation method thereof. Background technique [0002] The polypropylene composite material for automobile exterior parts is mainly made of automobile bumper body, grille, wheel eyebrow, side beam, etc. by injection molding, and the finished product is obtained by spraying primer, topcoat and varnish. These painted exterior parts often encounter water (such as muddy water, rainwater, dew, etc.), and as a result, the phenomenon of loss of gloss, peeling, wrinkling and blistering occurs. Therefore, the high temperature boiling test of substrates and coatings is an important indicator for evaluating painted parts. The current effective coating test methods for high temperature boiling resistance are as follows: 23°C water immersion (240h) test method at room temperature, 40°C water immersion ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/12C08L23/08C08K13/02C08K5/13C08K5/526C08K3/34C08K3/04
CPCC08L23/12C08L2205/035C08L2201/08C08L2205/025C08L23/0815C08K13/02C08K5/13C08K5/526C08K3/34C08K3/04
Inventor 李欣李晟徐昌竹张海洋张春怀张栋玮钱文轩
Owner TIANJIN KINGFA NEW MATERIAL
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