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Method for preparing transparent flexible electrode based on ionic liquid and flexible solar cell

A technology of solar cells and ionic liquids, applied in the manufacture of semiconductor/solid-state devices, circuits, electrical components, etc., can solve the problems of large contact resistance of transparent electrodes, poor electrical and mechanical properties, high technology, etc., to improve electrical properties and mechanical properties. Good performance, stability and repeatability

Active Publication Date: 2021-06-22
SUZHOU UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The electrical and mechanical properties of transparent flexible electrodes play a vital role in the photoelectric conversion efficiency of solar cells. At present, transparent flexible electrodes are mainly prepared by direct spin-coating silver nanowire solution, but the prepared transparent electrodes have large contact resistance. , poor electrical and mechanical properties; and the existing methods of improving the electrical properties and adhesion of transparent flexible electrodes generally require higher processes and / or greater energy consumption

Method used

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  • Method for preparing transparent flexible electrode based on ionic liquid and flexible solar cell
  • Method for preparing transparent flexible electrode based on ionic liquid and flexible solar cell
  • Method for preparing transparent flexible electrode based on ionic liquid and flexible solar cell

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0042] (1) Add ionic liquid, silver nitrate, and acetic acid into water to obtain an ionic liquid solution, in which the volume concentration of the ionic liquid is 0.125‰, the volume concentration of acetic acid is 0.5‰, and the concentration of silver nitrate is 0.017mg / mL; the ionic liquid is as follows :

[0043]

[0044] 0.3 mL of the above ionic liquid solution was added to 0.7 mL of silver nanowire aqueous solution to obtain a silver nanowire aqueous solution doped with ionic liquid solution, wherein the volume percentage of the ionic liquid solution was 30%, and the concentration of silver nanowire was 0.25 wt%.

[0045] (2) Spin-coat an aqueous solution of silver nanowires doped with an ionic liquid solution on a flexible transparent substrate, 2000 rpm for 40 s without heating, and then spin-coat 10 mg / mL aluminum-doped oxide on the silver nanowires doped with an ionic liquid. Zinc aqueous solution, 2000 rpm 60 s, 120 o C annealed for 15 minutes, then spin-coated...

Embodiment 2

[0057] The transparent flexible electrode prepared in Example 1 was placed in a nitrogen glove box, and the active layer solution was spin-coated on the surface of the conductive layer. The components of the solution were PBDB-T-2F and Y6, the solvent was pure CF, and the composition concentration was 16 mg / mL of solution, the rate of dispensing is 3000 rpm, the time is 30s, after the dispensing is completed, at 110 o Annealing at C for 10 minutes to obtain an active layer; then, in a coating machine, a molybdenum trioxide hole transport layer and an Al electrode were evaporated on the surface of the active layer with thicknesses of 10 nm and 100 nm, respectively. So far, the flexible solar cell has been prepared. It is a flexible organic solar cell prepared from silver nanowires doped with ionic liquid solution. The structure and photos are shown in Figure 6 .

[0058] The transparent flexible electrode prepared by the silver nanowires not doped with the ionic liquid solut...

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Abstract

The invention discloses a method for preparing a transparent flexible electrode based on an ionic liquid and a flexible solar cell, and relates to a flexible organic solar cell which can be completed at a low temperature, is easy to prepare, is relatively low in cost and is relatively high in efficiency. The transparent flexible electrode with better electrical properties and mechanical properties can be obtained, the surface resistance is as low as 12 omega / sq, the transparent flexible electrode has excellent mechanical properties, and particularly, the transparent flexible electrode is combined with an active layer and the like to prepare a flexible solar cell with excellent properties, and an unexpected technical effect is achieved.

Description

technical field [0001] The invention relates to a transparent flexible electrode, in particular to a novel transparent flexible electrode in a flexible organic solar cell and a preparation method thereof, in particular to a method for preparing a novel transparent flexible electrode from silver nanowires doped with an ionic liquid solution and the prepared flexible electrode. organic solar battery. Background technique [0002] Flexible optoelectronic devices based on organic materials are a major trend in the development of flexible electronic devices in the future and have great application prospects. However, obtaining high-performance transparent flexible electrodes is the prerequisite for realizing high-efficiency flexible organic optoelectronic devices, and it is also the core problem in this field. Regarding how to obtain transparent flexible electrodes with high conductivity, high light transmission, simple preparation methods, and green, remains a huge challenge. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): H01L51/44H01L51/48
CPCH10K71/60H10K30/82H10K77/111Y02E10/549
Inventor 陈潇斌刘硕陈扬
Owner SUZHOU UNIV