Film roll
A film roll and protective film technology, applied in the direction of layered products, synthetic resin layered products, chemical instruments and methods, etc., can solve the problems of increased manufacturing cost, the curled part cannot be well fitted, etc., to prevent curling Effect
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[0294] Hereinafter, the present invention will be described in further detail through examples. Unless otherwise stated, "%" and "part" in an example mean mass % and a mass part.
[0295] First, the measurement methods are collectively described.
[0296]
[0297] Gel Permeation Chromatography Assay
[0298] (1) Pretreatment method
[0299] Dissolve the sample in γ-butyrolactone to make a 20% by mass solution, then dilute it to 100 times with the eluent of N,N-dimethylformamide (sometimes described as DMF), and pass through a 0.45 μm membrane filter Filtration was performed, and the resulting solution was used as a measurement solution.
[0300] (2) Measurement conditions
[0301] Column: TSKgel SuperAWM-H×2+SuperAW2500×1 (inner diameter 6.0mm, length 150mm, 3 connections)
[0302] Eluent: DMF (added with 10mmol / L lithium bromide)
[0303] Flow: 0.6mL / min
[0305] Column temperature: 40°C
[0306] Injection volume: 20μL
[0307] Molec...
manufacture example 1
[0340] Production example 1: Production of polyamideimide resin 1
[0341] Under a nitrogen atmosphere, a reaction vessel equipped with a stirring blade in a detachable flask and an oil bath were prepared. Into the reaction container installed in the oil bath, 45 parts of TFMB and 768.55 parts of DMAc were charged. While stirring the contents of the reaction vessel at room temperature, TFMB was dissolved in DMAc. Next, 19.01 parts of 6FDA was further injected into the reaction container, and the contents in the reaction container were stirred at room temperature for 3 hours. Then, 4.21 parts of OBBC were put into the reaction container, and then 17.30 parts of TPC were put into the reaction container, and the content in the reaction container was stirred at room temperature for 1 hour. Next, 4.63 parts of 4-picoline and 13.04 parts of acetic anhydride were further put into the reaction container, and the contents in the reaction container were stirred at room temperature for...
manufacture example 2
[0343] Production Example 2: Preparation of Silica Sol 1
[0344] A GBL-substituted silica sol was prepared by solvent substitution using an amorphous silica sol produced by the sol-gel method and having an average primary particle diameter of 27 nm measured by the BET method as a raw material. The obtained sol was filtered with a membrane filter having a mesh size of 10 μm to obtain GBL-substituted silica sol 1 . In the obtained GBL-substituted silica sol, the content of silica particles was 30% by mass.
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