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Oriented electrical steel sheet and manufacturing method thereof

A technology of oriented electrical steel sheets and steel sheets, which is applied to circuits, electrical components, manufacturing tools, etc., can solve the problems of low-efficiency preparation methods, rising energy costs, and falling yields, and achieve excellent magnetic properties, high magnetic flux density, Excellent magnetic properties

Pending Publication Date: 2021-08-10
浦项股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0016] And this kind of heat treatment, along with the high-temperature heating to the steel billet, causes the energy cost to rise, and the steel billet washing (washing) phenomenon that the steel billet melts at a high temperature occurs, and edge cracks (edge ​​cracks) are generated during hot rolling, resulting in a decrease in yield, Can be considered a costly and inefficient preparation method
[0017] In addition, although high magnetic flux density characteristics can be ensured by adding Bi, most of the patents proposed in the past are directed at the surface and the unstable formation of secondary recrystallization caused by the main addition of Bi, and in order to overcome this Side effects, various improvement schemes are proposed for the process after hot rolling, but it is difficult to achieve stable production in the actual preparation process, requiring a lot of trial and error and exploration

Method used

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  • Oriented electrical steel sheet and manufacturing method thereof
  • Oriented electrical steel sheet and manufacturing method thereof
  • Oriented electrical steel sheet and manufacturing method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0107] As shown in Table 1 below, C, Si, Mn, acid-soluble Al, N, S, Se, Cu, Ni, Cr and Mo are used as the basic composition, and the contents of P, Sn, Sb, Ge, As, Pb and Bi are changed to To prepare steel, the steel of this composition system is vacuum-dissolved to prepare cast slabs.

[0108] After heating this slab to a temperature of 1150° C., rough rolling was performed six times to prepare a 40 mm bar, and after that, it was hot rolled to a thickness of 2.3 mm, cooled rapidly to 600° C., and then coiled.

[0109] At this time, for the first, second, and third rough rolling, rolling is performed at a rolling reduction of 20% or more, so that rough rolling is performed at a total cumulative rolling reduction of 60% or more.

[0110] Such a hot-rolled steel sheet was annealed at 1050° C., pickled, and then subjected to strong cold rolling so that the thickness of the steel sheet became 0.23 mm.

[0111] For the cold-rolled steel sheet, after heating to 850° C. at a heating...

Embodiment 2

[0121] A steel slab having the composition of Invention Material 12 evaluated in Example 1 and produced by vacuum dissolution was heated at 1200°C.

[0122] After rough rolling was performed by changing the number of times of rough rolling and rolling reduction on the heated billet, a hot rolled sheet having a thickness of 2.6 mm was prepared by hot rolling.

[0123] Such a hot-rolled steel sheet was subjected to hot-rolled sheet annealing at 1080° C., pickling, and then strong cold rolling so that the thickness of the steel sheet became 0.30 mm.

[0124] For the cold-rolled steel plate, after heating to 860°C at a heating rate of 30°C / sec, it is kept in a wet mixed atmosphere of hydrogen, nitrogen, and ammonia for 150 seconds to recrystallize once, and nitriding treatment is carried out at the same time, so that The total nitrogen content of the steel sheet was 180 ppm.

[0125] Next, an annealing separator mainly composed of MgO is coated on the steel sheet, and the final h...

Embodiment 3

[0132] A steel slab having the composition of Invention Material 8 evaluated in Example 1 and produced by vacuum dissolution was heated at 1130°C.

[0133] A total of six times of rough rolling are carried out on the heated billet, among which the reduction ratio of 20% or more is adopted in the third, fourth, fifth and sixth rough rolling, and the rough rolling is carried out with a cumulative reduction ratio of 76.0%. , After preparing a 60mm bar, it was hot-rolled to a thickness of 2.3mm.

[0134] Such a hot-rolled steel sheet was annealed at 1100° C., pickled, and then subjected to strong cold rolling so that the thickness of the steel sheet became 0.23 mm.

[0135] During cold rolling, change the rolling temperature to 50-350°C and perform rolling until the thickness becomes the thickness of the final product, then heat the cold-rolled steel sheet to 855°C at a heating rate of 70°C / sec, , nitrogen, and ammonia in a mixed atmosphere for 180 seconds to cause primary recrys...

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Abstract

Provided is an oriented electrical steel sheet according to one embodiment of the present invention, comprising by weight%: 0.01% or less (excluding 0%) or 0.01% to 0.1% of C; 2.0% to 4.0% of Si; 0.01% to 0.20% of Mn; 0.040% or less (excluding 0%) of acid soluble Al; 0.008% (excluding 0%) of N; 0.008% (excluding 0%) of S; 0.0001% to 0.008% of Se; 0.002% to 0.1% of Cu; 0.005% to 0.1% of Ni; 0.005% to 0.1% of Cr; 0.005% to 0.1% of P; and 0.005% to 0.20% of Sn, and comprising one or more of 0.0005% to 0.10% of Sb, 0.0005% to 0.10% of Ge, 0.0005% to 0.10% of As, 0.0001% to 0.10% of Pb, 0.0001% to 0.10% of Bi, and 0.001% to 0.1% of Mo, and the balance of Fe and other unavoidable impurities, wherein a magnetic flux density (B8) after a final secondary recrystallization is 1.92 Tesla or more.

Description

technical field [0001] The invention relates to a oriented electrical steel plate and a preparation method thereof. More specifically, it relates to a grain-oriented electrical steel sheet and a preparation method thereof that can further increase the magnetic flux density by controlling the composition of the steel sheet and controlling the rolling conditions during hot rolling to form a crystal orientation with excellent aggregation. Background technique [0002] Since grain-oriented electrical steel sheets are used as core materials for electronic products such as large rotating machines such as transformers and generators, in order to improve energy conversion efficiency by reducing power consumption of electronic equipment, a magnetic flux density of the core material is required Electrical steel sheet with high iron loss and excellent magnetic properties. [0003] Grain-oriented electrical steel sheet refers to the texture (also known as "Gaussian texture (Goss textur...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C22C38/34C22C38/42C22C38/00C22C38/04C22C38/06C21D8/12
CPCC22C38/34C22C38/42C22C38/04C22C38/06C22C38/02C22C38/008C21D9/46C21D8/1205C21D8/1222C21D8/1255C21D8/1233C21D8/1283C21D2201/05C21D6/008C21D8/1272C21D1/76C21D8/1266H01F1/16H01F1/14775C22C38/001C22C2202/02C21D6/004C21D6/005C21D8/1261C22C38/002C22C38/44C22C38/60H01F1/147
Inventor 韩奎锡朴昶洙金承日具周泳金载柳善英
Owner 浦项股份有限公司
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