Rubber composition and tire
A rubber composition, rubber technology, applied in special tires, tire parts, transportation and packaging, etc., can solve the problem of rapid disappearance of the effect, and achieve the effect of improving the overall performance
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[0185] The present invention is specifically described with reference to examples, but the present invention is not limited to the examples.
[0186] The microstructure and weight average molecular weight (Mw) of the rubber components used were evaluated as described below.
[0187]
[0188] The amount of structural units of the (co)polymer was measured using an AV400 NMR analyzer and data analysis software TOP SPIN 2.1 (both purchased from Bruker).
[0189]
[0190] The weight average molecular weight (Mw) is measured by gel permeation chromatography (GPC) under the following conditions (1) to (8).
[0191] (1) Device: HLC-8220 purchased from Tosoh Corporation;
[0192] (2) Separation chromatographic column: HM-H (2 in series) purchased from Tosoh Corporation;
[0193] (3) Measuring temperature: 40°C;
[0194] (4) Carrier: tetrahydrofuran;
[0195] (5) Flow rate: 0.6mL / min;
[0196] (6) Injection volume: 5 μL;
[0197] (7) Detector: differential refractometer;
[0...
Synthetic example 1
[0204] : hydrogenated styrene-butadiene rubber (hydrogenated SBR, styrene content: 34 mass%, vinyl-butadiene content: 0 mass%, cis or trans butadiene content: 5 mass%, ethylene content: 61% by mass, Mw: 250,000, hydrogenation degree of butadiene unit: 93% by mass), synthesized in Synthesis Example 1 below;
[0205] : Modified styrene-hydrogenated butadiene-styrene block copolymer terminated with alkoxysilyl group (modified SEBS, styrene content: 25% by mass, butadiene unit Degree of hydrogenation: 90% by mass, vinyl-butadiene unit content (based on hydrogenated butadiene units as 100% by mass): 0% by mass, cis-butadiene unit content (based on hydrogenated butadiene units Alkene unit (100% by mass): 5% by mass, Mw: 150,000, iodine value: 10), the modified copolymer ( The chain-end modified SBS block copolymer) is obtained by catalytic hydrogenation of Ti, and the difference is to change the amount of styrene introduced and other conditions;
[0206] : Block copolymer (tetrame...
Embodiment 4
[0262] Comparison between Example 4 and Comparative Examples 2 to 4 shows that processability, ozone resistance, The overall performance of , handling stability, abrasion resistance and fracture resistance is synergistically improved.
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