Magnet preform, magnet assembly and preparation method thereof
A technology of magnet assemblies and prefabricated parts, which is applied in the manufacture of permanent magnets, magnets, magnetic objects, etc., and can solve problems such as reducing the bonding performance of epoxy resins
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[0065]
[0066] The magnet assembly of the present invention is obtained through the steps of spraying, pre-curing and curing. The expandable composition for spraying on the surface of the magnet body can be prepared by the following method. The description will be made below.
[0067] (a) reacting ammonium polyphosphate, aliphatic polyol and epoxy resin, and cooling to obtain a first reactant; preferably, reacting ammonium polyphosphate, aliphatic polyol and epoxy resin in the presence of a solvent.
[0068] (b) reacting the first reactant with water-soluble carbodiimide or a salt thereof and N-hydroxysuccinimide or a derivative thereof to obtain a composition.
[0069] According to one embodiment of the present invention, the expandable composition is prepared by the following method:
[0070] (a) in the presence of a solvent, first reacting ammonium polyphosphate, aliphatic polyol and epoxy resin at low temperature, then at high temperature, and cooling to room temperat...
Embodiment 1 and comparative example 1~3
[0089] According to the formula in Table 1, ammonium polyphosphate, pentaerythritol, epoxy resin, triethylenetetramine and cyclohexanone were reacted at 50 °C for 4 hours, then heated to 80 °C for 2 hours, and cooled to room temperature to obtain the first reactant.
[0090] The first reactant was reacted with 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride (EDC) at 25°C for 3 h to obtain a pre-reactant; then the pre-reactant was reacted with N-hydroxysuccinimide (NHS) was reacted at 25° C. for 4 h to obtain swellable compositions (Example 1 and Comparative Example 3) or non-swellable compositions (Comparative Examples 1-2).
[0091] Table 1
[0092] Numbering Ammonium polyphosphate Pentaerythritol epoxy resin triethylenetetramine Cyclohexanone EDC NHS Example 1 15wt% 10wt% 35wt% 15wt% 15wt% 5wt% 5wt% Comparative Example 1 — — 35wt% 32.5wt% 32.5wt% — — Comparative Example 2 — — 35wt% 27.5wt% 27....
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