Color and conductivity dual-mode gas sensing device and preparation and use methods thereof
A technology of gas sensing and sensing devices, which is applied in measuring devices, color/spectral characteristic measurement, material analysis through electromagnetic means, etc., can solve the problems of low accuracy and reliability of sensing methods, and improve the system Stability, improve reliability, reduce the effect of false alarm rate
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Embodiment 1
[0039] like figure 1 As shown, a dual-mode gas sensing device of color and conductance, the sensing device includes a ceramic heating chip 10 and a metal oxide thin film 11 attached to the ceramic heating chip 10 . The metal oxide film 11 is a titanium dioxide film, and both ends of the ceramic heating chip 10 are provided with electrodes 20 and wires 21 . The wire 21 is connected to a gas sensitive detector, and a color detector 30 connected to a spectrometer is also arranged on the titanium dioxide film.
[0040] In this embodiment, the thickness of the titanium dioxide film is 1 μm, the ceramic heating plate 10 is a commercial ceramic heating plate 10 with a size of 30 mm×30 mm×3 mm, and the electrode 20 is a gold electrode.
[0041] The gas sensitive detector uses a commercial sensitive instrument such as the portable single-channel gas sensitive tester (model ZWX-P1) of Nanjing Zhiweixin formula, which is used to collect the conductance change of the titanium dioxide fil...
Embodiment 2
[0043] The method for preparing the sensing device in Example 1, the steps are as follows:
[0044] S1. Mix 0.1g of anatase titanium dioxide nanoparticles (p25) powder with 5 mL of deionized water, and fully sonicate in the ultrasonic pool until a uniform colloidal solution is formed;
[0045] S2. Take 0.1mL colloidal solution and drop it on the clean alumina ceramic heating plate 10, and spin-coat it at a working speed of 10-200r / min in a spin coater;
[0046] S3. After the colloidal solution to be spin-coated is dried, repeat the above S2 a total of 5 times, namely to make a ceramic heating plate 10 with a titanium dioxide film, and the thickness of the titanium dioxide film is 1 μm;
[0047] S4. Physically sputter-deposit gold electrodes at both ends of the ceramic heating chip 10 prepared in S3 by covering, and connect wires 21 to the gold electrodes, and set a color detector 30 on the titanium dioxide film;
[0048] S5. Connect the lead wires 21 at both ends of the ceram...
Embodiment 3
[0050] Utilize sensor in embodiment 1 to measure target gas, gas is concentration 100ppm ethanol vapor, method is as follows:
[0051] S1. Place the alumina ceramic heater 10 attached with a titanium dioxide film in the target gas environment to be measured, set the temperature of the ceramic heater 10 to 200°C through the heating function of the ceramic heater 10, and then the working temperature of the sensing device is 200°C ;
[0052] S2. Turn on the gas sensitivity tester, the color detector 30 and the UV-vis spectrometer, and record the optical absorption spectrum and conductivity change of the titanium dioxide film.
[0053] When the target gas appears in the environment, it can be observed that the color of the titanium dioxide film changes and gradually turns yellow.
[0054] In this embodiment, the change of titanium dioxide film resistance in the monitoring process is as follows: figure 2As shown, it can be seen that the resistance of the titanium dioxide film dr...
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