Positive electrode for lithium ion secondary battery, positive electrode sheet for lithium ion secondary battery, and manufacturing method thereof
A secondary battery, lithium ion technology, used in electrode manufacturing, secondary batteries, battery electrodes, etc., can solve the problems of increased insulating material costs, increased thickness of battery cells, cracks, etc., and achieves the effect of reducing manufacturing costs.
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no. 1 Embodiment approach
[0080] The electrode according to this embodiment is a positive electrode for a lithium ion secondary battery. figure 1 It is a partial sectional view of the electrode sheet 10 for explaining the structure of the positive electrode electrode for lithium ion secondary batteries of this embodiment. Positive electrodes for lithium-ion secondary batteries from figure 2 The electrode sheet 10 is cut out and produced. figure 1 For viewing from the direction of arrow I figure 2 The cross-sectional view at the line I-I of the electrode sheet 10.
[0081] The positive electrode for the lithium ion secondary battery of the present embodiment has a current collector (hereinafter also referred to as metal foil 9 ), and a first composite material containing at least a positive electrode active material provided on at least one surface of the current collector (metal foil 9 ). The material layer 11 and the second composite material layer 12 partially covered by the first composite mate...
Embodiment 1
[0215] Figure 9 (a1)~ Figure 9 (a3) is a figure which shows the flow of the manufacturing method of the electrode sheet 10 of Example 1 of this invention.
[0216] Such as Figure 9 Shown in (a1), in embodiment 1, as image 3 , Figure 6 As explained in , firstly, the second composite material layer 12 is coated on at least one surface of the metal foil 9 through step A1 or step A2. Therefore, the position of the die coater 22 of the coating device of the second composite material layer 12 can be set at a height h1 close to the upper surface of the metal foil 9 . which can be lower than Figure 9 The position of the die coater 22 of the coating device of the comparative example of (b2), that is, the height h2.
[0217] In this way, the die coater 22 can be arranged close to the metal foil 9, so as Figure 9 As shown in (a2), thin film coating of the second composite material layer 12 can be performed.
[0218] and, if Figure 9 As shown in (a3), the first composite ...
Embodiment 2
[0224] Figure 10 (a) and Figure 10 (b) is a diagram schematically showing a cross-sectional view of a lithium ion secondary battery of Example 2 fabricated using the positive electrode of the present invention.
[0225] Figure 10 The battery 150 of Example 2 shown in (a) uses the positive electrode 121 of the present invention having the second composite material layer 12 containing a conductive substance. Such as Figure 10 As shown in (a), under the situation that metal foreign matter 32 is mixed in the second composite material layer 12 in the step, metal foreign matter 32 is oxidized as the metal ion (M + ) dissolved in the electrolyte. If it reaches the negative side, then as Figure 10 As shown in (b), metal ions undergo a reduction reaction on the surface of the negative electrode at a reduction potential to form metal (M) and precipitate.
[0226] However, even if the deposited metal grows and breaks through the isolation film 120, when it reaches the second c...
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Abstract
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Application Information
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