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Polydopamine modified aluminum triphosphate corrosion inhibitor as well as preparation method and application thereof

A technology of aluminum tripolyphosphate and polydopamine, which is applied in coatings and devices for coating liquid on the surface, etc., can solve the problems of complex preparation components and processes, high cost, etc., reduce corrosion and rust, and improve compactness , long-lasting anti-corrosion effect

Pending Publication Date: 2021-12-07
JIMEI UNIV +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0006] In order to solve the problems of complex preparation components and process and high cost in the corrosion inhibitors with better corrosion inhibition effect in the above-mentioned prior art, the present invention provides a preparation of polydopamine modified aluminum tripolyphosphate corrosion inhibitor The method, wherein, comprises the following preparation steps:

Method used

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  • Polydopamine modified aluminum triphosphate corrosion inhibitor as well as preparation method and application thereof
  • Polydopamine modified aluminum triphosphate corrosion inhibitor as well as preparation method and application thereof
  • Polydopamine modified aluminum triphosphate corrosion inhibitor as well as preparation method and application thereof

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preparation example Construction

[0040] The preparation method of the above embodiment comprises the following preparation steps:

[0041] S100, mixing aluminum tripolyphosphate and water at a ratio of 180mL / g, and ultrasonically dispersing for 15 minutes to prepare a pre-dispersion liquid.

[0042] S200, add dopamine and trishydroxymethylaminomethane to the pre-dispersion liquid of S100 and stir well, adjust the pH of the mixed liquid to 8-9, carry out the polymerization reaction at 20-25°C, and the color of the reaction system solution changes from After being transparent to reddish brown, and then from reddish brown to dark brown or black, continue stirring at 20-25°C for 24 hours.

[0043]S300, centrifuge the black or dark brown solution obtained in S200 to collect the precipitate, and vacuum-dry the collected precipitate at 60-70° C. to obtain the corrosion inhibitor.

[0044] The present invention also provides the corrosion inhibitor shown in the following table as a comparative example:

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Abstract

The invention relates to the field of metal corrosion and protection, in particular to a polydopamine modified aluminum triphosphate corrosion inhibitor as well as a preparation method and application thereof. The preparation method of the polydopamine modified aluminum triphosphate corrosion inhibitor comprises the following preparation steps of 1, adding dopamine and tris(hydroxymethyl)aminomethane into a pre-dispersion liquid containing aluminum triphosphate to conduct polymerization reaction; and 2, after the solution of a reaction system in step 1 is black or dark brown, centrifuging the solution of the reaction system to obtain a precipitate, and drying the precipitate to obtain the corrosion inhibitor, wherein the molar ratio of the aluminum triphosphate to the dopamine is (3.5 to 18): (19 to 53). According to the preparation method of the polydopamine modified aluminum triphosphate corrosion inhibitor, the surfaces of aluminum triphosphate filler particles are coated with polydopamine, and the aluminum triphosphate filler particles are attached to a metal substrate through the polydopamine, so that the corrosion inhibition effect is further achieved, and therefore the anti-corrosion effect is more durable.

Description

technical field [0001] The invention relates to the field of metal corrosion and protection, in particular to a polydopamine-modified aluminum tripolyphosphate corrosion inhibitor and a preparation method and application thereof. Background technique [0002] In today's era of continuous growth in engineering demand, steel has become an indispensable metal material in various industries such as aerospace, automotive, machine building, and shipbuilding. However, due to the corrosion of metallic materials, the world suffers huge economic losses every year. According to reports, the direct economic loss caused by metal corrosion in the world is about 700 billion U.S. dollars every year, and the loss caused by metal corrosion in my country accounts for about 5% of the gross national product (GDP). In addition to direct economic losses, corrosion will also cause A series of indirect economic losses such as stoppage of work and production, product degradation, and efficiency reduc...

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Application Information

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IPC IPC(8): C23F11/18B05D7/24
CPCC23F11/184B05D7/24
Inventor 张贤慧陈宝吴建华朱伟春王邦建
Owner JIMEI UNIV
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