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Axial non-equidistant corrugated plate electrode

A non-equidistant, corrugated plate technology, applied in the direction of electrodes, electrode shape/type, electrolysis process, etc., can solve the problems of slow bubble diffusion, lower electrode electrolysis efficiency, electrolyte concentration fluctuations, etc., to avoid electrolysis concentration and ensure Effect of flow rate uniformity, avoidance of variance in bubble size and output rate

Pending Publication Date: 2021-12-21
HUANENG CLEAN ENERGY RES INST +9
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

During the flow of the electrolyte, the mastoid structure will generate resistance on the flow path. Due to the inconsistent distance between the electrolyte inlet and a certain horizontal line on the electrode plate, the existing uniformly distributed mastoid structure will cause the plate The flow rate of the electrolyte at the outer edge becomes lower. Since the potential of each point of the plate is basically the same under the condition of energization, the uneven flow rate of the electrolyte on the surface of the electrode will easily cause slow bubble diffusion, increased local resistance, fluctuations in electrolyte concentration, and surface electrolyte. Problems such as concentration difference will reduce the efficiency of electrode electrolysis, and will also affect the safe and stable operation of the electrolytic cell

Method used

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  • Axial non-equidistant corrugated plate electrode
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  • Axial non-equidistant corrugated plate electrode

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Such as figure 1 As shown, an axially non-equidistant corrugated plate electrode has positive and negative protruding mastoid structures on the electrode sheet 1, which are formed by mechanical stamping. The electrode piece 1 is connected to the pole frame 2 by welding or clamping.

[0030] The bottom and top of the pole frame 2 have electrolyte liquid inlets and liquid outlets.

[0031] The base material of the electrode sheet 1 is an electrical conductor such as stainless steel, metal nickel or metal titanium, and the surface of the electrode is plated with an electrocatalyst layer of a nickel-based alloy or a platinum-based alloy.

[0032] The pole piece is installed vertically in the electrolytic cell, and the mastoid structures on the left and right sides of the vertical central axis 3 are axially symmetrically distributed, and the distance from the central point of each vertical mastoid on the same side of the central axis 3 to the central axis 3 gradually increa...

Embodiment 2

[0042] An axial non-equidistant corrugated plate electrode, the electrode sheet 1 has positive and reverse protruding mastoid structures, which are formed by mechanical stamping. The electrode piece 1 is connected with the pole frame 2 by welding.

[0043] The bottom and top of the pole frame 2 have electrolyte liquid inlets and liquid outlets.

[0044] The base material of the electrode sheet 1 is 304 stainless steel, and the surface of the electrode is plated with nickel.

[0045] The pole piece is installed vertically in the electrolytic cell, and the mastoid structures on the left and right sides of the vertical central axis 3 are axially symmetrically distributed, and the distance from the central point of each vertical mastoid on the same side of the central axis 3 to the central axis 3 gradually increases. Diverge. The distance from the center line of the second column of positive mastoids to the central axis 3 is 3 cm, the distance from the center line of the second ...

Embodiment 3

[0047] An axial non-equidistant corrugated plate electrode, the electrode sheet 1 has positive and reverse protruding mastoid structures, which are formed by mechanical stamping. The electrode sheet 1 is embedded in the groove of the pole frame 2 and connected.

[0048] The bottom and top of the pole frame 2 have electrolyte liquid inlets and liquid outlets.

[0049] The base material of the electrode piece 1 is titanium material, and the surface of the electrode is plated with nickel-cobalt alloy.

[0050]The pole piece is installed vertically in the electrolytic cell, and the mastoid structures on the left and right sides of the vertical central axis 3 are axially symmetrically distributed, and the distance from the central point of each vertical mastoid on the same side of the central axis 3 to the central axis 3 gradually increases. Diverge. The distance from the center line of the second row of positive mastoids to the central axis 3 is 3 cm, the distance from the cente...

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Abstract

The invention discloses an axial non-equidistant corrugated plate electrode which comprises an electrode plate, and mastoid structures protruding forwards and reversely are arranged on the electrode plate. The mastoid structures are axially and symmetrically distributed along the central axis of the electrode plate, and the distance between every two adjacent mastoid structures is gradually increased towards the outer side with the central axis as the center. And the mastoid structures on the electrode plates are formed through mechanical stamping. The distance between the mastoid structures on the two sides of the central axis is multiplied. The positions of the mastoid structures on the electrode plates are radially arranged outwards from the vertical central shaft, so that after electrolyte is introduced in the working process of the electrolytic cell, when the electrolyte reaches the position far away from the central shaft, compared with the pole plates uniformly distributed at the mastoid positions, the resistance borne by the electrolyte is smaller, and the flow velocity of the electrolyte is closer to the flow velocity of the position near the central shaft. Therefore, the surface flow velocity consistency of the whole polar plate and the mass transfer uniformity of each position are ensured, the difference between the bubble size and the output rate is avoided, the electrolysis concentration difference is avoided, and the stable and safe operation of an electrolytic bath is facilitated.

Description

technical field [0001] The invention belongs to the technical field of hydrogen production by electrolysis of water, in particular to an axial non-equidistant corrugated plate electrode. Background technique [0002] Hydrogen is an important industrial raw material and an energy carrier. At present, the hydrogen production technology mainly uses fossil fuels such as coal and natural gas to react with steam at high temperature for conversion, accounting for more than 99% of the total output; another type of hydrogen production technology is electrolysis of water to produce hydrogen, which can be combined with wind power, Photovoltaic, hydropower and other renewable energy power generation processes are coupled together to realize the large-scale consumption of intermittent renewable energy, so that no carbon emissions are produced in the hydrogen production process, and under the background of a significant reduction in the cost of renewable energy power generation, the reali...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C25B11/02C25B11/052C25B1/04
CPCC25B11/02C25B11/052C25B1/04Y02E60/36Y02P20/133
Inventor 王金意张畅张欢任志博王鹏杰徐显明张竹砚
Owner HUANENG CLEAN ENERGY RES INST