Method for selectively preparing o-chlorotoluene
An o-chlorotoluene and selectivity technology, which is applied in the field of selective preparation of o-chlorotoluene, can solve the problems of difficult separation, complicated catalyst preparation, insufficient ortho-chlorination selectivity, etc., and achieves the effect of improving the selectivity.
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Embodiment 1
[0031] Add 30 mg of iron powder and 30 mg of 4-iododibenzothiophene (0.1% of the mass of toluene) into 30 ml of toluene, and under the condition of avoiding light and 35 ° C, uniformly and slowly pass in chlorine gas for about 7 hours, and take samples during the reaction. Gas chromatography detection. After the chlorination is finished, the toluene monochlorination mixed liquid component detection result is as follows: the transformation rate of toluene 99.81%, o-chlorotoluene content 68.50%, p-chlorotoluene content 30.08%, meta-chlorotoluene content 0.05%, the sum of polychlorinated toluene content was 1.18%.
Embodiment 2
[0033] 30 mg of iron powder and 15 mg of 1-bromodibenzothiophene (0.05% of the total mass of toluene) were added to 30 ml of toluene, and under the condition of avoiding light and 30°C, chlorine gas was uniformly and slowly introduced for about 8 hours, and samples were taken during the reaction. Gas chromatography detection. After the chlorination finishes, the toluene monochlorination mixed liquid component detection result is as follows: the conversion rate of toluene 99.28%, o-chlorotoluene content 63.69%, p-chlorotoluene content 33.30%, meta-chlorotoluene content 0.08%, the sum of polychlorinated toluene content was 2.21%.
Embodiment 3
[0035] 30mg of iron powder and 30mg of 2-bromodibenzothiophene (0.1% of the total mass of toluene) were added to 30ml of toluene, under the condition of avoiding light and 30°C, chlorine gas was evenly and slowly passed in for about 8 hours, and samples were taken during the reaction. Gas chromatography detection. After the chlorination finishes, the toluene monochlorination mixed liquid component detection result is as follows: the conversion rate of toluene 99.63%, o-chlorotoluene content 58.29%, p-chlorotoluene content 40.05%, meta-chlorotoluene content 0.15%, the sum of polychlorinated toluene content was 1.14%.
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