Charge-transporting varnish
A technology of charge transport and varnish, which is applied in the direction of circuits, conductive coatings, electrical components, etc., can solve the problems of leakage current circuit, uneven light emission of organic EL components, and the order of organic functional layers to perform functions, etc., to achieve excellent flatness, Excellent charge transport properties
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[0301] The method for producing the charge-transporting varnish is not particularly limited, and examples thereof include a method of adding a charge-transporting organic compound, a dopant, and, if necessary, other components to an organic solvent in an arbitrary order or simultaneously. In addition, in the case of a plurality of organic solvents, first, each component may be dissolved in one solvent sequentially or simultaneously, and another solvent may be added thereto, or each component may be sequentially dissolved in a mixed solvent of a plurality of organic solvents. or dissolve simultaneously.
[0302] In the charge-transporting varnish of the present invention, it is preferable to dissolve each component in an organic solvent and then filter using a submicron order filter or the like from the viewpoint of reproducibly obtaining a thin film with higher flatness.
[0303] The viscosity of the charge-transporting varnish of the present invention is usually 1 to 50 mPa·s...
Embodiment
[0346] Hereinafter, the present invention will be described more concretely with reference to synthesis examples, production examples, examples, and comparative examples, but the present invention is not limited to the following examples.
[0347] The apparatus used is described below.
[0348] (1) MALDI-TOF-MS: autoflex III smartbeam manufactured by Bruker
[0349] (2) 1 H-NMR: JNM-ECP300 FT NMR SYSTEM manufactured by JEOL Ltd.
[0350] (3) Substrate cleaning: Substrate cleaning equipment manufactured by Choshu Sangyo Co., Ltd. (decompression plasma method)
[0351] (4) Coating of varnish: spin coater MS-A100 manufactured by MIKASA Co., Ltd.
[0352] (5) Film thickness measurement and surface shape measurement: Micro shape measuring machine SURFCORDERET-4000A manufactured by Kosaka Laboratory
[0353] (6) Manufacture of components: Multifunctional vapor deposition system C-E2L1G1-N manufactured by Choshu Sangyo Co., Ltd.
[0354] (7) Measurement of the current density of...
Synthetic example 1-1
[0374] Dissolve MMA (10.0g), HEMA (12.5g), CHMI (20.0g), HPMA (2.50g), MAA (5.00g) and AIBN (3.20g) in PGME (79.8g), pass through The reaction was carried out for 20 hours to obtain an acrylic polymer P1 solution (solid content concentration: 40% by mass). The Mn of the acrylic polymer P1 was 3,700, and the Mw was 6,100.
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