Looking for breakthrough ideas for innovation challenges? Try Patsnap Eureka!

Polyurethane for solvent-free foot pad leather and preparation method thereof

A polyurethane, solvent-free technology, applied in the field of polyurethane, can solve problems such as environmental pollution, achieve the effects of environmental friendliness, increase the curing rate, and improve the bonding effect

Active Publication Date: 2022-03-04
JIAXING HEXIN CHEM IND
View PDF12 Cites 0 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, solvent-based polyurethane resin contains a large amount of toxic and harmful chemical solvents such as dimethylformamide and toluene. During the production and use of foot pad leather, a large amount of chemical solvents will volatilize into the surrounding environment, which will easily cause environmental pollution.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Image

Smart Image Click on the blue labels to locate them in the text.
Viewing Examples
Smart Image
  • Polyurethane for solvent-free foot pad leather and preparation method thereof
  • Polyurethane for solvent-free foot pad leather and preparation method thereof
  • Polyurethane for solvent-free foot pad leather and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

preparation example 1

[0047] The PBPHA polyol with a number-average molecular weight of 1500 is prepared from catalyst tetraisopropyl titanate, 1.10kg of composite polyol A and 1.900kg of 1,6-adipic acid, wherein composite polyol A and 1, The molar ratio of 6-adipic acid is 12:13, and the amount of catalyst-tetraisopropyl titanate is 40ppm of the total mass of composite polyol A and 1,6-adipic acid, and composite polyol A is composed of 1, 4-Butanediol, 1,2-propanediol, and 1,6-hexanediol are mixed in the reaction kettle in a mass ratio of 5:3:3.

[0048] The specific preparation method of PBPHA polyol is as follows: adding accurately metered composite polyol A, 1,6-adipic acid and tetraisopropyl titanate into a reaction kettle, mixing uniformly, and reacting at a temperature of 220 ° C for 1.3 hours Then, it is vacuumed step by step in the distillation tower (the degree of vacuum is gradually increased from 0.01Mpa to 0.098Mpa, when the vacuum reaches 0.098Mpa, the temperature at the top of the di...

preparation example 2

[0050] PBPHA polyol with a number-average molecular weight of 1500 is prepared from catalyst tetraisopropyl titanate, 1.19kg of composite polyol A and 1.900kg of 1,6-adipic acid, wherein composite polyol A and 1, The molar ratio of 6-adipic acid is 13:13, and the consumption of catalyst-tetraisopropyl titanate is 40ppm of the total mass of composite polyol A and 1,6-adipic acid, and composite polyol A is composed of 1, 4-Butanediol, 1,2-propanediol, and 1,6-hexanediol are mixed in the reaction kettle in a mass ratio of 5:3:3.

[0051]The specific preparation method of PBPHA polyol is as follows: adding accurately metered composite polyol A, 1,6-adipic acid and tetraisopropyl titanate into a reaction kettle, mixing uniformly, and reacting at a temperature of 220 ° C for 1.3 hours Then, it is vacuumed step by step in the distillation tower (the degree of vacuum is gradually increased from 0.01Mpa to 0.098Mpa, when the vacuum reaches 0.098Mpa, the temperature at the top of the di...

preparation example 3

[0053] The difference between this preparation example and preparation example 1 is that in this preparation example compound polyol A, 1,4-butanediol of the same mass is used to replace the 1,2-propanediol used to prepare compound polyol A in preparation 1.

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The invention relates to the field of polyurethane, and particularly discloses polyurethane for solvent-free foot pad leather and a preparation method of the polyurethane. The invention discloses polyurethane for solvent-free foot pad leather. The polyurethane is prepared from a component A, a component B and a component C, the component A is prepared from the following raw materials: PBPHA polyhydric alcohol, a chain extender, a flatting agent, a foam stabilizer and a pore opening agent; the component B is prepared from the following raw materials: aromatic diisocyanate and polyester polyol; the component C comprises a catalyst; and the molar ratio of the sum of the hydroxyl groups in the component A and the hydroxyl groups in the component B to the isocyanato in the component B is 1: 1. The preparation method comprises the following steps: S1, respectively preparing the component A, the component B and the component C; s2, mixing and stirring the component A, the component B and the component C to obtain the product. The product provided by the invention can be used for producing the foot pad leather, and has the advantage of reducing environmental pollution during production and use of the product.

Description

technical field [0001] The present application relates to the field of polyurethane, more particularly, it relates to a polyurethane for solvent-free footpad leather and a preparation method thereof. Background technique [0002] Polyurethane is a material made of liquid isocyanate and liquid polyether or glycol polyester polycondensation, which is commonly used in different fields such as footbed leather, coatings and adhesives. [0003] The polyurethane used for foot pad leather is soft to the touch and has a strong leather-like appearance, which is the most ideal substitute for natural leather, and the polyurethane used for foot pad leather is generally made of solvent-based polyurethane through a dry production process or a wet production process. have to. [0004] However, the solvent-based polyurethane resin contains a large amount of toxic and harmful chemical solvents such as dimethylformamide and toluene. During the production and use of the footpad leather, a larg...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
Patent Type & Authority Applications(China)
IPC IPC(8): C08G18/66C08G18/10C08G18/42C08G18/32C08G101/00
CPCC08G18/4238C08G18/10C08G18/664C08G2101/00C08G18/3206Y02P70/62
Inventor 徐欣欣晏雪生石磊冯敏超纪尚超文远海杨锐沈海忠
Owner JIAXING HEXIN CHEM IND
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Patsnap Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Patsnap Eureka Blog
Learn More
PatSnap group products