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Preparation method of CCM for water electrolysis hydrogen production, CCM and membrane electrode

A water electrolysis and anode technology, applied in battery electrodes, circuits, fuel cells, etc., can solve the problems of large proton exchange membrane thickness, failure to make membrane electrodes, and performance degradation of membrane electrodes, and achieve low equipment requirements and small deformation , the effect of improving performance

Pending Publication Date: 2022-03-22
鸿基创能科技(佛山)有限公司
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Problems solved by technology

[0005] In conventional fuel cell CCMs, the proton exchange membranes used are all ultra-thin reinforced proton exchange membranes, the thickness of which is generally only 8-15 μm, and the reinforcing material can alleviate the damage caused by the solvent on the surface of the proton exchange membrane when coating the slurry. Swelling, while the thickness of the proton exchange membrane currently used in CCM for hydrogen production by water electrolysis is relatively large. When the slurry is directly coated on the surface of the proton exchange membrane, the solvent will cause the proton exchange membrane to swell and wrinkle or curl, resulting in the prepared membrane Electrode performance degradation
When the degree of wrinkling or curling is high, even membrane electrodes cannot be made
Therefore, the current preparation of CCM for hydrogen production by water electrolysis generally adopts methods such as electrochemical deposition, ultrasonic spraying or transfer printing to avoid a large amount of catalyst slurry from directly contacting the proton exchange membrane. higher

Method used

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  • Preparation method of CCM for water electrolysis hydrogen production, CCM and membrane electrode
  • Preparation method of CCM for water electrolysis hydrogen production, CCM and membrane electrode
  • Preparation method of CCM for water electrolysis hydrogen production, CCM and membrane electrode

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Embodiment 1

[0051] This example provides a CCM for hydrogen production by water electrolysis, using Nafion 117 proton exchange membrane, specifically prepared by the following preparation method, including the following steps:

[0052] S1 ultrasonic atomization treatment: heating the proton exchange membrane to 90°C, ultrasonically atomizing water and spraying it on the surface of the proton exchange membrane;

[0053] S2 preparation of anode catalyst layer: 10g IrO 2 After the anode catalyst, 15g 20% ​​D2020 Nafion solution, 11g isopropanol and 17g water are mixed, use a high-speed shearing disperser to disperse evenly, and obtain the anode catalyst slurry through defoaming treatment; the proton after the step S1 treatment After the exchange membrane is heated to 90°C and fixed with a tension of 0.02MPa, the anode catalyst slurry is directly coated on one side of the surface in the heated state, and dried at 90°C, that is, formed on the side of the proton exchange membrane anode catalys...

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Abstract

The invention relates to the technical field of fuel cell preparation, in particular to a preparation method of a CCM for water electrolysis hydrogen production, the CCM and a membrane electrode, and the preparation method comprises the following steps: carrying out ultrasonic atomization treatment on a proton exchange membrane with a large thickness, fixing the proton exchange membrane by using tension, and preparing the CCM. And then coating catalyst slurry on the surfaces of the two sides of the proton exchange membrane respectively under a heating condition, and drying to form catalyst layers on the surfaces of the two sides of the proton exchange membrane. According to the method, swelling deformation of the proton exchange membrane in the coating process can be avoided, the CCM for water electrolysis hydrogen production can be prepared on a large scale by using common slit coating equipment, and the product quality is guaranteed while the production cost is greatly reduced.

Description

technical field [0001] The invention relates to the technical field of fuel cell preparation, and more specifically, to a preparation method of CCM for hydrogen production by water electrolysis, CCM and membrane electrode. Background technique [0002] As a green energy with wide sources, zero pollution, and zero carbon emissions, hydrogen energy is an ideal energy source for promoting the clean utilization of traditional fossil energy and promoting the large-scale development of renewable energy. In the next period of time, hydrogen energy will play an important role in my country's industrial carbon reduction process. [0003] According to different hydrogen production methods, hydrogen can be gray hydrogen, blue hydrogen and green hydrogen. Among them, gray hydrogen refers to the hydrogen produced by carbon-based energy sources such as coal, and the production process will emit carbon dioxide; Hydrogen that truly achieves zero carbon emissions. Based on the original in...

Claims

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Application Information

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IPC IPC(8): H01M4/88H01M8/0656H01M8/1004
CPCH01M4/8828H01M4/8882H01M8/1004H01M8/0656Y02E60/50
Inventor 蔡云敖洪亮古建孙昭红钟家强杨云松邹渝泉叶思宇唐军柯
Owner 鸿基创能科技(佛山)有限公司
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