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Method for enriching D-psicose 3-epimerase by using membrane and application of D-psicose 3-epimerase

A technology of epimerase and psicose, which is applied in the field of using membrane to enrich D-psicose 3-epimerase, and can solve the problem of D-psicose 3-epimerase The problems of low enzyme utilization rate and high preparation cost of psicose can achieve the effect of low production cost, large social benefit and broad economic benefit.

Pending Publication Date: 2022-04-01
BAOLINGBAO BIOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Aiming at the problems of high preparation cost of psicose and low utilization rate of D-psicose 3-epimerase in the prior art, the present invention discloses a method for enriching D-psicose 3-epimerase by membrane Methods and applications of epimerase

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0024] (1) Bacteria removal: the saccharification solution with a sugar concentration of 42% without enzymes is used for sterilization operation with a ceramic membrane with a pore size of 0.1um. During the operation, the temperature of the material inside the ceramic membrane is controlled at 18°C, and the pressure is controlled at 0.2MPa After the filtration is completed, rinse the ceramic membrane with 0.3 times water (V / V) until the sugar concentration of the permeated phase is zero;

[0025] (2) Ultrafiltration Enrichment Enzyme: Step (1) The permeate after ceramic membrane treatment is ultrafiltered with an ultrafiltration membrane. The molecular weight cut-off of the ultrafiltration membrane is 10,000 Daltons. , the pressure is controlled at 0.4Mpa, and the ultrafiltration membrane is washed with 0.4 times of water (V / V) until the sugar concentration of the permeated phase is zero, and the concentrated phase is collected, which is the recovered D-psicose 3-epimide Const...

Embodiment 2

[0028] (1) Bacteria removal: the saccharification solution with a sugar concentration of 50% without enzymes is used for sterilization operation with a ceramic membrane with a pore size of 0.1um. During the operation, the temperature of the material inside the ceramic membrane is controlled at 20°C, and the pressure is controlled at 0.4MPa After the filtration is completed, wash the ceramic membrane with 0.5 times water (V / V) until the sugar concentration of the permeated phase is zero;

[0029] (2) Ultrafiltration Enrichment Enzyme: Step (1) The permeate after ceramic membrane treatment is ultrafiltered by ultrafiltration membrane, the molecular weight cut-off of ultrafiltration membrane is 10000 Daltons, and the temperature of the material inside the ultrafiltration membrane is controlled at 18°C , the pressure is controlled at 0.6Mpa, and the ultrafiltration membrane is washed with 0.4 times of water (V / V) until the sugar concentration of the permeated phase is zero, and the...

Embodiment 3

[0032] Reuse of the D-psicose 3-epimerase recovered in Example 1:

[0033] Prepare a fructose solution with a sugar concentration of 45%, adjust the pH value to 6.2, add the D-psicose 3-epimerase recovered in Example 1, and add the enzyme in an amount of 35 U / g fructose dry basis, After reacting at 60°C for 20 h, the components of the saccharification solution were determined to be: 0.27% polysaccharide, 0.73% disaccharide, 0.99% glucose, 1.21% mannose, 70.45% fructose, and 26.18% allulose; 1) Compared with the composition of the saccharification solution in the medium, the conversion rate of fructose into allulose is roughly the same (the amount of enzyme added is equal), so the D-psicose 3-epimerase recovered by the present invention Still has a strong transformation ability.

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Abstract

The invention discloses a method for enriching D-psicose 3-epimerase by using a membrane and application of the D-psicose 3-epimerase. The method comprises the following steps: performing sterilization operation on saccharification liquid without enzyme deactivation by using a ceramic membrane, controlling the pressure to be 0.2-0.4 MPa, and washing the ceramic membrane with water after filtration is completed; and carrying out ultrafiltration on the permeate treated by the ceramic membrane by using an ultrafiltration membrane at the pressure of 0.4-0.8 MPa, washing the ceramic membrane by using water after ultrafiltration, and collecting a concentrated phase, thereby obtaining the recovered D-psicose 3-epimerase. The saccharification liquid without enzyme deactivation is treated by the ceramic membrane and the ultrafiltration membrane, the enrichment method is simple in process and low in production cost, unutilized D-psicose 3-epimerase is recycled, convenience is provided for functional sugar manufacturing enterprises, cost is saved, and the method has wide economic benefits and social benefits and high popularization value.

Description

technical field [0001] The invention belongs to the technical field of biological enzyme recovery, and in particular relates to a method and application for enriching D-psicose 3-epimerase by using a membrane. Background technique [0002] With the continuous development of the national economy, people's dietary structure has changed, and chronic diseases such as obesity, diabetes, hyperglycemia, and hyperlipidemia have become prevalent worldwide. Therefore, people pay more and more attention to healthy diet, especially the intake of sugary foods, which makes low-calorie sweeteners show broad application prospects [0003] D-psicose, as a six-carbon rare ketose, is an epimer of fructose, a rare monosaccharide that exists in nature but is very low in content. It is mainly derived from a small number of plants and a few bacteria. Its taste is close to that of sucrose, its sweetness is 70% of that of sucrose, and its calories are 0.3% of that of sucrose. Maillard reaction can...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C12N9/90C12P19/02C12P19/24
Inventor 李克文栾庆民陈雪薛雅莺高蕾蕾杨俊丽韩敏森茂治续晓琪
Owner BAOLINGBAO BIOLOGY