Toughened grafted polymers
A technology of copolymers, mixtures, applied in the direction of graft polymer adhesives, adhesive types, preparations for skin care, etc., can solve the problem of hard touch, not so satisfactory, etc.
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Embodiment 1
[0149] poly(tert-butyl acrylate-co-methoxyethyl acrylate-co-acrylic acid)-graft-[poly(n-propyl methacrylate-co-methacrylic acid); poly(dimethylsilyl Synthesis of oxane)] copolymers
Embodiment 2
[0152] Synthesis of poly(tert-butyl acrylate-co-methoxyethyl acrylate-co-methacrylic acid)-graft-poly(n-propyl methacrylate-co-methacrylic acid) copolymer
[0153] Into a round bottom flask equipped with a reflux condenser, temperature controller, mechanical stirring device, and under a slight argon pressure (8 psi), was charged acetone (0.5 L), tert-butyl acrylate (42.4 g), acrylic acid-2 - Methoxyethyl ester (29 g), methacrylic acid (9 g) and vinylphenyl terminated (n-propyl methacrylate-co-methacrylic acid) macromonomer (20 g) (obtained from Example 2) . The solution was stirred until all components were dissolved, then heated to 60°C. Azobisisobutyronitrile (0.5 g) was added to the system. After 10 hours, the solution was cooled and precipitated in water to give a graft copolymer.
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