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Package-mix agricultural chemical compositions having improved stability

A composition and pesticide technology, applied in biocides, pharmaceutical formulations, plant raw materials, etc., can solve problems such as physical instability and high specific gravity

Inactive Publication Date: 2002-10-16
MONSANTO TECH LLC
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, if this mixture composition is provided in liquid form, then two problems have to be overcome
[0018] The first problem is that suspensions of flufenazil microparticles in aqueous solutions of glyphosate salts are physically unstable, and in particular such suspensions have a tendency to settle due to the high specific gravity (20 °C is 1.51)
[0019] The second issue is that flufenazim has been found to chemically degrade when exposed to high concentrations of saline solutions such as phosphine salt for prolonged periods of time

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0109] The compositions of the present invention, which are detailed in Table 4, containing glyphosate isopropylammonium salt and flumefluzamide, were prepared according to the procedure described below.

[0110] Component

gram

Propyrylflufen Premixed Suspension

Propyridine (99.4%)

Phenylxylylethane, Sorpol TM 7065

Emulsifier, Sorpol TM 7830P

Emulsifier, Sorpol TM 7377 P

Propylene Glycol

12.5

25.0

31.0

41.0

21.0

Total

130.5

Glyphosate Aqueous Premix

Glyphosate Isopropyl Ammonium Salt (62% Aqueous Solution)

Deionized water

Organosiloxane defoamer, Shin-etsu TM KM-90 (10%)

500.0*

353.5

1.0

Total

854.5

viscosity modifier

Colloidal Hydrophilic Silica, Aerosil TM COK-84

15.0

[0111] *Equivalent to 310.0 g glyphosate isopropyl ammonium salt; 230.0 g glyphosate acid equi...

Embodiment 2

[0116] Listed in Table 5 in detail, the composition of the present invention containing glyphosate isopropyl ammonium salt and propargyl flufenamide is prepared with steps similar to Example 1, but using Santicizer TM 141 as an organic solvent.

[0117] Component

[0118] *Equivalent to 310 grams of glyphosate isopropyl ammonium salt; 230 grams of glyphosate acid equivalent

Embodiment 3

[0120] Listed in Table 6 in detail, the composition of the present invention containing glyphosate isopropyl ammonium salt and propargyl flufluramid is prepared by steps similar to Example 1, but using the Vinicizer of Kao Company TM 40 as an organic solvent. Use additional emulsifier New Kalgen TM 4016EHB.

[0121] Component

[0122] *Equivalent to 310 grams of glyphosate isopropyl ammonium salt; 230 grams of glyphosate acid equivalent

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PUM

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Abstract

A high-concentration mixed composition (package-mixcomposition) is proposed, which contains water-soluble pesticides or plant growth regulators, such as the salt of the herbicide glyphosate, and water-insoluble solid pesticides or plant growth regulators, such as the herbicide C Fluflufenafil. The water-soluble pesticide or plant growth regulator is dissolved in the continuous water phase of the composition, while the solid particles of the water-insoluble pesticide or plant growth regulator are suspended in the water phase. These solid particles, individually or in clusters, are closely surrounded by a barrier layer containing one or two water-immiscible organic solvents or emulsifiers with a hydrophilic-lipophilic balance (HLB) of not greater than about 15. The composition may optionally additionally contain a viscosity modifier, such as colloidal hydrophilic silica, dispersed in the aqueous phase. The composition of the present invention exhibits improved inhibition of settling of solid particles and / or increased inhibition of chemical degradation of water-insoluble pesticides or plant growth regulators compared to other similar compositions that do not contain a barrier layer or organic solvent.

Description

field of invention [0001] This invention relates to pesticide and / or plant growth regulator compositions for use in agriculture and related industries. More particularly, the present invention relates to liquid high concentration compositions containing at least two active ingredients. One of the active ingredients is water soluble and the other is substantially water insoluble. The liquid high-concentration composition is suitable for application to plants or soil after being diluted with water. Active ingredients that may be formulated into compositions of the present invention include pesticides such as herbicides, algicides, fungicides, bactericides, viricides, insecticides, acaricides, nematicides and molluscicides , and plant growth regulators. Background of the invention [0002] For various purposes in agriculture and related industries, it is often desirable to simultaneously apply two or more biologically active compounds, each of which is...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): A01N25/00A01N25/04A01N43/84A01N57/20A61K36/58
CPCA01N25/04A01N43/84A01N57/20Y10S977/70Y10S977/795Y10S977/775Y10S977/776Y10S977/963Y10S977/787A01N39/04A01N37/40A01N2300/00
Inventor T·佐藤M·口羽
Owner MONSANTO TECH LLC
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