Process for continuously preparing double metal cyanide complex catalyst
Patent Information
- Authority / Receiving Office
- CN · China
- Patent Type
- Applications(China)
- Current Assignee / Owner
- SINOPEC JINLING PETROCHEMICAL CO LTD
- Publication Date
- 2003-11-26
- Estimated Expiration
- Not applicable · inactive patent
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Abstract
Description
technical field
[0001] The present invention relates to double metal cyanide (DMC) complex catalyst manufacturing process Background technique
[0002] As we all know, double metal cyanide complex catalyst (DMC cat) is used for ring-opening polymerization of epoxide, and its composition is generally:
[0003] m a 1 [M 2 (CN) b (G) c ] d ·xM 3 (X) e ·wH 2 O·yL 1 · zL 2 Formula I
[0004] m 1 is at least one metal ion selected from: Zn (II) , Fe (II) , Fe (III) 、Co (II) 、Ni (II) 、Mo (IV) , Sn (II) 、Cu (II) , Pb (II) 、Mo (VI) 、Al (III) , V (IV) , V (V) 、Sr (II) , W (IV) , W (VI) , Mn (II) and Cr (III)
[0005] m 2 is at least one transition metal ion selected from: Fe (II) , Fe (III) 、Co (II) 、Co (III) 、Cr (II) 、Cr (III) , Mn (II) , Mn (III) , V (IV) , V (V) 、Ir (III) 、Rh (III) 、Ni (II) 、Ru (II)
[0006] m 3 stands for M 1 and / or M 2
[0007] G, X is CN - , F - , Cl - 、Br - , I - , OH - , NO 2 - , CO 3 2- , NO ...