Composite nano material modified emulsion and its preparation method
A technology of composite nanomaterials and inorganic nanomaterials, applied in the field of emulsion modified by composite nanomaterials and its preparation, can solve the problems of high surface energy, large amount of residual emulsion, large specific surface area of nanopowder, etc., and achieve improved storage stability Effect
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Embodiment 1
[0014] 1. Preparation of nanomaterial compound
[0015] 10 parts by weight of nano-alumina powder (particle size 20nm) and 400 parts by weight of nano-silica sol (solid content 25%, average particle size 10nm) are stirred evenly in a container, and then placed in an ultrasonic disperser (power: 800 watts) Disperse until the particle size is less than 120nm to obtain a compound, wherein the nano-alumina powder accounts for 10% of the solid content of the nano-silica sol, and store it for future use.
[0016] 2. The formula of acrylate emulsion is shown in Table 1.
[0017] components
raw material name
Dosage
435
532
acrylic
33
coupling agent
KH570
2
Emulsifier
20
Initiator
6
Deionized water
1500
[0018] 3. Preparation of modified emulsion
...
Embodiment 2
[0021] 1. The same formula and method as in Example 1 were used to prepare the nanomaterial compound.
[0022] 2. The formula of the acrylate emulsion is the same as in Example 1.
[0023] 3. Preparation of modified emulsion
[0024] Add the compound prepared according to the formula and method of Example 1 and 2 / 3 of deionized water (1000 parts) into the reactor to raise the temperature. When the temperature reaches 84-88°C, follow the emulsion polymerization of Example 1 Methods The emulsion polymerization was completed in the presence of the compound, and the acrylate emulsion modified by composite nanomaterials was prepared.
Embodiment 3
[0032] 1. Prepare the composite of nanomaterials according to the formula and method of Example 1.
[0033] 2. The formula of styrene-acrylic emulsion is shown in Table 2.
[0034] components
raw material name
Dosage
435
100
432
acrylic
33
coupling agent
KH570
2
Emulsifier
MS-1
40
Initiator
8
Deionized water
1500
[0035] 3. Preparation of modified emulsion.
[0036] Except that the monomers in Table 2 are used to replace the monomers in Table 1 of Example 1, the rest of the operations are the same as in Example 1. The prepared styrene-acrylic emulsion is added to the prepared nanomaterial compound under stirring, and mixed for 0.5 hours to obtain Styrene-acrylic emulsion modified by composite nanomaterials.
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