Method for treating awste water for oil field tertiary oil production prepared polymer solution

A technology for preparing polymers and treatment methods, which is applied in the field of oilfield tertiary oil recovery to prepare polymer solutions for wastewater treatment. It can solve the problems of polymer solution viscosity drop, oil field recovery rate limitation, and polymer restrictions, and achieve high viscosity. Effect

Active Publication Date: 2005-03-02
PETROCHINA CO LTD
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AI Technical Summary

Problems solved by technology

However, due to the serious shortage of fresh water resources in most oil fields in my country, the continuous application of the mature clear water polymer flooding technology to improve oil recovery is limited, and there are also serious problems in the treatment and discharge of sewage produced by oil wells, and the use of sewage instead of clear water to prepare polymers One of the most serious problems brought by the solution is the degradation of the polymer by various complex chemical components in the sewage. The most important thing is that the sewage contains the active substance ferrous ions (Fe 2+ ) leads to a substantial decrease in the viscosity of the polymer solution
The simple method of oxygen waterfall in sewage can oxidize ferrous ions to ferric ions, temporarily relieve Fe 2+ Degradation of polymers, but the underground oil reservoir is a high-temperature and high-pressure reducing environment. After the ferrous ions in the sewage are oxidized, they remain in the sewage in the form of ferric iron and are injected into the underground oil reservoir. In the reducing environment It is reduced to ferrous ions, which degrades the polymer twice in the oil layer (reduces the viscosity of the polymer solution). Therefore, the sewage produced in the oil field seriously restricts the application of polymer flooding EOR technology

Method used

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Embodiment Construction

[0016] In order to further understand the content of the invention, characteristics and effects of the present invention, the following examples are cited hereby, and the details are as follows: Under normal temperature and pressure conditions,

[0017] The first step; fresh sewage through a 40m 3 Catalytic oxidation tank, that is, use an air compressor to fill a large amount of air into the sewage through the bottom of the tank, so that the ferrous ions in the sewage are oxidized into ferric ions, and other active substances in the sewage are also oxidized and deactivated; The dissolved hydrogen sulfide gas is carried away by the air. Gas volume: for 40m 3 The catalytic oxidation tank, its air filling volume is 1m 3 / minute.

[0018] The second step: the aerated and oxygenated sewage passes through the filter device to remove ferric ions or other harmful divalent metal ions (calcium ions Ca 2+ or magnesium ion Mg 2+ ), ferric ions in sewage are represented by ferric hydr...

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Abstract

The treating process of oil field waste water for compounding tertiary oil production polymer solution includes aeration of waste water in aeration tank with air compressor to aerate from the bottom of the tank; filtering to eliminate three-valent iron ion and other harmful two-valent metal ion, with the three-valent iron being eliminated as ferric hydroxide with manganese sand; and treatment in oxygen eliminating apparatus. The treated waste water may be used directly in compounding polymer solution injected to stratum for displacing oil. The polymer solution compounded with the treated waste water has higher viscosity than that compounded with clear water and thus higher oil recovering rate. The present invention can eliminate environmental pollution caused by oil field waste water and make full use of water resource.

Description

technical field [0001] The invention belongs to a technology for enhancing oil recovery, and in particular relates to a method for treating sewage used for preparing polymer solution in oilfield tertiary oil recovery by using oilfield output sewage instead of clear water to prepare polymer. Background technique [0002] Most of the oil reservoirs in my country belong to continental deposits, and the reservoir heterogeneity is serious. After water flooding development, due to serious fingering of injected water, the sweep efficiency of water flooding is low, and the development effect is poor. According to the calibration results of the recovery rate of onshore water-flooded oilfields organized by the former China National Petroleum Corporation Development Bureau, the recovery rate is only 35%. Under the current situation that my country's reserve resources are very scarce, how to extract nearly two-thirds of the remaining underground resources as much as possible is a strate...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/20C02F1/64C02F1/72
Inventor 狄连成何鲜倪方天杨怀军赵丕兰阎云贵张杰
Owner PETROCHINA CO LTD
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