Highly active cement mineral forming promoter

An accelerator and high-activity technology, which is applied in the field of new dry process cement production and high-activity cement mineral formation accelerator, can solve the problem that mineralizers cannot meet the requirements of seed crystals and mineralizers, and the fineness of steel slag is difficult to reach cement crystals. Requirements of species, problems affecting clinker quality, production process stability, etc., to achieve the effects of broadening the range of firing, improving ease of firing, and good economic and social benefits

Inactive Publication Date: 2005-04-06
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the amount of general mineralizer in the raw meal is small (1-3%), it is not easy to mix evenly, and it is easy to cause local lumps, which affects the quality of clinker and the stability of the production process.
At the same time, there is no intensive activation treatment for industrial waste residues, and the effect of its seed crystals and modification is not significant
For example, it involves a cement mineralizer composed of industrial by-products containing calcium silicate and gypsum (patent application number 94111660.3). The difference is large, and the fineness of steel slag is difficult to meet the requirements of cement seed crystals, so that the mineralizer cannot meet the requirements of the role of crystal seeds and mineralizers; and in the batching process, there is no substitute for the corresponding raw materials for steel slag with a large amount. , it is easy to cause changes in raw material ratio
Another example relates to a raw material multi-component activator used in the production of shaft kiln cement (patent application number 00112032.8), which is composed of steel slag or clinker, fluorite and gypsum, and does not consider the fineness of the material, and does not give The amount of this activator in the raw meal and its applicable raw meal ratio value range, when the raw meal is mixed, because the steel slag is used to completely replace the iron raw material, and the steel slag content is not high, so the iron ratio of the raw meal is low , the viscosity of the liquid phase increases during firing, which cannot meet the requirements of large and stable industrial production

Method used

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  • Highly active cement mineral forming promoter
  • Highly active cement mineral forming promoter

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] 0.8kg steel slag and 0.2kg mineralizer (chemical composition: SiO 2 3.1%, Al 2 o 3 0.65%, Fe 2 o 3 0.35%, CaO 23.2%, SO 3 23.5%, P 2 o 3 0.7%, CaF 2 48.5%) compound grinding to make an activator with a fineness of 450m 2 / kg, then with a fineness of 350m 2 Mix 4kg of high-calcium ash per kg evenly, and mix it into 95kg of raw meal. The raw meal rate of cement is KH=0.88, n=2.0, p=1.2.

Embodiment 2

[0023] 0.4kg steel slag and 0.6kg mineralizer (chemical composition: SiO 2 3.6%, Al 2 o 3 0.8%, Fe 2 o 3 0.45%, CaO 21.6%, SO 3 24.8%, P 2 o 3 0.5%, CaF 2 48.25%) compound grinding to make an activator with a fineness of 550m 2 / kg, then with a fineness of 450m 2 Mix 11kg / kg slag powder evenly, and mix it into 88kg of raw meal. The raw meal rate of cement is KH=0.98, n=3.0, p=1.8.

Embodiment 3

[0025] 0.6kg steel slag and 0.4kg mineralizer (chemical composition: SiO 2 3.9%, Al 2 o 3 0.72%, Fe 2 o 3 0.42%, CaO 23.9%, SO 3 20.6%, P 2 o 3 0.76%, CaF 2 49.7%) compound grinding, made into activator, the fineness is 500m 2 / kg, then with a fineness of 400m 2 Mix 7kg / kg steel slag powder evenly, and mix it into 92kg of raw meal. The cement raw meal rate values ​​are KH=0.94, n=2.5, p=1.5.

[0026] Attached Table 1: Formula (parts by weight) of highly active cement mineral formation accelerator

[0027]

[0028] Attached Table 2: Seed Crystal Activator Formula

[0029]

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Abstract

The invention relates to high activity cement mineral forming accelerating agent applied to produce new type dry method cement. It is made up of seed crystal activating agent and high calcium carrier, and their proportioning by weight respectively are from one portion to three portion, and from eight portion to twenty four portion. The constituent and weight content of the seed crystal activating agent is from forty percent to eighty percent of the slag, the mineralizing agent is from twenty percent to sixty percent. The main effects of the accelerating agent supplied by the invention are that it obviously appear the seed crystal and mineralizing action, can greatly improve the raw material inflammability, reduce the fire temperature, broaden the fire range, increase the C3S content and activity of the clinker, so that increase the output and quality, as well as save resource and energy source, reduce the environment loading, and possess better economic and social benefit.

Description

technical field [0001] The invention relates to the field of building materials, in particular to a highly active cement mineral formation accelerator, which is suitable for the production of new dry process cement. Background technique [0002] Additives that accelerate or improve the formation of cement minerals, such as cement mineralizers, raw meal activators, etc., have been studied a lot at home and abroad, and there are a lot of literature. The main technical contents in these documents are: [0003] 1. Mineralizer formed by cement minerals: Cement clinker firing is a solid-liquid phase reaction process with slow reaction speed and high temperature, and CaCO 3 Decomposition and liquid phase formation require a large amount of energy and affect clinker yield and quality. The introduction of mineralizer can accelerate the generation of liquid phase and promote C 3 The formation of S can improve the burnability of raw meal, increase the output and quality of clinker, ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B7/42
Inventor 马保国许婵娟穆松李叶青胡贞武
Owner WUHAN UNIV OF TECH
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